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A comprehensive theoretical description is given for the spin relaxation and diffusion in solids. The formulation is made in a general statistical-mechanical way. The method of the nonequilibrium statistical operator (NSO) developed by D.…

Statistical Mechanics · Physics 2009-11-11 A. L. Kuzemsky

We consider nuclear spin-lattice relaxation rate resulted from a diffusion equation for rotational wobbling in a cone. We show that the widespread point of view that there are no analytical expressions for correlation functions for wobbling…

Soft Condensed Matter · Physics 2015-05-30 A. E. Sitnitsky

It is the purpose of this paper to present a computational framework for reliably determining the frequency-dependent intermolecular and intramolecular NMR dipole-dipole relaxation rate of spin $1/2$ nuclei from MD simulations. The approach…

Soft Condensed Matter · Physics 2024-02-20 Dietmar Paschek , Johanna Busch , Eduard Mock , Ralf Ludwig , Anne Strate

The diffusion motion of spin-bearing molecules is considerably affected in confined environments. In Nuclear Magnetic Resonance (NMR) experiments, under the presence of magnetic field gradients, this movement can be encoded in spin phase…

Statistical Mechanics · Physics 2022-07-19 Felipe Pereira-Alves , Diogo O. Soares-Pinto , Fernando F. Paiva

The work is devoted to the problem of multiple signals of nuclear spin echoes in magnets, excited by a series of radio-frequency (RF) arbitrary duration pulses exceeding the free induction decay time. The quantum-statistical approach based…

Other Condensed Matter · Physics 2012-06-19 M. D Zviadadze , G. I. Mamniashvili , T. O. Gegechkori , A. M. Akhalkatsi , T. A. Gavasheli

The methods of Nuclear Magnetic Resonance belong to the best developed and often used tools for studying random motion of particles in different systems, including soft biological tissues. In the long-time limit the current mathematical…

Statistical Mechanics · Physics 2018-03-06 Vladimir Lisy , Jana Tothova

At low temperatures, spin dynamics in ideal spin ice is due mainly to dilute, thermally excited magnetic monopole excitations. I consider how these will affect the dynamics of a nuclear spin (the same theory applies to muon spin resonance…

Strongly Correlated Electrons · Physics 2012-10-31 Christopher L. Henley

Transverse NMR relaxation from spins diffusing through a random magnetic medium is sensitive to its structure on a mesoscopic scale. In particular, this results in the time-dependent relaxation rate. We show analytically and numerically…

Soft Condensed Matter · Physics 2018-10-12 Alexander Ruh , Philipp Emerich , Harald Scherer , Dmitry S. Novikov , Valerij G. Kiselev

The NMR relaxation rate $1/T_{1}$ is studied for one-dimensional multicomponent spin-orbital systems. By combining the bosonization techniques and the exact solution of the SU($n$) model, we evaluate the power-law exponent and the…

Strongly Correlated Electrons · Physics 2015-06-24 Akira Kawaguchi , Tatsuya Fujii , Norio Kawakami

In this contribution, we compute the $^1$H nuclear magnetic resonance (NMR) relaxation rate of liquid water at ambient conditions. We are using structural and dynamical information from Coupled Cluster Molecular Dynamics (CCMD) trajectories…

The existing theory of the microscopic interpretation of the dynamical contribution to zero-field muon depolarization spectra in a longitudinal geometry is developed. The predicted relaxation of the muon depolarization is calculated from…

Materials Science · Physics 2009-11-11 C. A. Steer

Traditional theories of the NMR autocorrelation function for intramolecular dipole pairs assume single-exponential decay, yet the calculated autocorrelation of realistic systems display a rich, multi-exponential behavior resulting in…

The attenuation function S(t) for an ensemble of spins in a magnetic-field gradient is calculated by accumulation of the phase shifts in the rotating frame resulting from the displacements of spin-bearing particles. The found S(t),…

Statistical Mechanics · Physics 2017-01-11 V. Lisy , J. Tothova

Reorientational dynamics-motion defined by changes in the direction of a vector or tensor-determine relaxation behavior in nuclear magnetic resonance (NMR). However, if multiple processes exist that result in reorientation, then analyzing…

Chemical Physics · Physics 2021-11-18 Albert A. Smith

Nuclear Magnetic Resonance (NMR) spans diverse fields from biology to quantum science. Employing NMR on a floating object could unveil novel possibilities beyond conventional operational paradigms. Here, we observe Nuclear Magnetic…

Quantum Physics · Physics 2024-07-30 J. Voisin , A. Durand , T. Copie , M. Perdriat , G. Hétet

Redfield's master equation is solved analytically for a nuclear system with spin $I=7/2$. The solutions of each density matrix element are computed using the irreducible tensor operator basis. The $^{133}$Cs nuclei of the…

This study investigates spin squeezed states in nuclear magnetic resonance (NMR) quadrupolar systems with spins $I=3/2$ and $I=7/2$ at room temperature, taking into account the effects of relaxation on the dynamics. The origin of spin…

The translational-diffusion coefficient $D_T$ and the spin-rotation contribution to the $^1$H NMR relaxation time $T_{1J}$ for methane (CH$_4$) are investigated using MD (molecular dynamics) simulations, over a wide range of densities…

Chemical Physics · Physics 2018-06-13 Philip M. Singer , D. Asthagiri , Walter G. Chapman , George J. Hirasaki

We study relaxation of a spin in magnetic resonance force microscopy (MRFM) experiments. We evaluate the relaxation rate for the spin caused by high-frequency mechanical noise of the cantilever under the conditions of adiabatic spin…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 D. Mozyrsky , I. Martin , D. Pelekhov , P. C. Hammel

We study the decay of multiple quantum (MQ) NMR coherences in systems with the large number of equivalent spins. As being created on the preparation period of MQ NMR experiment, they decay due to the dipole-dipole interactions (DDI) on the…

Quantum Physics · Physics 2011-01-25 S. I. Doronin , E. B. Fel'dman , A. I. Zenchuk