Related papers: Understanding correlation between two bound state …
While calculations and measurements of single-particle spectral properties often offer the most direct route to study correlated electron systems, the underlying physics may remain quite elusive, if information at higher particle levels is…
It can be argued that electron correlation, as a concept, deserves the same prominence in general chemistry as molecular orbital theory. We show how it acts as Nature's "chemical glue" at both the molecular and supramolecular levels.…
In quantum chemistry calculations, the correlation energy is defined as the difference between the Hartree-Fock limit energy and the exact solution of the nonrelativistic Schrodinger equation. With this definition, the electron correlation…
The leading-order electron-atom bremsstrahlung is investigated within the rigorous relativistic approach based on the partial-wave representation of the Dirac wave functions in the external atomic field. Approximating the atomic target by…
The electronic conductance of a molecule making contact to electrodes is determined by the coupling of discrete molecular states to the continuum electrode density of states. Interactions between bound states and continua can be modeled…
The effects on the non-relativistic dynamics of a system compound by two electrons interacting by a Coulomb potential and with an external harmonic oscillator potential, confined to move in a two dimensional Euclidean space, are…
The tunability of binding energies is explored by modulating a finite dielectric slab width in a planar, three dielectric system. After verifying the equivalence of the field method and method of images, three different configurations are…
We introduced some contact potentials that can be written as a linear combination of the Dirac delta and its first derivative, the $\delta$-$\delta'$ interaction. After a simple general presentation in one dimension, we briefly discuss a…
Understanding the electrical double layer (EDL), i.e, the distribution of electrolyte at an electrified interface, in concentrated electrolytes is important for various technologies, such as supercapacitors, batteries and electrocatalysis.…
New ways to treat electron correlation in electronic structure problems are discussed in the context of many-electron theory. The present work focuses primarily on static correlation. In related work, a method for including dynamical…
The correlation holes for densities of equal and opposite spin around a test electron are determined from the Schr\"{o}dinger equation with proper boundary conditions. The traditional "exchange" term follows from the boundary condition…
For the first time the exact analytical expressions for the three-dimensional bound electron states in the Coulomb field of the chain consisting of positively charged ions, are obtained within the Dirac description, using the new spinor…
It is shown that the Coulomb correlation problem for a system of two electrons (two charged particles) in an external oscillator potential possesses a hidden $sl_2$-algebraic structure being one of recently-discovered quasi-exactly-solvable…
We present an analysis of the two-dimensional Schrodinger equation for two electrons interacting via Coulombic force and confined in an anizotropic harmonic potential. The separable case of wy = 2wx is studied particularly carefully. The…
Approximate solutions of the Dirac equation are found for ultrarelativistic particles moving in a periodic potential, which depends only on one coordinate, transverse to the largest component of the momentum of the incoming particle. As an…
The prototypical exciton model of two interacting Dirac particles in graphene was analyzed in [1] and it was found that in one of the electron-hole scattering channels the total kinetic energy vanishes, resulting in a singular behaviour. We…
An insight into bispinor analysis makes it possible to describe the electron in selfaction as a fundamental steady state. The electromagnetic theory, and the Dirac equation for the study of an electron in presence of external potentials,…
We study two correlated electrons in a nearest neighbour tight- binding chain, with both on site and nearest neighbour interaction. Both the cases of parallel and antiparallel spins are considered. In addition to the free electron band for…
The family of solutions to the Dirac equation for an electron moving in an electromagnetic lattice with the chiral structure created by counterpropagating circularly polarized plane electromagnetic waves is obtained. At any nonzero…
We demonstrate the control of electron-electron correlation in frustrated double ionization (FDI) of the two-electron triatomic molecule D$_{3}^{+}$ when driven by two orthogonally polarized two-color laser fields. We employ a…