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Combined relativistic configuration interaction and many-body perturbation calculations are performed for the 359 fine-structure levels of the $2s^2 2p^3$, $2s 2p^4$, $2p^5$, $2s^2 2p^2 3l$, $2s 2p^3 3l$, $2p^4 3l$, and $2s^2 2p^2 4l$…

Atomic Physics · Physics 2016-03-23 K. Wang , R. Si , W. Dang , P. Jönsson , X. L. Guo , S. Li , Z. B. Chen , H. Zhang , F. Y. Long , H. T. Liu , D. F. Li , R. Hutton , C. Y. Chen , J. Yan

To enrich and enhance the diversity of the \textsc{quest} database of highly-accurate excitation energies [\href{https://doi.org/10.1002/wcms.1517}{V\'eril \textit{et al.}, \textit{WIREs Comput.~Mol.~Sci.}~\textbf{11}, e1517 (2021)}], we…

No lines have been observed for transitions between the doublet and quartet levels of B I. Consequently, energy levels based on observation for the latter are obtained through extrapolation of wavelengths along the iso-electronic sequence…

We present the most accurate up-to-date theoretical values of the {2p_{1/2}}-{2s} and {2p_{3/2}}-{2s} transition energies and the ground-state hyperfine splitting in ${\rm Sc}^{18+}$. All two- and three-electron contributions to the energy…

The fully relativistic multiconfiguration Dirac--Hartree--Fock method is used to compute excitation energies and lifetimes for the 143 lowest states of the $3s^23p^3$, $3s3p^4$, $3s^23p^23d$, $3s3p^33d$, $3p^5$, $3s^23p3d^2$ configurations…

Atomic Physics · Physics 2018-04-11 K. Wang , P. Jönsson , G. Gaigalas , L. Radžiūtė , P. Rynkun , G. Del Zanna , C. Y. Chen

The \textit{ab initio} approach is used to evaluate the excitation energies of the $2s2p \, ^{2S+1}P_J$ states from the ground state as well as the $2s2p \, ^3P_1 \rightarrow 2s2p \, ^3P_0$ and $2s2p \, ^3P_2 \rightarrow 2s2p \, ^3P_1$…

Atomic Physics · Physics 2024-11-05 A. V. Malyshev , Y. S. Kozhedub , V. M. Shabaev , I. I. Tupitsyn

Accurate atomic data are essential for opacity calculations and for abundance analyses of the Sun and other stars. The aim of this work is to provide accurate and extensive results of energy levels and transition data for C I - IV. The…

Atomic Physics · Physics 2021-02-03 W. Li , A. M. Amarsi , A. Papoulia , J. Ekman , P. Jönsson

The ground and some excited states of the Li atom in external uniform magnetic fields are calculated by means of our 2D mesh Hartree-Fock method for field strengths ranging from zero up to 2.35 10^8 T. With increasing field strength the…

Atomic Physics · Physics 2009-10-31 M. V. Ivanov , P. Schmelcher

Molecular ions formed in cold hybrid ion-atom experiments may find interesting applications ranging from precision measurements to controlled chemical reactions. Here, we investigate electronic structure of the Sr$_2^+$ molecular ion, which…

Atomic Physics · Physics 2020-06-17 Michał Śmiałkowski , Tatiana Korona , Michał Tomza

We investigate the intermolecular interactions between laser-cooled CaF and Ca, in their ground and excited electronic states, aiming to understand atom-exchange reaction pathways. Using state-of-the-art \textit{ab initio} quantum chemistry…

Atomic Physics · Physics 2025-10-28 Dibyendu Sardar , John L. Bohn

Employing two state-of-the-art methods, multiconfiguration Dirac--Hartree--Fock and second-order many-body perturbation theory, the excitation energies and lifetimes for the lowest 200 states of the $2s^2 2p^4$, $2s 2p^5$, $2p^6$, $2s^2…

Atomic Physics · Physics 2017-04-19 K. Wang , P. Jönsson , J. Ekman , G. Gaigalas , M. R. Godefroid , R. Si , Z. B. Chen , S. Li , C. Y. Chen , J. Yan

Bilodeau and Haugan [1], using Infrared laser photodetachment spectroscopy, measured the binding energies (BEs) of the ground state (4Fe9/2) and the excited state (4Fe7/2) of the Os^- ion to be 1.07780(12) eV and 0.553(3) eV, respectively.…

Atomic Physics · Physics 2012-08-09 Zineb Felfli , Filmon Kiros , Kelvin Suggs , Alfred Z. Msezane

We report calculations of energy levels, radiative rates and electron impact excitation cross sections and rates for transitions in He-like Ga XXX, Ge XXXI, As XXXII, Se XXXIII and Br XXXIV. The {\sc grasp} (general-purpose relativistic…

Atomic Physics · Physics 2015-06-15 Kanti M Aggarwal , Francis P Keenan

Results for energy levels, radiative rates and electron impact excitation (effective) collision strengths for transitions in Be-like Cl XIV, K XVI and Ge XXIX are reported. For the calculations of energy levels and radiative rates the…

Solar and Stellar Astrophysics · Physics 2015-06-22 K. M. Aggarwal , F. P. Keenan

Energy levels and radiative rates for transitions in five Br-like ions (Sr IV, Y V, Zr VI, Nb VII and Mo VIII) are calculated with the general-purpose relativistic atomic structure package ({\sc grasp}). Extensive configuration interaction…

Atomic Physics · Physics 2015-06-23 K. M. Aggarwal , F. P. Keenan

The ab initio quasirelativistic Hartree-Fock method developed specifically for the calculation of spectroscopic parameters of heavy atoms and highly charged ions was used to derive spectral data for the multicharged tungsten ion W$^{35+}$.…

Atomic Physics · Physics 2015-04-20 P. Bogdanovich , R. Kisielius

Fourier transform spectra of Nd Penning and hollow cathode discharge lamps were recorded within the region 32,500-54,000 cm$^{-1}$ (3077-1852 {\AA}) and grating spectra of Nd vacuum sliding sparks were recorded within the regions 820-1159…

Atomic Physics · Physics 2024-12-04 M. Ding , A. N. Ryabtsev , E. Y. Kononov , T. Ryabchikova , J. C. Pickering

We have performed large-scale configuration interaction (CI) calculations using CIV3for the lowest (in energy) 155 fine-structure levels of aluminum-like germanium ion. We have calculated the energy levels, lifetimes, oscillator strengths,…

Atomic Physics · Physics 2015-08-17 Waleed Othman Younis , Alan Hibbert

We report calculations of energy levels, radiative rates and electron impact excitation cross sections and rates for transitions in Be-like Ti XIX. The GRASP (General-purpose Relativistic Atomic Structure Package) is adopted for calculating…

Atomic Physics · Physics 2015-06-11 Km Aggarwal , Fp Keenan

We present systematic calculations of energy levels of the $1s^22l$ and $1s2l2l'$ states of ions along the lithium isoelectronic sequence from carbon till chlorine. The calculations are performed by using the…

Atomic Physics · Physics 2017-12-29 V. A. Yerokhin , A. Surzhykov , A. Müller