Related papers: Computational molecular field theory for nematic l…
We study a nanosecond electro-optic response of a nematic liquid crystal in a geometry where an applied electric field $\textbf{E}$ modifies the tensor order parameter but does not change the orientation of the optic axis (director…
Nematic liquid crystals possess three different phases: isotropic, uniaxial, and biaxial. The ground state of most nematics is either isotropic or uniaxial, depending on the external temperature. Nevertheless, biaxial domains have been…
This chapter is about the modeling of nematic liquid crystals (LCs) and their numerical simulation. We begin with an overview of the basic physics of LCs and discuss some of their many applications. Next, we delve into the modeling…
Using a generalized order parameter gradient expansion within density functional theory, we derive a phase-field-crystal model for liquid crystals composed by apolar particles in three spatial dimensions. Both the translational density and…
Topological defects are an essential part of the structure and dynamics of all liquid crystals, and they are particularly important in experiments and simulations on active liquid crystals. In a recent paper, Vromans and Giomi [Soft Matter,…
Liquid crystals in two dimensions undergo a first-order isotropic-to-quasi-nematic transition, provided the particle interactions are sufficiently ``sharp and narrow''. This implies phase coexistence between isotropic and quasi-nematic…
We study the spontaneous breaking of rotational symmetry in the helical surface state of three-dimensional topological insulators due to strong electron-electron interactions, focusing on time-reversal invariant nematic order. Owing to the…
Uniaxial nematic liquid crystals whose molecular orientation is subjected to a tangential anchoring on a curved surface offer a non trivial interplay between the geometry and the topology of the surface and the orientational degree of…
We mathematically model Smectic-A (SmA) phases with a modified Landau-de Gennes (mLdG) model. The orientational order of the SmA phase is described by a tensor-order parameter $\mathbf{Q}$, and the positional order is described by a real…
We study the symmetry and the spatial uniformity of orientational order of the biaxial nematic phase in the light of recent experimental observations of phase biaxiality in thermotropic bent-core and calamitic-tetramer nematics. We present…
We propose a continuum model to describe the molecular alignment in thin nematic shells. By contrast with previous accounts, the two-dimensional free energy, aimed at describing the physics of thin films of nematics deposited on curved…
We propose a simple surface potential favoring the planar degenerate anchoring of nematic liquid crystals, i.e., the tendency of the molecules to align parallel to one another along any direction parallel to the surface. We show that, at…
Modeling liquid crystal elastomers (LCEs) at the molecular level is crucial for the predictable design of energy-conversion and stimuli-responsive materials. Here, we develop a self-consistent field theory for LCEs which captures the…
We propose a novel approach to the solution of nematic Liquid Crystal models based on the derivation of a system of nonlinear wave equations for order parameters such that the occurrence of uniaxial and biaxial phase transitions can be…
We present a generalized approach to compute the shape and internal structure of two-dimensional nematic domains. By using conformal mappings, we are able to compute the director field for a given domain shape that we choose from a rich…
The optical birefringence of rod-like nematogens (7CB, 8CB), imbibed in parallel silica channels with 10 nm diameter and 300 micrometer length, is measured and compared to the thermotropic bulk behavior. The orientational order of the…
We consider a four-elastic-constant Landau-de Gennes energy characterizing nematic liquid crystal configurations described using the $Q$-tensor formalism. The energy contains a cubic term and is unbounded from below. We study dynamical…
The physics of nematic liquid crystals has been subject of intensive research since the late 19th century. However, because of the limitations of chemistry the focus has been centered around uni- and biaxial nematics associated with…
A rigorous theory of liquid-crystal transitions is developed starting from the Liouville equation. The starting point is an all-atom description and a set of order parameter field variables that are shown to evolve slowly via Newton's…
Liquid crystals consisting of biaxial particles can exhibit a much richer phase behavior than their uniaxial counterparts. Usually, one has to rely on simulation results to understand the phase diagram of these systems, since very few…