English
Related papers

Related papers: Empirical Line Lists in the ExoMol Database

200 papers

Accurate line lists are important for the description of the spectroscopic nature of small molecules. While a line list for CN (an important molecule for chemistry and astrophysics) exists, no underlying energy spectroscopic model has been…

Chemical Physics · Physics 2021-06-08 Anna-Maree Syme , Laura K. McKemmish

Comprehensive line lists for phosphorus monoxide ($^{31}$P$^{16}$O) and phosphorus monosulphide ($^{31}$P$^{32}$S) in their $X$ $^2\Pi$ electronic ground state are presented. The line lists are based on new ab initio potential energy (PEC),…

Solar and Stellar Astrophysics · Physics 2017-09-12 Laxmi Prajapat , Pawel Jagoda , Lorenzo Lodi , Maire N. Gorman , Sergei N. Yurchenko , Jonathan Tennyson

Computing and using opacities is a key part of modeling and interpreting data of exoplanetary atmospheres. Since the underlying spectroscopic line lists are constantly expanding and currently include up to ~ 10^10 - 10^11 transition lines,…

Artificial intelligence is revolutionizing computational chemistry, bringing unprecedented innovation and efficiency to the field. To further advance research and expedite progress, we introduce the Quantum Open Organic Molecular (QO2Mol)…

Chemical Physics · Physics 2024-10-28 Weiqi Liu , Xi Ai , Zhijian Zhou , Chao Qu , Junyi An , Zhipeng Zhou , Yuan Cheng , Yinghui Xu , Fenglei Cao , Alan Qi

This work presents the AYT2 line list: a comprehensive list of 114 million $^{1}$H$_2$$^{32}$S vibration-rotation transitions computed using an empirically-adjusted potential energy surface and an {\it ab initio} dipole moment surface. The…

Earth and Planetary Astrophysics · Physics 2016-07-05 Ala'a A. A. Azzam , Jonathan Tennyson , Sergei N. Yurchenko , Olga V. Naumenko

This work communicates analysis of aluminum monoxide, AlO, laser-plasma emission records using line strength data and the ExoMol astrophysical database. A nonlinear fitting program computes comparisons of measured and simulated diatomic…

Plasma Physics · Physics 2023-05-04 Christian G. Parigger

Line lists for the sulphur-containing molecules SH (the mercapto radical) and NS are computed as part of the ExoMol project. These line lists consider transitions within the $X$ ${}^2\Pi$ ground state for $^{32}$SH, $^{33}$SH, $^{34}$SH and…

Solar and Stellar Astrophysics · Physics 2018-05-02 Sergei N. Yurchenko , Wesley Bond , Maire N. Gorman , Lorenzo Lodi , Laura K. McKemmish , William Nunn , Rohan Shah , Jonathan Tennyson

Imidogen (NH) is a reactive molecule whose presence in astrochemical environments is of interest due to its role in the formation of nitrogen-containing molecules and as a potential probe of nitrogen abundance. Spectroscopic NH monitoring…

Earth and Planetary Astrophysics · Physics 2024-05-24 Armando N. Perri , Laura K. McKemmish

SiS has long been observed in the circumstellar medium of the carbon-rich star IRC+10216 CW Leo. Comprehensive and accurate rotation-vibrational line lists and partition functions are computed for 12 isotopologues of silicon sulphide…

Solar and Stellar Astrophysics · Physics 2018-08-21 Apoorva Upadhyay , Eamon K. Conway , Jonathan Tennyson , Sergei N. Yurchenko

Molecular line lists are important for modelling absorption and emission processes in atmospheres of different astronomical objects, such as cool stars and exoplanets. In order to be applicable for high temperatures, line lists for…

Earth and Planetary Astrophysics · Physics 2017-09-20 Sergei N. Yurchenko , David S. Amundsen , Jonathan Tennyson , Ingo P. Waldmann

Extensive line lists generated as part of the ExoMol project are used to compute lifetimes for individual rotational, rovibrational and rovibronic excited states, and temperature-dependent cooling functions by summing over all…

Chemical Physics · Physics 2016-02-01 Jonathan Tennyson , Kelsey Hulme , Omree K. Naim , Sergei N. Yurchenko

Methanol (CH$_{3}$OH) is a key complex organic molecule (COM) in the interstellar medium, widely used as a tracer of dense gas and hot molecular cores (HMCs). Using high-resolution ALMA observations from the ATOMS survey, we investigate the…

The GYT line list covering rotational, rovibrational and rovibronic transitions of the mercapto radical SH is presented. This work extends and replaces the SNaSH line list [Yurchenko et al., 2018, MNRAS, 478, 270] which covers the ground…

Earth and Planetary Astrophysics · Physics 2019-10-25 Maire N. Gorman , Sergei N. Yurchenko , Jonathan Tennyson

This work describes the update of NO along with the incorporation of NO$_{2}$ and N$_{2}$O to the HITEMP database. Where appropriate, the HITRAN line lists for the same molecules have also been updated. This work brings the current number…

Accurate line lists for the carbon dimer, C$_2$, are presented. These line lists cover rovibronic transitions between the eight lowest electronic states: $X\,{}^{1}\Sigma_{g}^{+}$, $a\,{}^{3}\Pi_{u}$, $A\,{}^{1}\Pi_{u}$,…

Solar and Stellar Astrophysics · Physics 2018-12-19 Sergei N. Yurchenko , István Szabó , Elizaveta Pyatenko , Jonathan Tennyson

We describe the atomic database of the XSTAR spectral modeling code, summarizing the systematic upgrades carried out in the past twenty years to enable the modeling of K lines from chemical elements with atomic number $Z\leq 30$ and recent…

In this research note, we present linemake, an open-source atomic and molecular line list generator. Rather than a replacement for a number of well-established atomic and molecular spectral databases, linemake aims to be a lightweight,…

Instrumentation and Methods for Astrophysics · Physics 2021-04-20 Vinicius M. Placco , Christopher Sneden , Ian U. Roederer , James E. Lawler , Elizabeth A. Den Hartog , Neda Hejazi , Zachary Maas , Peter Bernath

Molecular line-transition lists are an essential ingredient for radiative-transfer calculations. With recent databases now surpassing the billion-lines mark, handling them has become computationally prohibitive, due to both the required…

Earth and Planetary Astrophysics · Physics 2017-11-29 Patricio Cubillos

Accurate line lists for three molecules, BeH, MgH and CaH, in their ground electronic states are presented. These line lists are suitable for temperatures relevant to exoplanetary atmospheres and cool stars (up to 2000K). A combination of…

Solar and Stellar Astrophysics · Physics 2012-08-22 Benjamin Yadin , Thomas Veness , Pierandrea Conti , Christian Hill , Sergei N. Yurchenko , Jonathan Tennyson

Comprehensive rotation-vibration line lists are presented for the two main isotopologues of methyl chloride, $^{12}$CH$_3{}^{35}$Cl and $^{12}$CH$_3{}^{37}$Cl. The line lists, OYT-35 and OYT-37, are suitable for temperatures up to…

Earth and Planetary Astrophysics · Physics 2018-08-21 A. Owens , A. Yachmenev , W. Thiel , A. Fateev , J. Tennyson , S. N. Yurchenko