Related papers: Core-shell microgels via precipitation polymerizat…
We provide a detailed description of the Chimera code, a code developed to model core collapse supernovae in multiple spatial dimensions. The core collapse supernova explosion mechanism remains the subject of intense research. Progress to…
We study a heuristic, core-scale model for the transport of polymer particles in a two phase (oil and water) porous medium. We are motivated by recent experimental observations which report increased oil recovery when polymers are injected…
The formation of soluble hydrogen-bonding interpolymer complexes between poly(acrylic acid) (PAA) and poly(acrylic acid-co-2-acrylamido-2-methyl-1-propane sulfonic acid)-graft-poly(N, N dimethylacrylamide) (P(AA-co-AMPSA)-g-PDMAM) at pH =…
Current Lagrangian (particle-tracking) algorithms used to simulate diffusion-reaction equations must employ a certain number of particles to properly emulate the system dynamics---particularly for imperfectly-mixed systems. The number of…
In this work we developed a theoretical model to describe the polymerization of very long macromolecules with simultaneous precipitation. As a reference system for our model we consider UHMWPE polymerization process, via homogeneous…
Inspired by the path followed by Matthias Ballauff over the past 20 years, the development of thermosensitive core-shell microgel structures is reviewed. Different chemical approaches, from hard nanoparticle cores to double…
We summarize the current status of the turbulent model of star formation in turbulent molecular clouds. In this model, clouds, clumps and cores form a hierarchy of nested density fluctuations caused by the turbulence, and either collapse or…
The diffusion of small molecular penetrants through polymeric materials represents an important fundamental problem, relevant to the design of materials for applications such as coatings and membranes. Polymer networks hold promise in these…
We examine the conditions under which binary and multiple stars may form out of turbulent molecular cloud cores using high resolution 3-D, adaptive mesh refinement (AMR) hydrodynamics (Truelove et al., 1997, 1998; Klein, 1999). We argue…
We describe the elasticity of compressed microgel suspensions starting from a core--shell model for the single particle. The mechanical properties of the inner core and of the outer corona are described via the mean field Flory theory, and…
The angular momentum of a molecular cloud core plays a key role in star formation, since it is directly related to the outflow and the jet emanating from the new-born star and it eventually results in the formation of the protoplanetary…
Many biological tissues feature a heterogeneous network of fibers whose tensile and bending rigidity contribute substantially to these tissues' elastic properties. Rigidity percolation has emerged as a important paradigm for relating these…
We consider the gelation of particles which are permanently connected by random crosslinks, drawn from an ensemble of finite-dimensional continuum percolation. To average over the randomness, we apply the replica trick, and interpret the…
Recent studies have suggested that low-energy cosmic rays (CRs) may be accelerated inside molecular clouds by the shocks associated with star formation. We use a Monte Carlo transport code to model the propagation of CRs accelerated by…
We present a confocal-microscopy study of demixing and remixing in binary liquids containing colloidal particles. First, particle-stabilized emulsions have been fabricated by nucleation and growth of droplets upon cooling from the…
R Coronae Borealis (RCB) stars are rare hydrogen-deficient carbon-rich variable supergiants thought to be the result of dynamically unstable white dwarf mergers. We attempt to model RCBs through all the relevant timescales by simulating a…
The physical conditions in a collapsing cloud can be traced by observations of molecular lines. To correctly interpret these observations the abundance distributions of the observed species need to be derived. The chemistry in a collapsing…
In this thesis the formation and properties of a polymer gel on and at a surface are investigated. The gel under investigation is defined as a three-dimensional network of "phantom" macromolecules that form permanent links with one another…
We investigate by means of a number of different dynamical Monte Carlo simulation methods the self-assembly of equilibrium polymers in dilute, semidilute and concentrated solutions under good-solvent conditions. In our simulations, both…
We implement a Monte Carlo radiative transfer method, that uses a large number of monochromatic luminosity packets to represent the radiation transported through a system. These packets are injected into the system and interact…