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Lead-free halide double perovskites are promising stable and non-toxic alternatives to methylammonium lead iodide in the field of photovoltaics. In this context, the most commonly used double perovskite is Cs$_2$AgBiBr$_6$, due to its…

Materials Science · Physics 2022-08-29 Elisabetta Landini , Karsten Reuter , Harald Oberhofer

Solid solutions of perovskite oxides (KNbO3)1-x+(La2NiMnO6)x (x=0, 0.1, 0.2 and 0.3) with a variation of band gap (1.33-3.6 eV) have been introduced as a promising photovoltaic absorber. The structural characterization of the prepared…

Materials Science · Physics 2018-09-21 Md S. Sheikh , A. Dutta , T. K. Bhowmik , S. K. Ghosh , S. K. Rout , T. P. Sinha

Double perovskite halides are emerging as promising materials for a wide range of applications, particularly in renewable energy technologies such as solar cell devices, thereby contributing to addressing global energy demands. In this…

Materials Science · Physics 2026-04-10 Huda A. Alburaih , Sikander Azam , N. A. Noor , A. Laref , Sohail Mumtaz

In the search for stable lead (Pb) free perovskites, Vacancy ordered double perovskite (VODP), A$_2$BX$_6$ has emerged as a promising class of materials for solar harvesting owing to their nontoxicity, better stability, and unique…

Materials Science · Physics 2023-09-13 Supriti Ghorui , Jiban Kangsabanik , M. Aslam , Aftab Alam

Hybrid Lead halide perovskites, despite having unique intrinsic properties with the possibility of flexible synthesis and device fabrication, still suffer from two fundamental issues, i.e. stability in external environment and toxicity due…

Materials Science · Physics 2018-05-16 Jiban Kangsabanik , Vipinraj Sugathan , Anuradha Yadav , Aswani Yella , Aftab Alam

The vacancy-ordered double perovskites (VODP) are emerging materials for the renewable energy because of their extraordinary stability. In the present work, we have addressed the structural, electronic and optical properties of the…

Computational Physics · Physics 2023-02-27 M. Talebi , A. Mokhtari

Halide perovskites constitute a chemically-diverse class of crystals with great promise as photovoltaic absorber materials, featuring band gaps between about 1 and 3.5 eV depending on composition. Their diversity calls for a general…

Materials Science · Physics 2019-10-23 Linn Leppert , Tonatiuh Rangel , Jeffrey B. Neaton

Density functional theory screening of the hybrid double perovskites (MA)2BIBiX6 (BI=K,Cu,Ag,Tl; X=Cl,Br,I) shows that systems with band gaps similar to those of the MAPbX3 lead compounds can be expected for BI=Cu,Ag,Tl. Motivated by these…

Materials Science · Physics 2016-11-10 Zeyu Deng , Fengxia Wei , Shijing Sun , Gregor Kieslich , Anthony K. Cheetham , Paul D. Bristowe

This work is aimed to study mixed-cation (hybrid methyl ammonium plus inorganic cations) halide perovskites using first principles Density Functional Theory (DFT) formalism in order to find their potential applications in perovskite based…

Materials Science · Physics 2021-10-19 Manaswita Kar

Using density-functional theory calculations, we analyze the optical absorption properties of lead (Pb)-free metal halide perovskites (AB$^{2+}$X$_3$) and double perovskites (AB$^+$B$^{3+}$X$_6$) (A = Cs or monovalent organic ion, B$^{2+}$…

Materials Science · Physics 2017-06-19 Weiwei Meng , Xiaoming Wang , Zewen Xiao , Jianbo Wang , David Mitzi , Yanfa Yan

Inorganic metal-halide cubic perovskite semiconductors have become more popular in industrial applications of photovoltaic and optoelectronic devices. Among various perovskites, lead-free materials are currently most explored due to their…

Materials Science · Physics 2022-03-17 Nazmul Hasan , Md Arifuzzaman , Alamgir Kabir

A$_2$BB$^\prime$X$_6$ halide double perovskites based on bismuth and silver have recently been proposed as potential environmentally-friendly alternatives to lead-based hybrid halide perovskites. In particular, Cs$_2$BiAgX$_6$ (X = Cl, Br)…

Recently, direct bandgap double perovskites are becoming more popular among photovoltaic research community owing to their potential to address issues of lead (Pb) toxicity and structural instability inherent in lead halide (simple)…

Materials Science · Physics 2021-01-13 I. B. Ogunniranye , T. Atsue , O. E. Oyewande

Single crystals of Cs2BiAgBr6 lead-free perovskite were grown by crystallization from supersaturated solution. According to characterization by XRD and EBSD methods the double perovskite single crystal are of the cubic Fm-3m symmetry with…

Recently, replacing or mixing organic molecules in the hybrid halide perovskites with the inorganic Cs or Rb cations has been reported to increase the material stability with the comparable solar cell performance. In this work, we…

Materials Science · Physics 2018-09-19 Un-Gi Jong , Chol-Jun Yu , Yun-Sim Kim , Yun-Hyok Kye , Chol-Ho Kim

Structure, optical and electronic properties of predicted stables Perovskites ABX3 are calculated using DFT approach. The modified Becke-Johnson potential is also used to investigate electrical and optical properties. The density of states…

Materials Science · Physics 2022-05-24 Kashif Murad , G. Murtaza , Muhammad Noman , Shamim Khan

The outstanding optoelectronics and photovoltaic properties of metal halide perovskites, including high carrier motilities, low carrier recombination rates, and the tunable spectral absorption range are attributed to the unique electronic…

Materials Science · Physics 2020-08-14 Shuxia Tao , Xi Cao , Peter Bobbert

Halide double perovskite semiconductors such as Cs2AgBiBr6 are widely investigated as a more stable, less toxic alternative to lead-halide perovskites in light conversion applications including photovoltaics and photoredox catalysis.…

Despite the exceeding 23\% photovoltaic efficiency achieved in organic-inorganic hybrid perovskite solar cells obtaining, the stable materials with desirable band gap are rare and are highly desired. With the aid of first-principles…

Applied Physics · Physics 2020-02-21 Qiaoqiao Li , Liujiang Zhou , Yanfeng Ge , Yulu Ren , Jiangshan Zhao , Wenhui Wan , Kaicheng Zhang , Yong Liu

Organic-inorganic halide perovskite materials have emerged as attractive alternatives to conventional solar cell building blocks. Their high light absorption coefficients and long diffusion lengths suggest high power conversion efficiencies…