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Related papers: Ab initio theory of graphene-iron(II) phthalocyani…

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The magnetic tetrapyrrole molecules (such as porphyrins and phthalocyanines) with an active transition metal atom in their centre are currently intensively studied as prosperous potential elements of devices for high-density information…

Materials Science · Physics 2022-10-06 Aleksei Koshevarnikov , Tomi Ketolainen , Jacek A. Majewski

Transition metal phthalocyanines (TMPc's) are under intense scrutiny in the field of spintronics, as they may be promising storage devices. The simplicity and cheapness of such molecules increase their commercial potential. There is an…

Materials Science · Physics 2022-10-04 Aleksei Koshevarnikov , Jacek A. Majewski

In this paper, we have done a comparative study of electronic and magnetic properties of iron phthalocyanine (FePc) and cobalt phthalocyanine (CoPc) molecules physisorbed on monolayer of MoS$_2$ and graphene by using density functional…

Materials Science · Physics 2018-09-05 Soumyajyoti Haldar , Sumanta Bhandary , Hakkim Vovusha , Biplab Sanyal

Depositing magnetic insulators on graphene has been a promising route to introduce magnetism via exchange proximity interaction in graphene for future spintronics applications. Molecule-based magnets may offer unique opportunities because…

Mesoscale and Nanoscale Physics · Physics 2021-09-28 Haiyang Pan , Xiaobo Wang , Qiaoming Wang , Xiaohua Wu , Chang Liu , Nian Lin , Yue Zhao

The moir\'e superstructure of graphene grown on metals can drive the assembly of molecular architectures, as iron-phthalocyanine (FePc) molecules, allowing for the production of artificial molecular configurations. A detailed analysis of…

Hybrids of graphene and two dimensional transition metal dichalcogenides (TMDC) have the potential to bring graphene spintronics to the next level. As we show here by performing first-principles calculations of graphene on monolayer…

Mesoscale and Nanoscale Physics · Physics 2015-10-14 Martin Gmitra , Jaroslav Fabian

We report an advanced organic spin-interface architecture with magnetic remanence at room temperature, constituted by metal phthalocyanine molecules magnetically coupled with Co layer(s), mediated by graphene. Fe- and Cu-phthalocyanines…

The magnetic and electronic properties of metal phthalocyanines (MPc) and fluorinated metal phthalocyanines (F$_{16}$MPc) are studied by means of spin density functional theory (SDFT). Several metals (M) such as Ca, all first d-row…

Materials Science · Physics 2013-04-22 O. I. Arillo-Flores , M. M. Fadlallah , C. Schuster , U. Eckern , A. H. Romero

Metalated phthalocyanines (Pc's) are robust and versatile molecular complexes, whose properties can be tuned by changing their functional groups and central metal atom. The electronic structure of magnesium Pc (MgPc) - structurally and…

Inducing magnetic moment in otherwise nonmagnetic two-dimensional semiconducting materials is the key first step to design spintronic materials. Here, we study the absorption of transition-metals on pristine and defected single-layer…

Mesoscale and Nanoscale Physics · Physics 2016-07-05 Rohit Babar , Mukul Kabir

Doping of the graphene lattice with transition metal atoms resulting in high magnetic anisotropy energy (MAE) is an important goal of materials research owing to its potential application in spintronics. In this article, by using…

Using first-principles calculations based on density functional theory and the nonequilibrium Green function formalism, we studied the spin transport through metal-phthalocyanine (MPc, M=Ni, Fe, Co, Mn, Cr) molecules connected to aurum…

Mesoscale and Nanoscale Physics · Physics 2017-02-27 Li Niu , Huan Wang , Lina Bai , Ximing Rong , Xiaojie Liu , Hua Li , Haitao Yin

Iron phthalocyanine (FePc) is a molecular semiconductor whose building blocks are one-dimensional ferromagnetic chains. We show that its optical and magnetic properties are controlled by the growth strategy, obtaining extremely high…

Strongly Correlated Electrons · Physics 2019-10-17 Zhenlin Wu , Peter Robaschik , Luke R. Fleet , Solveig Felton , Gabriel Aeppli , Sandrine Heutz

Epitaxial graphene/ferromagnetic metal (Gr/FM) heterostructures deposited onto heavy metals (HM) have been proposed for the realization of novel spintronic devices because of their perpendicular magnetic anisotropy and sizeable…

We present a systematic investigation of molecule-metal interactions for transition-metal phthalocyanines (TMPc, with TM = Fe, Co, Ni, Cu) adsorbed on Ag(100). Scanning tunneling spectroscopy and density functional theory provide insight…

Materials Science · Physics 2012-04-20 A. Mugarza , R. Robles , C. Krull , R. Korytar , N. Lorente , P. Gambardella

The revealing properties of transition metal (T)-doped graphene systems are investigated with the use of the first-principles method. The detailed calculations cover the bond length, position and height of adatoms, binding energy,…

Materials Science · Physics 2019-05-06 Ngoc Thanh Thuy Tran , Duy Khanh Nguyen , Shih-Yang Lin , Godfrey Gumbs , Ming Fa-Lin

The use of single molecules to design electronic devices is an extremely challenging and fundamentally different approach to further downsizing electronic circuits. Two-terminal molecular devices such as diodes were first predicted [1] and,…

Using first principles calculations in the framework of Density Functional Theory, we investigated the electronic and transport properties of metal(II)-phthalocyanine (M(II)Pc) systems, both in a single molecule configuration and in a…

Soft Condensed Matter · Physics 2009-11-13 Arrigo Calzolari , Andrea Ferretti , Marco Buongiorno Nardelli

Individual magnetic molecules are promising building blocks for quantum technologies because of their chemical tunability, nanoscale dimensions, and ability to self-assemble into ordered arrays. However, harnessing their properties in…

Graphene is hailed as an ideal material for spintronics due to weak intrinsic spin-orbit interaction that facilitates lateral spin transport and tunability of its electronic properties, including a possibility to induce magnetism in…

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