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We report on the magnetic, thermodynamic, dielectric, and pyroelectric measurements on the hitherto unreported Fe${_4}$Ta${_2}$O${_9}$. This system is seen to exhibit a series of magnetic transitions, many of which are coupled to the…

Strongly Correlated Electrons · Physics 2018-07-18 Soumendra Nath Panja , Luminita Harnagea , Jitender Kumar , P. K. Mukharjee , R. Nath , A. K. Nigam , Sunil Nair

Strongly correlated materials with multiple order parameters provide unique insights into the fundamental interactions in condensed matter systems and present opportunities for innovative technological applications. A class of…

Co4Ta2O9 exhibits a three-dimensional magnetic lattice based on the buckled honeycomb motif. It shows unusual magnetoelectric effects, including the sign change and non-linearity. These effects cannot be understood without the detailed…

The honeycomb antiferromagnet Co4Nb2O9 is known to exhibit an interesting magnetoelectric effect that the electric polarization rotates at the twice speed in the opposite direction relative to the rotation of the external magnetic field…

Strongly Correlated Electrons · Physics 2020-04-22 Masashige Matsumoto , Mikito Koga

Through analysis of single crystal neutron diffraction data, we present the magnetic structures of magnetoelectric Co4Nb2O9 under various magnetic fields. In zero-field, neutron diffraction experiments below TN=27 K reveal that the Co2+…

Magnetoelectric systems offer potential for device applications exploiting coupled states between electric and magnetic properties. Among magnetoelectric materials, \FNO has attracted special attention because of its pronounced dielectric…

Magnetoelectric effects in honeycomb antiferromagnet Co4Nb2O9 are investigated on the basis of symmetry analyses of Co ions in trigonal P-3c1 space group. For each Co ion, the possible spin dependence is classified by C3 point-group…

Strongly Correlated Electrons · Physics 2020-07-16 Masashige Matsumoto , Mikito Koga

We report remarkable multiferroic effects in polycrystalline Bi2Fe4O9. High-resolution X-ray diffraction shows that this compound has orthorhombic structure. Magnetic measurements confirm an antiferromagnetic transition around 260 K. A…

Materials Science · Physics 2009-11-13 A. K. Singh , S. D. Kaushik , Brijesh Kumar , A. Venimadhav , P. K. Mishra , V. Siriguri , S. Patnaik

Low-dimensional magnetic systems based on honeycomb lattices provide a promising platform for exploring exotic quantum phenomena that emerge from the intricate interplay of competing spin, orbital, lattice, and dipolar degrees of freedom.…

Co4Nb2O9 (CNO) having {\alpha}-Al2O3 crystal structure with Co chains along c-direction shows gigantic magnetoelelctric coupling below antiferromagnetic ordering temperature of 27 K but above a spin flop field of 1.6 T. We have investigated…

Materials Science · Physics 2016-06-16 C. Dhanasekhar , S. K. Mishra , R. Rawat , A. K. Das , A. Venimadhav

Two-dimensional high-spin bipartite honeycomb networks, where anisotropy, competing exchange interactions, and spin fluctuations interplay, provide an alternative platform to test theoretical models that distinguish between classical and…

Strongly Correlated Electrons · Physics 2026-05-05 M. Barik , Q. Faure , F. Damay , J. P. Embs , S. Petit , P. Khuntia

We investigated the crystal structure, magnetic behavior, and optical properties of the layered honeycomb compound Na2Cu2TeO6. X-ray and neutron diffraction confirmed a monoclinic structure, with Cu ions arranged in dimerized chains.…

Strongly Correlated Electrons · Physics 2025-08-25 Shubham Patil , S. D. Kaushik

We report the magnetic structure and properties of a thiocyanate-based honeycomb magnet [Na(OH$_2$)$_3$]Mn(NCS)$_3$ which crystallises in the unusual low-symmetry trigonal space group $P\overline{3}$. Magnetic measurements on powder samples…

We report temperature dependent magnetization and neutron diffraction measurements on the corundum related magnetoelectric antiferromagnet Mn$_{4}$Ta$_{2}$O$_{9}$. Measurements performed on a single crystalline specimen reveal that the…

Strongly Correlated Electrons · Physics 2021-01-20 Soumendra Nath Panja , Pascal Manuel , Sunil Nair

The development of magnetoelectric materials requires chemical design strategies that integrate structural polarity with magnetic lattices capable of supporting competing spin interactions. Here, we demonstrate such an approach in the…

Materials Science · Physics 2026-03-17 Faith O. Adeyemi , Xudong Huai , Mohamed Kandil , Pradip Karki , Wencan Jin , Thao T. Tran

Ni$_{2}$Mo$_{3}$O$_{8}$ is a pyroelectric honeycomb antiferromagnet exhibiting peculiar changes of its electric polarization at magnetic transitions. Ni$_{2}$Mo$_{3}$O$_{8}$ stands out from the isostructural magnetic compounds, showing an…

We have carried out high magnetic field studies of single-crystalline Li$_2$MnO$_3$, a honeycomb lattice antiferromagnet. Its magnetic phase diagram was mapped out using magnetization measurements at applied fields up to 35 T. Our results…

Strongly Correlated Electrons · Physics 2015-06-22 K. Balamurugan , Sang-Hyun Lee , Jun-Sung Kim , Jong-Mok Ok , Youn-Jung Jo , Young-Mi Song , Shin-Ae Kim , E. S. Choi , Manh Duc Le , Je-Geun Park

Single crystals of a honeycomb lattice antiferromagnet, Tb$_2$Ir$_3$Ga$_9$ were synthesized, and the physical properties have been studied. From magnetometry, a long-range antiferromagnetic ordering at $\approx$12.5 K with highly…

Mesoscale and Nanoscale Physics · Physics 2019-11-27 Mojammel A. Khan , Qiang Zhang , Jin-Ke Bao , Randy S. Fishman , Antia S. Botana , Y. Choi , G. Fabbris , D. Haskel , John Singleton , John F. Mitchell

Synthesis and extensive structural, pyroelectric, magnetic, dielectric and magneto-electric characterizations are reported for polycrystalline Co4Nb2O9 towards unraveling the multiferroic state especially in reference to the magnetic spin…

Materials Science · Physics 2016-12-07 P. Srivastava , S. Chaudhary , J. Saha , S. Patnaik

Evidence for multiple magnetic transitions and unconventional spin exchange interactions in the ilmenite insulator MnTiO3 is provided via neutron scattering. On cooling, while G-type antiferromagnetic (AFM) order sets in first at 63 K with…

Strongly Correlated Electrons · Physics 2026-03-09 Srimal Rathnayaka , Luke Daemen , Despina Louca
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