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Understanding the physics of light emitter in quantum nanostructure regarding scalability, geometry, structure of the system and coupling between different degrees of freedom is important as one can improve the design and further provide…

Mesoscale and Nanoscale Physics · Physics 2019-01-25 Chen-Yen Lai , S. A. Trugman , Jian-Xin Zhu

We find that the spontaneous and collective emissions have a strong influence on the excitation of two-level absorbers (atoms, molecules) interacting in resonance with the plasmonic mode near the metal nanoparticle. The spontaneous and…

Optics · Physics 2024-07-25 Igor E. Protsenko , Alexander V. Uskov , Nikolay V. Nikonorov

We explore whether localized surface plasmon polariton modes can transfer heat between molecules placed in the hot spot of a nanoplasmonic cavity through optomechanical interaction with the molecular vibrations. We demonstrate that external…

Quantum Physics · Physics 2019-07-16 S. Mahmoud Ashrafi , R. Malekfar , A. R. Bahrampour , Johannes Feist

Electrically connected and plasmonically enhanced molecular junctions combine the optical functionalities of high field confinement and enhancement (cavity function), and of high radiative efficiency (antenna function) with the electrical…

Polaritons are quasiparticles arising from the strong coupling of electromagnetic waves in cavities and dipolar oscillations in a material medium. In this framework, localized surface plasmon in metallic nanoparticles defining optical…

Surface and volume plasmons excited in a metal cluster by moving electron and corresponding inelastic scattering spectra are studied based on the hydrodynamic approach. Along with the bulk losses traditionally taken into account, the…

Plasma Physics · Physics 2016-04-20 V. B. Gildenburg , V. A. Kostin , I. A. Pavlichenko

Light-driven plasmonic enhancement of chemical reactions on metal catalysts is a promising strategy to achieve highly selective and efficient chemical transformations. The study of plasmonic catalyst materials has traditionally focused on…

Materials Science · Physics 2021-06-16 Oscar A. Douglas-Gallardo , Connor L. Box , Reinhard J. Maurer

Plasmonic nanoparticles (NPs) hold tremendous promise for catalyzing light-driven chemical reactions. The conventionally assumed detrimental absorption loss from plasmon damping can now be harvested to drive chemical transformations of the…

When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) emerge as the fundamental excitations…

Chemical Physics · Physics 2024-10-23 Xinyang Li , Sergei Tretiak , Yu Zhang

Some basic radiative and non-radiative processes taking place in semiconductor nanocrystals are discussed, and rates of these processes are calculated. In particular, in the present review we explore both intra-crystallite processes, such…

Mesoscale and Nanoscale Physics · Physics 2020-01-16 Vladimir A. Burdov

Nanoscale localization of electromagnetic fields near metallic nanostructures underpins the fundamentals and applications of plasmonics. The unavoidable energy loss from plasmon decay, initially seen as a detriment, has now expanded the…

Plasmonic excitations decay within femtoseconds, leaving non-thermal (often referred to as "hot") charge carriers behind that can be injected into molecular structures to trigger chemical reactions that are otherwise out of reach -- a…

Materials Science · Physics 2025-01-28 Jakub Fojt , Paul Erhart , Christian Schäfer

Plasmonic structures are known to support the modes with subwavelength volumes in which the field matter interactions are greatly enhanced. Coupling between the molecular excitations and plasmons leading to formation of plexcitons has been…

Optics · Physics 2018-11-27 Jacob B Khurgin

Recent experiments claimed that the enhancement of catalytic reaction rates occurs via the reduction of activation barriers driven by non-equilibrium (``hot'') electrons in plasmonic metal nanoparticles. These experiments place plasmonic…

Chemical Physics · Physics 2020-04-22 Yonatan Sivan , Ieng Wai Un , Yonatan Dubi

Presence of a metal nanoparticle near a quantum dipole emitter, when a localized surface plasmon mode is excited via the resonant coupling with an excited quantum dipole, changes dramatically the relaxation dynamics: it is no longer…

Optics · Physics 2015-06-18 Khachatur V. Nerkararyan , Sergey I. Bozhevolnyi

The manipulation of coupled quantum excitations is of fundamental importance in realizing novel photonic and optoelectronic devices. We use electroluminescence to probe plasmon-exciton coupling in hybrid structures consisting of a nanoscale…

Coupling molecular transition dipole moments to surface-plasmon polaritons (SPPs) results in the formation of new optical quasiparticles, i.e., plexcitons. Mixing the specific properties of matter excitations and light modes has proven to…

Photonic condensates are complex systems exhibiting phase transitions due to the interaction with their molecular environment. Given the macroscopic number of molecules that form a reservoir of excitations, numerical simulations are…

Quantum Physics · Physics 2019-11-20 Benjamin T. Walker , Henry J. Hesten , Robert A. Nyman , Florian Mintert

Metal nanoparticles are attractive for plasmon-enhanced generation of hot carriers, which may be harnessed in photochemical reactions. In this work, we analyze the coherent femtosecond dynamics of photon absorption, plasmon formation, and…

Mesoscale and Nanoscale Physics · Physics 2021-01-14 Tuomas P. Rossi , Paul Erhart , Mikael Kuisma

We study the plasmonic properties of arrays of atomic chains which comprise noble (Cu, Ag, and Au) and transition (Pd, Pt) metal atoms using time-dependent density-functional theory. We show that the response to the electromagnetic…

Mesoscale and Nanoscale Physics · Physics 2018-10-02 Kevin Conley , Neha Nayyar , Tuomas P. Rossi , Mikael Kuisma , Volodymyr Turkowski , Martti Puska , Talat S. Rahman