Related papers: Separate silicate and carbonaceous solids formed f…
Ice chemistry in the dense, cold interstellar medium (ISM) is probably responsible for the formation of interstellar complex organic molecules (COMs). Recent laboratory experiments performed at T=4 K have shown that irradiation of CO:N2 ice…
Refractory organic compounds formed in molecular clouds are among the building blocks of the solar system objects and could be the precursors of organic matter found in primitive meteorites and cometary materials. However, little is known…
The abundance of both amorphous and crystalline silicates in very small grains is limited by the fact that the 10 micron silicate emission feature is not detected in the diffuse ISM. On the basis of the observed IR emission spectrum for the…
Syn-glycolamide, a glycine isomer, has recently been detected in the G+0.693-0.027 molecular cloud. Investigations on its formation in the interstellar medium could offer insights into synthetic routes leading to glycine in prebiotic…
Astronomical observations and analysis of stardust isolated from meteorites have revealed a highly diverse interstellar and circumstellar grain inventory, including a wide range of amorphous materials and crystalline compounds (silicates…
The detection of the amino acid glycine and its amine precursor methylamine on the comet 67P/Churyumov-Gerasimenko by the Rosetta mission provides strong evidence for a cosmic origin of prebiotics on Earth. How and when such complex organic…
Glycoaldehyde, ethylene glycol, and methyl formate are complex organic molecules that have been observed in dark molecular clouds. Because there is no efficient gas-phase route to produce these species, it is expected that a low-temperature…
A set of 45 dust envelopes of carbon stars has been modeled. Among them, 34 were selected according to their dust envelope class (as suggested by Sloan, Little-Marenin & Price, 1998) and 11 are extreme carbon stars. The models were…
Major components of ices on interstellar grains in molecular clouds - water and carbon oxides - occur at various optical depths. This implies that selective desorption mechanisms are at work. An astrochemical model of a contracting low-mass…
ISOCAM allowed the observation of diffuse interstellar regions where the transition from atomic to molecular gas takes place. In this contribution we report on spectacular variations of small dust grains abundance in such regions observed…
We calculate and discuss the chemical evolution of the isotopic silicon abundances in the interstellar medium at distances and times appropriate to the birth of the solar system. This has several objectives, some of which are related to…
Icy interstellar dust grains are a source of complex organic molecule (COM) production, although their formation mechanisms are debated. Laboratory experiments show that atomic C deposited onto interstellar ice analogs can react with…
The interstellar medium (ISM) seems to have a significant surplus of oxygen which was dubbed as the "O crisis": independent of the adopted interstellar reference abundance, the total number of O atoms depleted from the gas phase far exceeds…
An outstanding question of astrobiology is the link between the chemical composition of planets, comets, and other solar system bodies and the molecules formed in the interstellar medium. Understanding the chemical and physical evolution of…
Context. Excess microwave emission, commonly known as anomalous microwave emission (AME), is now routinely detected in the Milky Way. Although its link with the rotation of interstellar (carbonaceous) nano-grains seems to be relatively well…
The disk midplane temperature is potentially affected by the dust traps/rings. The dust depletion beyond the water snowline will cast a shadow. In this study, we adopt a detailed gas-grain chemical reaction network, and investigate the…
Complex Organic Molecules (COMs) have been detected in the interstellar medium (ISM). However, it is not clear whether their synthesis occurs on the icy surfaces of interstellar grains or via a series of gas-phase reactions. As a test case…
We investigate the formation of the recently detected HNSO molecule using quantum chemical calculations on ices and astrochemical models in tandem. Our results indicate that HNSO is efficiently produced on grain surfaces through reactions…
In regions where stars form, variations in density and temperature can cause gas to freeze-out onto dust grains forming ice mantles, which influences the chemical composition of a cloud. The aim of this paper is to understand in detail the…
Context. We investigate the binding energies of atoms to interstellar dust particles, which play a key role in their growth and evolution, as well as for the chemical reactions on their surfaces. Aims. We aim to compute the binding energies…