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Ab initio calculation of the electronic properties of materials is a major challenge for solid state theory. Whereas the experience of forty years has proven density functional theory (DFT) in a suitable, e.g. local approximation (LDA) to…

Strongly Correlated Electrons · Physics 2009-11-13 K. Held , O. K. Andersen , M. Feldbacher , A. Yamasaki , Y. -F. Yang

Density functional theory (DFT), the most widely adopted method in modern computational chemistry, fails to describe accurately the electronic structure of strongly correlated systems. Here we show that DFT can be formally and practically…

Chemical Physics · Physics 2022-04-18 Daniel Gibney , Jan-Niklas Boyn , David A. Mazziotti

First principles methods can provide insight into materials that is otherwise impossible to acquire. Density Functional Theory (DFT) has been the first principles method of choice for numerous applications, but it falls short of predicting…

Materials Science · Physics 2019-07-24 Arpita Paul , Turan Birol

We review the basic ideas of the dynamical mean field theory (DMFT) and some of the insights into the electronic structure of strongly correlated electrons obtained by this method in the context of model Hamiltonians. We then discuss the…

Strongly Correlated Electrons · Physics 2007-05-23 G. Kotliar , S. Y. Savrasov

Subsystem Density-Functional Theory (DFT) is an emerging technique for calculating the electronic structure of complex molecular and condensed phase systems. In this topical review, we focus on some recent advances in this field related to…

Chemical Physics · Physics 2015-06-24 Alisa Krishtal , Debalina Sinha , Alessandro Genova , Michele Pavanello

Several methods have been developed to improve the predictions of density functional theory (DFT) in the case of strongly correlated electron systems. Out of these approaches, DFT+$U$, which corresponds to a static treatment of the local…

Strongly Correlated Electrons · Physics 2025-04-01 Alberto Carta , Iurii Timrov , Peter Mlkvik , Alexander Hampel , Claude Ederer

We review recent results on the properties of materials with correlated electrons obtained within the LDA+DMFT approach, a combination of a conventional band structure approach based on the local density approximation (LDA) and the…

Strongly Correlated Electrons · Physics 2015-03-13 J. Kunes , I. Leonov , M. Kollar , K. Byczuk , V. I. Anisimov , D. Vollhardt

We investigate the electronic structure of SrMnO$_3$ with Density Functional Theory (DFT) plus Dynamical Mean-Field Theory (DMFT). Within this scheme the selection of the correlated subspace and the construction of the corresponding Wannier…

Strongly Correlated Electrons · Physics 2018-06-20 Daniel Bauernfeind , Robert Triebl , Manuel Zingl , Markus Aichhorn , Hans Gerd Evertz

The dynamical mean field theory (DMFT) has become a standard technique for the study of strongly correlated models and materials overcoming some of the limitations of density functional approaches based on local approximations. An important…

Strongly Correlated Electrons · Physics 2015-10-28 K. Hallberg , D. J. García , Pablo S. Cornaglia , Jorge I. Facio , Y. Núñez-Fernández

We introduce natural atomic orbitals as the local projector to define the correlated subspace for DFT + DMFT (density functional theory plus dynamical mean-field theory) calculation. The natural atomic orbitals are found to be stably…

Strongly Correlated Electrons · Physics 2020-01-01 Jae-Hoon Sim , Myung Joon Han

A new approach for calculating spectral density functions of strongly correlated electron systems is proposed within the exact diagonalization method of dynamical mean-field theory (DMFT). This approach is based on the analytic continuation…

Strongly Correlated Electrons · Physics 2016-10-05 Song-Jin O , Hak-Chol Pak , Kwang-Il Ryom , Song-Jin Im

In this thesis we study the strongly-correlated-electron physics of the longstanding H-Tc-superconductivity problem using a non-perturbative method, the Dynamical Mean Field Theory (DMFT), capable to go beyond standard perturbation-theory…

Strongly Correlated Electrons · Physics 2007-10-16 Marcello Civelli

We introduce the unification of dynamical mean field theory (DMFT) and linear-scaling density functional theory (DFT), as recently implemented in ONETEP, a linear-scaling DFT package, and TOSCAM, a DMFT toolbox. This code can account for…

Strongly Correlated Electrons · Physics 2020-05-04 Edward B. Linscott , Daniel J. Cole , Nicholas D. M. Hine , Michael C. Payne , Cédric Weber

The LDA+DMFT method is a very powerful tool for gaining insight into the physics of strongly correlated materials. It combines traditional ab-initio density-functional techniques with the dynamical mean-field theory. The core aspects of the…

Strongly Correlated Electrons · Physics 2017-11-22 Eva Pavarini

We have formulated and implemented a fully charge-self-consistent density functional theory plus dynamical mean field theory methodology which enables an efficient calculation of the total energy of realistic correlated electron systems.…

Strongly Correlated Electrons · Physics 2015-06-22 Hyowon Park , Andrew J. Millis , Chris A. Marianetti

The qualitative reliability of the dynamical mean field theory (DMFT) is investigated for systems in which either the actual carrier density or the effective carrier density is low, by comparing the exact perturbative and dynamical mean…

Strongly Correlated Electrons · Physics 2024-03-28 Anqi Mu , Zhiyuan Sun , Andrew J. Millis

The sensitivity of Density Functional Theory plus Dynamical Mean Field Theory calculations to different constructions of the correlated orbitals is investigated via a detailed comparison of results obtained for the quantum material…

Strongly Correlated Electrons · Physics 2021-05-12 Jonathan Karp , Alexander Hampel , Andrew J. Millis

Density functional theory (DFT) provides a theoretical framework for efficient and fairly accurate calculations of the electronic structure of molecules and crystals. The main features of density functional theory are described and DFT…

Chemical Physics · Physics 2012-06-12 Hauke Paulsen , Alfred Xaver Trautwein

ComDMFT is a massively parallel computational package to study the electronic structure of correlated-electron systems (CES). Our approach is a parameter-free method based on ab initio linearized quasiparticle self-consistent GW (LQSGW) and…

Strongly Correlated Electrons · Physics 2019-07-22 Sangkook Choi , Patrick Semon , Byungkyun Kang , Andrey Kutepov , Gabriel Kotliar

For reliable and efficient inclusion of electron-electron correlation effects in nanosystems we propose a combined density-functional-theory/nonhomogeneous dynamical-mean-field-theory (DFT + DMFT) approach which employs an approximate…

Strongly Correlated Electrons · Physics 2013-11-14 Alamgir Kabir , Volodymyr Turkowski , Talat S. Rahman