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We describe a simple yet rigorous theoretical model capable of analytical estimation of plasmonic field enhancement in complex metal structures. We show that one can treat the complex structures as coupled multi-pole modes with highest…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Gregory Sun , Jacob Khurgin , Alexander M. Bratkovsky

The collective absorption and emission of light by an ensemble of atoms is at the heart of many fundamental quantum optical effects and the basis for numerous applications. However, beyond weak excitation, both experiment and theory become…

Non-adiabatic molecular dynamics simulations are used to analyze the role of different solvent degrees of freedom in the non-radiative relaxation of the first excited state of the hydrated electron. The relaxation occurs through a…

chem-ph · Physics 2008-02-03 Oleg V. Prezhdo , Peter J. Rossky

Plasmon-mediated superradiance for molecules around metallic nanospheres was proposed ten years ago. However, its demonstration has not been achieved yet due to the experimental difficulty of positioning molecules, and the theoretical…

Light-induced energy confinement in nanoclusters via plasmon excitations influences applications in nanophotonics, photocatalysis, and the design of controlled slow electron sources. The resonant decay of these excitations through the…

Atomic and Molecular Clusters · Physics 2023-06-21 Rasheed Shaik , Hari R. Varma , Mohamed El-Amine Madjet , Fulu Zheng , Thomas Frauenheim , Himadri S. Chakraborty

Excitons and plasmons are the two most fundamental types of collective electronic excitations occurring in solids. Traditionally, they have been studied separately using bulk techniques that probe their average energetic structure over…

Solving the challenging problem of the amplification and generation of an electromagnetic field in nanostructures enables to implement many properties of the electromagnetic field at the nanoscale in novel practical applications. A…

Mesoscale and Nanoscale Physics · Physics 2017-05-17 A. A. Zyablovsky , E. S. Andrianov , I. A. Nechepurenko , A. V. Dorofeenko , A. A. Pukhov , A. P. Vinogradov

The description of carrier dynamics in spatially confined semiconductor nanocrystals (NCs), which have enhanced electron-hole and exciton-phonon interactions, is a great challenge for modern computational science. These NCs typically…

Materials Science · Physics 2022-11-01 Dipti Jasrasaria , Daniel Weinberg , John P. Philbin , Eran Rabani

Spontaneous emission of quantum emitters can be modified by engineering their optical environment. This allows a resonant nanoantenna to significantly modify the radiative properties of a quantum emitter. In this article, we go beyond the…

With recent experiments investigating the optical properties of progressively smaller plasmonic particles, quantum effects become increasingly more relevant, requiring a microscopic description. Using the density matrix formalism we analyze…

Mesoscale and Nanoscale Physics · Physics 2018-10-17 Alexandra Crai , Andreas Pusch , Doris E. Reiter , Lara Román Castellanos , Tilmann Kuhn , Ortwin Hess

Progress in electron-beam spectroscopies has recently enabled the study of optical excitations with combined space, energy and time resolution in the nanometer, millielectronvolt and femtosecond domain, thus providing unique access into…

Optics · Physics 2019-11-13 Albert Polman , Mathieu Kociak , F. Javier García de Abajo

Surface plasmon-polaritons in a multilayer structure consisting of a metallic film and one or more layers of nanocrystal (NC) quantum dots (QDs) are studied. It is shown that there is resonance coupling between the plasmon-polaritons…

Mesoscale and Nanoscale Physics · Physics 2011-02-14 Yu. V. Bludov , M. I. Vasilevskiy

The ultrafast non-radiative relaxation of a molecular ensemble coupled to a cavity mode is considered theoretically and by real-time quantum dynamics. For equal coupling strength of single molecules to the cavity mode, the non-radiative…

Chemical Physics · Physics 2018-12-26 Oriol Vendrell

Conventional approaches to probing ultrafast molecular dynamics rely on the use of synchronized laser pulses with a well-defined time delay. Typically, a pump pulse excites a wavepacket in the molecule. A subsequent probe pulse can then…

Mesoscale and Nanoscale Physics · Physics 2020-03-27 R. E. F. Silva , Javier del Pino , Francisco J. García-Vidal , Johannes Feist

Achieving and controlling strong light-matter interactions in many-body systems is of paramount importance both for fundamental understanding and potential applications. In this paper we demonstrate both experimentally and theoretically how…

Mesoscale and Nanoscale Physics · Physics 2016-12-26 Pierre Fauche , Christian Gebhardt , Maxim Sukharev , Renaud A. L. Vallee

There are two types of two-photon transitions in molecular aggregates, that is, non-local excitations of two monomers and local double excitations to some higher excited intra-monomer electronic state. As a consequence of the inter-monomer…

Quantum Physics · Physics 2015-06-04 Yun-an Yan , Oliver Kühn

Metallic nanoparticles can localize the incident light to hotspots as plasmon oscillations, where the intensity can be increased up to four orders of magnitude. Even though the lifetime of plasmons are typically short, it can be increased…

Optics · Physics 2020-01-22 Bilge Can Yildiz , Alpan Bek , Mehmet Emre Tasgin

In this work we show how to maximize absorption of plasmonic nanoparticles in terms of size, geometry and material. For that reason the interaction of nanoparticles with light was decomposed into different effects. We determined that the…

Optics · Physics 2025-02-07 Matej Bubaš , Jordi Sancho-Parramon

Ultrafast light-matter interaction is a powerful tool for the study of solids. Upon laser excitation, carrier multiplication and lattice acceleration beyond thermal velocity can occur, as a result of far-from-equilibrium carrier relaxation.…

Materials Science · Physics 2019-01-04 Chao Lian , S. B. Zhang , Sheng Meng

Exciton-polaritons provide a versatile platform for the study of a wide range of phenomena, including polariton lasers, topological polaritons, and bosonic condensation. Transition metal dichalcogenide monolayers host excitons with large…

Mesoscale and Nanoscale Physics · Physics 2026-05-15 Lukas Krelle , Lukas Husel , Kenji Watanabe , Takashi Taniguchi , Ismail Bilgin , Alexander Högele , Farsane Tabataba-Vakili