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The double ionization potential (DIP) equation-of-motion (EOM) coupled-cluster (CC) method with a full treatment of 4-hole-2-particle (4$h$-2$p$) correlations and triply excited clusters, abbreviated as DIP-EOMCCSDT(4$h$-2$p$), and its…

Chemical Physics · Physics 2025-02-12 Karthik Gururangan , Achintya Kumar Dutta , Piotr Piecuch

We report our successful implementation of the full fledged relativistic equation of motion coupled cluster (EOMCC) method. This method is employed to compute the principal ionization potentials (IPs) of closed-shell rare gas atoms, He-like…

Atomic Physics · Physics 2014-04-24 Himadri Pathak , B. K. Sahoo , B. P. Das , Nayana Vaval , Sourav Pal

We employ two-photon spectroscopy to study the vibrational states of the triplet ground state potential ($a^3\Sigma^+$) of the $^{23}$Na$^{6}$Li molecule. Pairs of Na and Li atoms in an ultracold mixture are photoassociated into an excited…

The spectroscopic properties of Li atom and Li-like Ca and Ti ions in the plasma environment are investigated using a relativistic coupled-cluster (RCC) method. Assuming the plasma is of low density and very hot, we consider the Debye model…

Atomic Physics · Physics 2015-06-18 Madhulita Das , B. K. Sahoo , Sourav Pal

Utilizing a simplified quantum model approach, the low-energy inelastic collision processes between yttrium atoms (ions) and hydrogen atoms have been studied. Rate coefficients corresponding to the mutual neutralization, ion-pair formation,…

Solar and Stellar Astrophysics · Physics 2023-08-16 Yu Wang , Sofya Alexeeva , Feng Wang , Ling Liu , Yong Wu , JianGuo Wang , Gang Zhao , Svetlana A. Yakovleva , Andrey K. Belyaev

Echo-based spectroscopy of the superhyperfine interaction of an electronic spin with nuclear spins in its surroundings enables detailed insights into the microscopic magnetic environment of spins in solids. Still, it is an outstanding…

Studies of ion-molecule reactions at low temperatures are difficult because stray electric fields in the reaction volume affect the kinetic energy of charged reaction partners. We describe a new experimental approach to study ion-molecule…

Only a few weakly-bound complexes containing the O2 molecule have been characterized by high resolution spectroscopy, no doubt due to the complications added by the oxygen molecule's unpaired electron spin. Here we report an extensive…

Atomic and Molecular Clusters · Physics 2018-07-04 A. J. Barclay , A. R. W. McKellar , N. Moazzen-Ahmadi , Richard Dawes , Xiao-Gang Wang , Tucker Carrington

We perform two-photon photoassociation spectroscopy of the heteronuclear CsYb molecule to measure the binding energies of near-threshold vibrational levels of the $X~^{2}\Sigma_{1/2}^{+}$ molecular ground state. We report results for…

We demonstrate precision laser spectroscopy of a trapped $^{173}$Yb$^+$ ion that is not directly laser cooled by coupling it to ultracold atoms. The atomic bath continuously cools the internal degrees of freedom of the ion to its hyperfine…

Atomic Physics · Physics 2026-03-24 Egor Kovlakov , Rene Gerritsma

We present a neutron triple-axis and resonant spin-echo spectroscopy study of the spin correlations in untwinned YBCO crystals with x= 0.3, 0.35, and 0.45 as a function of temperature and magnetic field. As the temperature T approaches 0,…

Strongly Correlated Electrons · Physics 2015-05-19 D. Haug , V. Hinkov , Y. Sidis , P. Bourges , N. B. Christensen , A. Ivanov , T. Keller , C. T. Lin , B. Keimer

High-spin rotational bands in rare-earth Er ($Z=68$), Tm ($Z=69$) and Yb ($Z=70$) isotopes are investigated by three different nuclear models. These are (i) the cranked relativistic Hartree-Bogoliubov (CRHB) approach with approximate…

Nuclear Theory · Physics 2020-05-06 Zhen-Hua Zhang , Miao Huang , A. V. Afanasjev

The spectral properties of a multilevel atomic system interacting with multiple electromagnetic fields, a modified inverted-Y system, have been theoretically investigated. In this study, a numerical matrix propagation method has been…

Atomic Physics · Physics 2019-05-22 Charu Mishra , A. Chakraborty , S. R. Mishra

We calculate accurate potential energy curves for a ground-state He$^+$ ion interacting with a He atom in the lowest-energy metastable $^3\!S$ electronic state. We employ the full configuration interaction method, equivalent to exact…

Atomic Physics · Physics 2023-11-30 Jacek Gȩbala , Michał Przybytek , Marcin Gronowski , Michał Tomza

Spectroscopic techniques are very essential tools in studying electronic structures, spectroscopic constants and energetic properties of diatomic molecules. These techniques are also required for parametrization of new method based on…

Chemical Physics · Physics 2015-04-15 Babatunde J. Falaye , Sameer M. Ikhdair , Majid Hamzavi

We use tunneling spectroscopy to study the evolution of few-electron spin states in parallel InAs nanowire double quantum dots (QDs) as a function of level detuning and applied magnetic field. Compared to the much more studied serial…

Mesoscale and Nanoscale Physics · Physics 2018-12-19 Claes Thelander , Malin Nilsson , Florinda Viñas Boström , Adam Burke , Sebastian Lehmann , Kimberly A. Dick , Martin Leijnse

Intermediate-mass young stellar objects (YSOs) provide a link to understand how feedback from shocks and UV radiation scales from low to high-mass star forming regions. Aims: Our aim is to analyze excitation of CO and H$_2$O in…

Solar and Stellar Astrophysics · Physics 2015-05-27 M. Matuszak , A. Karska , L. E. Kristensen , G. J. Herczeg , L. Tychoniec , T. van Kempen , A. Fuente

We study theoretically interaction potentials and low energy collisions between different alkali atoms and alkali ions. Specifically, we consider systems like X + Y$^{+}$, where X(Y$^{+})$ is either Li(Cs$^+$) or Cs(Li$^+$), Na(Cs$^+$) or…

Atomic Physics · Physics 2016-09-13 Arpita Rakshit , Chedli Ghanmi , Hamid Berriche , Bimalendu Deb

A variational model for the infra-red spectrum of VO is presented which aims to accurately predict the hyperfine structure within the VO $\mathrm{X}\,^4\Sigma^-$ electronic ground state. To give the correct electron spin splitting of the…

Chemical Physics · Physics 2022-10-25 Qianwei Qu , Sergei N. Yurchenko , Jonathan Tennyson

We present a near-linear scaling formulation of the explicitly-correlated coupled-cluster singles and doubles with perturbative triples method (CCSD(T)$_{\overline{\text{F12}}}$) for high-spin states of open-shell species. The approach is…

Chemical Physics · Physics 2024-07-30 Ashutosh Kumar , Frank Neese , Edward F. Valeev