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The mixed-field orientation of an asymmetric-rotor molecule with its permanent dipole moment non-parallel to the principal axes of polarizability is investigated experimentally and theoretically. We find that for the typical case of a…

We study interaction of generic asymmetric molecules with a pair of strong time-delayed short laser pulses with crossed linear polarizations. We show that such an excitation not only provides unidirectional rotation of the most polarizable…

Chemical Physics · Physics 2018-02-28 E. Gershnabel , I. Sh. Averbukh

We examine the potential-energy curves and polarization of the dipole moments of two static polar molecules under the influence of an external dc electric field and their anisotropic dipole-dipole interaction. We model the molecules as…

Quantum Physics · Physics 2024-09-24 Felipe Isaule , Robert Bennett , Jörg B. Götte

We investigate the process of circularly polarized high harmonic generation in molecules using a bicircular laser field. In this context, we show that molecules offer a very robust framework for the production of circularly polarized…

Atomic Physics · Physics 2016-06-22 F Mauger , A. D. Bandrauk , T Uzer

We examine the impact of the combination of a static electric field and a non resonant linearly polarized laser field on an asymmetric top molecule. Within the rigid rotor approximation, we analyze the symmetries of the Hamiltonian for all…

Chemical Physics · Physics 2015-05-28 J. J. Omiste , R. González-Férez , P. Schmelcher

A beam of rotating dipolar particles (molecules or clusters) will broaden when passed through an electric or magnetic field gradient region. This broadening, which is a common experimental observable, can be expressed in terms of the…

Atomic and Molecular Clusters · Physics 2012-01-05 Jaap Bulthuis , Vitaly V. Kresin

Half-cycle laser pulse is applied on an absorbed molecule to investigate its alignment and orientation behavior. Crossover from field-free to hindered rotation motion is observed by varying the angel of hindrance of potential well. At small…

Atomic Physics · Physics 2007-05-23 Y. Y. Liao , Y. N. Chen , D. S. Chuu

We present a theoretical study of the impact of an electrostatic field combined with nonresonant linearly polarized laser pulses on the rotational dynamics of a thermal ensemble of linear molecules. We solve the time-dependent Schr\"odinger…

Quantum Physics · Physics 2015-06-16 Juan J. Omiste , Rosario González Férez

We consider the elastic scattering of electrons by hydrogen atoms in the presence of a two-color circularly polarized laser field in the domain of moderate intensities below $10^{13}$ W/cm$^2$ and high projectile energies. A hybrid approach…

Atomic Physics · Physics 2023-06-16 Gabriela Buica

The dynamics of non-polar diatomic molecules interacting with a far-detuned narrow-band laser field, that only may drive rotational transitions, is studied. The rotation of the molecule is considered both classically and quantum…

Quantum Physics · Physics 2009-11-10 A. Adelswaerd , S. Wallentowitz

A strong inhomogeneous static electric field is used to spatially disperse a supersonic beam of polar molecules, according to their quantum state. We show that the molecules residing in the lowest-lying rotational states can be selected and…

Alignment and orientation of molecules by intense, ultrashort laser fields are crucial for a variety of applications in physics and chemistry. These include control of high harmonics generation, molecular orbitals tomography, control of…

We study the ionization dynamics of oriented HeH$^+$ in strong linearly-polarized laser fields by numerically solving the time-dependent Schr\"{o}dinger equation. The calculated photoelectron momentum distributions for parallel orientation…

Atomic Physics · Physics 2020-11-11 S. Wang , J. Y. Che , C. Chen , G. G. Xin , Y. J. Chen

The classical dynamics of a charged particle traveling in a laser field modeled by an elliptically polarized monochromatic electromagnetic plane wave is discussed within the time reparametrization invariant form of the non-relativistic…

Classical Physics · Physics 2008-06-17 Paul Jameson , Arsen Khvedelidze

We theoretically consider the phenomenon of field-free long-lasting orientation of symmetric-top molecules ionized by two-color laser pulses. The anisotropic ionization produces a significant long-lasting orientation of the surviving…

Chemical Physics · Physics 2023-03-08 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We theoretically demonstrate a scheme for tomographic reconstruction of asymmetric molecular orbitals based on high-order harmonic generation with a two-color multicycle laser field. It is shown that by adjusting the relative phase of the…

Atomic Physics · Physics 2013-12-30 Meiyan Qin , Xiaosong Zhu , Qingbin Zhang , Peixiang Lu

We present a theoretical study of the mixed-field-orientation of asymmetric top molecules in tilted static electric field and non-resonant linearly polarized laser pulse by solving the time-dependent Schr\"odinger equation. Within this…

Chemical Physics · Physics 2016-12-21 Juan J. Omiste , Rosario González-Férez

We provide a theory of the deflection of polar and non-polar rotating molecules by inhomogeneous static electric field. Rainbow-like features in the angular distribution of the scattered molecules are analyzed in detail. Furthermore, we…

Chemical Physics · Physics 2015-05-20 E. Gershnabel , I. Sh. Averbukh

Impulsive orientation of symmetric-top molecules excited by two-color femtosecond pulses is considered. In addition to the well-known transient orientation appearing immediately after the pulse and then reemerging periodically due to…

Optics · Physics 2021-07-22 Long Xu , Ilia Tutunnikov , Yehiam Prior , Ilya Sh. Averbukh

We demonstrate to image asymmetric molecular orbitals via high-order harmonic generation in a one-color inhomogeneous field. Due to the broken inversion symmetry of the inhomogeneous field in space, the returning electrons with energy in a…

Optics · Physics 2018-03-14 Hua Yuan , Lixin He , Feng Wang , Baoning Wang , Xiaosong Zhu , Pengfei Lan , Peixiang Lu
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