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The nonadiabatic quantum kinetic equations and Dirac-Heisenberg-Wigner formalism for Schwinger pair production in a spatially uniform and time-varying electric field with multiple components are derived and proven to be equivalent. The…

High Energy Physics - Theory · Physics 2025-03-05 Z. L. Li , R. Z. Jiang , Y. J. Li

The variational quantum eigensolver (VQE) algorithm, designed to calculate the energy of molecular ground states on near-term quantum computers, requires specification of symmetries that describe the system, e.g. spin state and number of…

Quantum Physics · Physics 2020-06-18 Gabriel Greene-Diniz , David Muñoz Ramo

Variational quantum eigensolver (VQE), which combines quantum systems with classical computational power, has been arisen as a promising candidate for near-term quantum computing applications. However, the experimental resources such as the…

The combined quantum electron-nuclear dynamics is often associated with the Born-Huang expansion of the molecular wave function and the appearance of nonadiabatic effects as a perturbation. On the other hand, native multicomponent…

Adiabatic quantum computing is a universal model for quantum computing whose implementation using a gate-based quantum computer requires depths that are unreachable in the early fault-tolerant era. To mitigate the limitations of near-term…

Quantum Physics · Physics 2024-10-18 Ioannis Kolotouros , Ioannis Petrongonas , Miloš Prokop , Petros Wallden

Quantum operations by utilizing the underlying geometric phases produced in physical systems are favoured due to its potential robustness. When a system in a non-degenerate eigenstate undergoes an adiabatically cyclic evolution dominated by…

Quantum Physics · Physics 2024-05-22 Hao-Long Zhang , Yi-Hao Kang , Fan Wu , Zhen-Biao Yang , Shi-Biao Zheng

This paper explores the potential contribution of quantum computing, specifically the Variational Quantum Eigensolver (VQE), into atmospheric physics research and application problems using as an example the Lorenz system, a paradigm of…

Quantum Physics · Physics 2024-01-09 V. Armaos , Athanassios A. Argiriou , Ioannis Kioutsioukis

We use the Variational Quantum Eigensolver (VQE) as implemented in the Qiskit software package to compute the ground state energy of small molecules derived from water, H$_2$O, and hydrogen cyanide, HCN. The work aims to benchmark…

Quantum Physics · Physics 2021-07-07 P. Lolur , M. Rahm , M. Skogh , L. García-Álvarez , G. Wendin

We propose an extension of the Variational Quantum Eigensolver (VQE) that leads to more accurate energy estimations and can be used to study excited states. The method is based on the introduction of a sequence of increasing penalties in…

Quantum Physics · Physics 2023-05-17 Rodolfo Carobene , Stefano Barison , Andrea Giachero

By exploiting the invariance of the molecular Hamiltonian by a unitary transformation of the orbitals it is possible to significantly shorter the depth of the variational circuit in the Variational Quantum Eigensolver (VQE) algorithm by…

Quantum Physics · Physics 2025-09-03 Leonardo Ratini , Chiara Capecci , Leonardo Guidoni

The variational quantum eigensolver (VQE) is a hybrid algorithm that has the potential to provide a quantum advantage in practical chemistry problems that are currently intractable on classical computers. VQE trains parameterized quantum…

Quantum Physics · Physics 2023-11-10 Quoc Hoan Tran , Shinji Kikuchi , Hirotaka Oshima

Quantum annealing (QA) is an algorithm to find the ground state of the problem Hamiltonian by using an adiabatic time evolution. An approach to evaluate adiabaticity in the experiment by applying spectroscopic techniques has recently been…

Quantum Physics · Physics 2024-08-20 Yuichiro Mori , Harunobu Hiratsuka , Yuichiro Matsuzaki

We propose an experimental method for evaluating the adiabatic condition during quantum annealing (QA), which will be essential for solving practical problems. The adiabatic condition consists of the transition matrix element and the energy…

Quantum Physics · Physics 2024-04-10 Yuichiro Mori , Shiro Kawabata , Yuichiro Matsuzaki

The geometric (Berry) phase of a two-level system in a dissipative environment is analyzed by using the second-quantized formulation, which provides a unified and gauge-invariant treatment of adiabatic and nonadiabatic phases and is thus…

Quantum Physics · Physics 2009-05-09 Kazuo Fujikawa , Ming-Guang Hu

The variational quantum eigensolver (VQE) algorithm combines the ability of quantum computers to efficiently compute expectation values with a classical optimization routine in order to approximate ground state energies of quantum systems.…

Variational Quantum Eigensolver (VQE) faces significant challenges due to hardware noise and the presence of barren plateaus and local traps in the optimization landscape. To mitigate the detrimental effects of these issues, we introduce a…

Quantum Physics · Physics 2025-12-09 Chayan Patra , Rahul Maitra

Within the present noisy intermediate-scale quantum-computing era, hybrid quantum-classical-processor algorithms have emerged as promising avenues for tackling electronic-structure eigenproblems. Among them, the so-called…

Quantum Physics · Physics 2026-05-21 Christophe Soule , Bruno Senjean , Benjamin Lasorne

Quantum chemistry applications on quantum computers currently rely heavily on the variational quantum eigensolver (VQE) algorithm. This hybrid quantum-classical algorithm aims at finding ground state solutions of molecular systems based on…

The quantum adiabatic theorem incorporating the Berry phase phenomenon can be characterized as a factorization of the time evolution operator into a path-dependent geometric factor, a usual dynamical factor and a non-adiabatic factor that…

Quantum Physics · Physics 2007-09-08 J. Chee

We propose a cost-efficient measurement scheme of the variational quantum eigensolver (VQE) for atomistic simulations of electronic structures based on a tight-binding (TB) theory. Leveraging the lattice geometry of a material domain, the…

Quantum Physics · Physics 2025-08-28 Dongkeun Lee , Hoon Ryu
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