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Direct air capture (DAC) of carbon dioxide is a critical technology for mitigating climate change, but current materials face limitations in efficiency and scalability. We discover novel DAC materials using a combined machine learning (ML)…

Materials Science · Physics 2024-10-21 Megan C. Davis , Wilton J. M. Kort-Kamp , Ivana Matanovic , Piotr Zelenay , Edward F. Holby

Copper-based catalysts are of particular interest for electrochemical reduction of CO$_2$ (CO2RR) as products beyond CO can form. To improve activity and selectivity, several studies have focused on the addition of other elements as…

Metal-organic frameworks (MOFs) are promising materials for gas sensing but are often limited to single-use detection. We demonstrate a hybridization strategy synergistically deploying conductive MOFs (cMOFs) and conductive polymers (cPs)…

Synthesis of ammonia through photo- and electrocatalysis is a rapidly growing field. Titania-based catalysts are widely reported for photocatalytic ammonia synthesis and have also been suggested as electrocatalysts. The addition of…

Chemical Physics · Physics 2019-12-13 Benjamin M. Comer , Max H. Lenk , Aradhya P. Rajanala , Emma L. Flynn , Andrew J. Medford

Metal catalysts supporting the growth of Single Wall Carbon Nanotubes display different carbon solubilities and chemical reactivities. In order to specifically assess the role of carbon solubility, we take advantage of the physical…

Materials Science · Physics 2017-02-23 Juan-Manuel Aguiar-Hualde , Yann Magnin , Hakim Amara , Christophe Bichara

Sustainable development and the recent fast growing global demands for energy and functional chemicals urgently call for effective methods for CO2 remediation and efficient metal-free catalysts for selective oxidation of aromatic alcohol.…

Chemical Physics · Physics 2018-12-31 Jiang Gong , Huijuan Lin , Konrad Grygiel , Jiayin Yuan

Novel photoelectrocatalysts that use sunlight to power the CO$_2$ reduction reaction will be crucial for carbon-neutral power and energy-efficient industrial processes. Scalable photoelectrocatalysts must satisfy a stringent set of…

Single atom catalysts (SACs) based on 2D materials are identified to be efficient in many catalytic reaction. In this work, the catalytic performance of Pd/Pt embedded planar carbon nitride (CN) for CO oxidation, has been investigated via…

Chemical Physics · Physics 2020-01-08 Yongchao Rao , Xiangmei Duan

Single-atom catalysts are considered as a promising method for efficient energy conversion, owing to their advantages of high atom utilization and low catalyst cost. However, finding a stable two-dimensional structure and high hydrogen…

Materials Science · Physics 2023-09-08 Wei Xun , Xin Liu , Qing-Song Jiang , Xiao Yang , Yin-Zhong Wu , Ping Li

The ability to design and dynamically control chiroptical responses in solid-state matter at wafer scale enables new opportunities in various areas. Here we present a full stack of computer-aided designs and experimental implementations of…

Optics · Physics 2024-06-21 Jichao Fan , Ruiyang Chen , Minhan Lou , Haoyu Xie , Nina Hong , Yingheng Tang , Weilu Gao

Hydrogen fuel is an ideal energy source to replace the traditional fossil fuels because of its high energy density and renewability. Electrochemical water splitting is also regarded as a sustainable, cleaning and eco-friendly method for…

Chemical Physics · Physics 2021-03-23 Zhexu Xi

The search for earth abundant, efficient and stable electrocatalysts that can enable the chemical reduction of CO2 to value-added chemicals and fuels at an industrially relevant scale, is a high priority for the development of a global…

It has been proposed that the superconducting transition temperature $T_{\mathrm{c}}$ of an unconventional superconductor with a large pairing scale but strong phase fluctuations can be enhanced by coupling it to a metal. However, the…

Superconductivity · Physics 2022-12-05 Philip M. Dee , Steven Johnston , Thomas Maier

Data from recent laser-shock experiments, density-functional theory (DFT) with molecular-dynamics (MD), and path-integral Monte Carlo (PIMC) simulations on carbon are compared with predictions from the neutral-pseudo-atom (NPA)+…

Statistical Mechanics · Physics 2017-05-30 M. W. C. Dharma-wardana

Monolayer transition metal dichalcogenides (TMDs) with strong spin-orbit coupling combined with broken inversion symmetry, leading to a coupling of spin and valley degrees of freedom, make these materials highly interesting for potential…

Mesoscale and Nanoscale Physics · Physics 2020-09-23 Liang Xilong , Qin Chengbing , Gao Yan , Han Shuangping , Zhang Guofeng , Chen Ruiyun , Hu Jianyong , Xiao Liantuan , Jia Suotang

We use computational screening to systematically investigate the use of transition metal doped carbon nanotubes for chemical gas sensing. For a set of relevant target molecules (CO, NH3, H2S) and the main components of air (N2, O2, H2O), we…

Mesoscale and Nanoscale Physics · Physics 2010-06-28 J. M. García-Lastra , D. J. Mowbray , K. S. Thygesen , A. Rubio , K. W. Jacobsen

Hydrogen is deemed as an attractive energy carrier alternative to fossil fuels, and it is required to store for many applications. Physisorption is one of the promising ways to store H$_2$ for its practical applications. Covalent Organic…

Materials Science · Physics 2021-11-05 Nilima Sinha , Srimanta Pakhira

The interplay between charge transfer and electronic disorder in transition-metal dichalcogenide multilayers gives rise to superconductive coupling driven by proximity enhancement, tunneling and superconducting fluctuations, of a yet…

A long-standing puzzle for methanol electrooxidation is how to achieve a CO-free pathway and accurately understand the origin of electrocatalytic selectivity. Herein, we unequivocally demonstrate that the Bi-modified Pt/C follows a CO-free…

Two-dimensional materials (2DM) have attracted much interest due to their distinct optical, electronic, and catalytic properties. These properties can be by tuned a range of methods including substitutional doping or, as recently…