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Analytical forces have been derived in the Lagrangian framework for several random phase approximation (RPA) correlated total energy methods based on the range separated hybrid (RSH) approach, which combines a short-range density functional…

Chemical Physics · Physics 2016-03-16 Bastien Mussard , Peter G. Szalay , János G. Ángyán

Approximation of a tensor network by approximating (e.g., factorizing) one or more of its constituent tensors can be improved by canceling the leading-order error due to the constituents' approximation. The utility of such robust…

Chemical Physics · Physics 2024-07-30 Karl Pierce , Varun Rishi , Edward F. Valeev

Renormalization is a powerful concept in the many-body problem. Inspired by the highly successful density matrix renormalization group (DMRG) algorithm, and the quantum chemical graphical representation of configuration space, we introduce…

Chemical Physics · Physics 2016-03-23 Zhendong Li , Garnet Kin-Lic Chan

Statistical mechanics is founded on the assumption that a system can reach thermal equilibrium, regardless of the starting state. Interactions between particles facilitate thermalization, but, can interacting systems always equilibrate…

Recently, Hohenstein et al[1] introduced tensor hypercontraction density fitting to decompose the rank-4 electron repulsion integral tensor as the product of five rank-2 tensors. In this paper, we use this methodology to construct an…

Chemical Physics · Physics 2012-09-14 Neil Shenvi , Helen Van Aggelen , Weitao Yang

Energy functions for pure and heterogenous systems are one of the backbones for molecular simulation of condensed phase systems. With the advent of machine learned potential energy surfaces (ML-PESs) a new era has started. Statistical…

We investigate the application of tensor-train (TT) algorithms to multigroup thermal radiation transport (i.e., photon radiation transport). The TT framework enables simulations at discretizations that might otherwise be computationally…

Instrumentation and Methods for Astrophysics · Physics 2026-04-10 Aditya S. Deshpande , Patrick D. Mullen , Alex A. Gorodetsky , Joshua C. Dolence , Chad D. Meyer , Jonah M. Miller , Luke F. Roberts

Numerical modelling of several coupled passive linear dynamical systems (LDS) is considered. Since such component systems may arise from partial differential equations, transfer function descriptions, lumped systems, measurement data, etc.,…

Optimization and Control · Mathematics 2019-11-12 Juha Kuortti , Jarmo Malinen , Tom Gustafsson

We propose a method to improve the computational and memory efficiency of numerical solvers for the nonequilibrium Dyson equation in the Keldysh formalism. It is based on the empirical observation that the nonequilibrium Green's functions…

Strongly Correlated Electrons · Physics 2023-07-31 Jason Kaye , Denis Golež

We address prediction problems on tabular categorical data, where each instance is defined by multiple categorical attributes, each taking values from a finite set. These attributes are often referred to as fields, and their categorical…

We have developed efficient numerical algorithms for solving 3D steady-state Poisson-Nernst-Planck (PNP) equations with excess chemical potentials described by the classical density functional theory (cDFT). The coupled PNP equations are…

Numerical Analysis · Mathematics 2016-08-24 Da Meng , Bin Zheng , Guang Lin , Maria L. Sushko

Recurrent neural networks (RNNs) are powerful tools for sequential modeling, but typically require significant overparameterization and regularization to achieve optimal performance. This leads to difficulties in the deployment of large…

Machine Learning · Computer Science 2021-11-11 Charles C. Onu , Jacob E. Miller , Doina Precup

A new method is presented to generate atomic structures that reproduce the essential characteristics of arbitrary material systems, phases, or ensembles. Previous methods allow one to reproduce the essential characteristics (e.g. chemical…

Materials Science · Physics 2024-09-24 James M. Goff , Coreen Mullen , Shizhong Yang , Oleg N. Starovoytov , Mitchell A. Wood

We propose an efficient algorithm for the evaluation of the potential and its gradient of gravitational/electrostatic $N$-body systems, which we call particle mesh multipole method (PMMM or PM$^3$). PMMM can be understood both as an…

Instrumentation and Methods for Astrophysics · Physics 2014-10-20 Keigo Nitadori

A linearized tensor renormalization group (LTRG) algorithm is proposed to calculate the thermodynamic properties of one-dimensional quantum lattice models, that is incorporated with the infinite time-evolving block decimation technique, and…

Strongly Correlated Electrons · Physics 2011-04-05 Wei Li , Shi-Ju Ran , Shou-Shu Gong , Yang Zhao , Bin Xi , Fei Ye , Gang Su

Many applications in data science and scientific computing involve large-scale datasets that are expensive to store and compute with, but can be efficiently compressed and stored in an appropriate tensor format. In recent years, randomized…

Numerical Analysis · Mathematics 2019-05-20 Rachel Minster , Arvind K. Saibaba , Misha E. Kilmer

We introduce a numerical approach to calculate the statistics of work done on 1D quantum lattice systems initially prepared in thermal equilibrium states. This approach is based on two tensor-network techniques: Time Evolving Block…

Statistical Mechanics · Physics 2022-01-04 Jiayin Gu , Fan Zhang , H. T. Quan

Understanding quantum many-body states of correlated electrons is one main theme in modern condensed matter physics. Given that the Fermi-Hubbard model, the prototype of correlated electrons, has been recently realized in ultracold optical…

Strongly Correlated Electrons · Physics 2021-01-27 Bin-Bin Chen , Chuang Chen , Ziyu Chen , Jian Cui , Yueyang Zhai , Andreas Weichselbaum , Jan von Delft , Zi Yang Meng , Wei Li

High throughput screening of materials for technologically relevant areas, like identification of better catalysts, electronic materials, ceramics for high temperature applications and drug discovery, is an emerging topic of research. To…

Chemical Physics · Physics 2020-05-04 Edgar Josué Landinez Borda , Amit Samanta

The direct variational optimization of the two-electron reduced density matrix (2RDM) can provide a reference-independent description of the electronic structure of many-electron systems that naturally captures strong or nondynamic…

Chemical Physics · Physics 2024-06-19 Run R. Li , Marcus D. Liebenthal , A. Eugene DePrince