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Variational Quantum Eigensolvers (VQEs) represent a promising approach to computing molecular ground states and energies on modern quantum computers. These approaches use a classical computer to optimize the parameters of a trial wave…

We present a novel approach for efficient preparation of electronic ground states, leveraging the optimizer ExcitationSolve [J\"ager et al., Comm. Phys. (2025)] and established variational quantum eigensolver-based operator selection…

Quantum Physics · Physics 2026-02-13 Max Haas , Thierry N. Kaldenbach , Thomas Hammerschmidt , Daniel Barragan-Yani

Subradiant excited states in finite chains of two-level quantum emitters coupled to a one-dimensional reservoir are a resource for superior photon storage and controlled photon manipulation. Typically, states storing multiple excitations…

The accurate computation of properties of large molecular systems is classically infeasible and is one of the applications in which it is hoped that quantum computers will demonstrate an advantage over classical devices. However, due to the…

Quantum Physics · Physics 2024-10-15 Michael A. Jones , Harish J. Vallury , Lloyd C. L. Hollenberg

This work introduces an approach rooted in quantum thermodynamics to enhance sampling efficiency in quantum machine learning (QML). We propose conceptualizing quantum supervised learning as a thermodynamic cooling process. Building on this…

Quantum Physics · Physics 2025-01-07 Nayeli A. Rodríguez-Briones , Daniel K. Park

The energies of molecular excited states arise as solutions to the electronic Schr\"{o}dinger equation and are often compared to experiment. At the same time, nuclear quantum motion is known to be important and to induce a red-shift of…

Chemical Physics · Physics 2021-06-28 Timothy J. H. Hele , Bartomeu Monserrat , Antonios M. Alvertis

Quantum computing holds immense promise for simulating quantum systems, a critical task for advancing our understanding of complex quantum phenomena. One of the primary goals in this domain is to accurately approximate the ground state of…

Quantum Physics · Physics 2024-11-28 Thilo R. Müller , Manuel Geiger , Christian B. Mendl

Data-driven techniques are increasingly used to replace electronic-structure calculations of matter. In this context, a relevant question is whether machine learning (ML) should be applied directly to predict the desired properties or be…

Quantum computing leverages the quantum resources of superposition and entanglement to efficiently solve computational problems considered intractable for classical computers. Examples include calculating molecular and nuclear structure,…

Recently developed neural network-based wave function methods are capable of achieving state-of-the-art results for finding the ground state in real space. In this work, a neural network-based method is used to compute excited states. We…

Computational Physics · Physics 2021-10-04 Yimeng Min

We present an efficient quantum algorithm for preparing a pure state on a quantum computer, where the quantum state corresponds to that of a molecular system with a given number $m$ of electrons occupying a given number $n$ of spin…

Quantum Physics · Physics 2009-05-01 Hefeng Wang , S. Ashhab , Franco Nori

A continuously monitored quantum system prepared in an excited state will decay to its ground state with an abrupt jump. The jump occurs stochastically on a characteristic time scale T1, the lifetime of the excited state. These quantum…

Mesoscale and Nanoscale Physics · Physics 2011-03-15 R. Vijay , D. H. Slichter , I. Siddiqi

The ground and excited state calculations at key geometries, such as the Frank-Condon (FC) and the conical intersection (CI) geometries, are essential for understanding photophysical properties. To compute these geometries on noisy…

Quantum Physics · Physics 2023-01-02 Shigeki Gocho , Hajime Nakamura , Shu Kanno , Qi Gao , Takao Kobayashi , Taichi Inagaki , Miho Hatanaka

NISQ era devices suffer from a number of challenges like limited qubit connectivity, short coherence times and sizable gate error rates. Thus, quantum algorithms are desired that require shallow circuit depths and low qubit counts to take…

We present computational chemistry data for small molecules ($CO$, $HCl$, $F_2$, $NH_4^+$, $CH_4$, $NH_{3}$, $H_3O^+$, $H{_2}O$, $BeH_{2}$, $LiH$, $OH^-$, $HF$, $HeH^+$, $H_2$), obtained by implementing the Unitary Coupled Cluster method…

Quantum Physics · Physics 2019-07-02 V. Armaos , Dimitrios A. Badounas , Paraskevas Deligiannis

Quantum machine learning is a rapidly advancing discipline that leverages the features of quantum mechanics to enhance the performance of computational tasks. Quantum reservoir processing, which allows efficient optimization of a single…

Quantum reservoir computing is a machine learning framework that offers ease of training compared to other quantum neural networks, as it does not rely on gradient-based optimization. Learning is performed in a single step on the output…

Quantum Physics · Physics 2026-02-04 Baptiste Carles , Julien Dudas , Léo Balembois , Julie Grollier , Danijela Marković

Various methods have been developed for the quantum computation of the ground and excited states of physical and chemical systems, but many of them require either large numbers of ancilla qubits or high-dimensional optimization. The quantum…

Quantum Physics · Physics 2019-12-16 Kübra Yeter-Aydeniz , Raphael C. Pooser , George Siopsis

Quantum state preparation is an important class of quantum algorithms that is employed as a black-box subroutine in many algorithms, or used by itself to generate arbitrary probability distributions. We present a novel state preparation…

Quantum Physics · Physics 2020-06-02 Yutaro Iiyama

Quantum chemistry is envisioned as an early and disruptive application for quantum computers. Yet, closer scrutiny of the proposed algorithms shows that there are considerable difficulties along the way. Here, we propose two criteria for…

Quantum Physics · Physics 2026-04-09 Thibaud Louvet , Thomas Ayral , Xavier Waintal