Related papers: Benzonitrile as a proxy for benzene in the cold IS…

This paper presents a modeling study of the oxidation of cyclohexane from low to intermediate temperature (650-1050 K), including the negative temperature coefficient (NTC) zone. A detailed kinetic mechanism has been developed using…

Cold, continuous, high flux beams of benzonitrile, fluorobenzine, and anisole have been created. Buffer-gas cooling with a cryogenic gas provides the cooling and slow forward beam velocities. The beam of benzonitrile was measured to have a…

Experimental results on the thermal desorption of benzene (C6H6) from amorphous silica (SiO2) are presented. The amorphous SiO2 substrate was imaged using atomic force microscopy (AFM), revealing a surface morphology reminiscent of that of…

Context. The gas kinetic temperature (TK) determines the physical and chemical evolution of the Interestellar Medium (ISM). However, obtaining reliable TK estimates usually requires expensive observations including the combination of…

The reactions of ground state atomic carbon, C(3P), are likely to be important in astrochemistry due to the high abundance levels of these atoms in the dense interstellar medium. Here we present a study of the gas-phase reaction between…

The study of single-crystal Raman spectra of a series of crystalline secondary amides (acetanilide, methacetin, phenacetine, orthorhombic and monoclinic polymorphs of paracetamol) as well as simple amides formanilide and benzanilide in the…

The reaction between atomic carbon in its ground electronic state, C(3P), and nitrous oxide, N2O, has been studied below room temperature due to its potential importance for astrochemistry, with both species considered to be present at high…

In this work, we present the results of our investigation into the chemistry of Z- and E-cyanomethanimine (HNCHCN), both of which are possible precursors to the nucleobase adenine. Ab initio quantum chemical calculations for a number of…

Cyanogen (NCCN) is the simplest member of the dicyanopolyynes group, and has been proposed as a major source of the CN radical observed in cometary atmospheres. Although not detected through its rotational spectrum in the cold interstellar…

In cold core of dark molecular clouds, where the UV radiation from external sources is strongly attenuated, cosmic rays can induce chemical reactions on the surface of ice-covered grains promoting the ejection of the processed material to…

Rate coefficients have been measured for the reaction of CH radicals with formaldehyde, CH$_{2}$O, over the temperature range 31 - 133 K using a pulsed Laval nozzle apparatus combined with pulsed laser photolysis and laser induced…

Amino acids are the essential keys that contribute to the study of the formation of life. The simplest amino acid, glycine (NH$_{2}$CH$_{2}$COOH), has been searched for a long time in the interstellar medium, but all surveys of glycine have…

Atomic oxygen in its first excited singlet state, O(1 D), is an important species in the photochemistry of several planetary atmospheres and has been predicted to be a potentially important reactive species on interstellar ices. Here, we…

The increasingly large number of complex organic molecules detected in the interstellar medium necessitates robust kinetic models that can be relied upon for investigating the involved chemical processes. Such models require rate constants…

Much of the interstellar medium in disk galaxies is in the form of neutral atomic hydrogen, H I. This gas can be in thermal equilibrium at relatively low temperatures, T < 300 K (the cold neutral medium, or CNM) or at temperatures somewhat…

We present the first localized detections of the cold neutral medium (CNM) in IC10, offering a rare view of dense atomic gas in a low-metallicity (0.27 solar metallicity) dwarf galaxy. As a low-metallicity starburst, IC10's interstellar…

Based on our comprehensive theoretical investigation and known experimental results for small boron clusters, we predict the existence of a novel aromatic inorganic molecule, B12H6. This molecule, which we refer to as borozene, has…

In the context of the search for gasoline surrogates for kinetic modeling purpose, this paper describes a new model for the low-temperature auto-ignition of n-heptane/iso-octane/hexene/toluene blends for the different linear isomers of…

Measuring the temperature and abundance patterns of clouds in the interstellar medium (ISM) provides an observational basis for models of the physical conditions within the clouds, which play an important role in studies of star and planet…

Isobutene ((CH$_3$)$_2$C=CH$_2$) is one of the four isomers of butene (C$_4$H$_8$). Given the detection of propene (CH$_3$CH=CH$_2$) toward TMC-1, and also in the warmer environment of the solar-type protostellar system IRAS 16293$-$2422,…