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Schwarzites are crystalline, 3D porous structures with stable negative curvature formed of sp2-hybridized carbon atoms. These structures present topologies with tunable porous size and shape and unusual mechanical properties. In this work,…

Mesoscale and Nanoscale Physics · Physics 2018-01-18 Cristiano F. Woellner , Tiago Botari , Eric Perim , Douglas S. Galvao

Schwarzites are porous crystalline structures with Gaussian negative curvature. In this work, we investigated the mechanical behavior and energy absorption properties of two carbon-based diamond schwarzites (D688 and D8bal). We carried out…

Since graphene was synthesized the interest for building new 2D and 3D structures based on the carbon allotropes has been growing every day. One of these 3D structures is know as carbon schwarzites. Schwarzites consist of carbon…

Materials Science · Physics 2020-08-26 Raphael M. Tromer , Levi C. Felix , Cristiano F. Woellner , Douglas S. Galvao

We investigated through fully atomistic molecular dynamics simulations, the mechanical behavior (compressive and tensile) and energy absorption properties of two families (primitive (P688 and P8bal) and gyroid (G688 and G8bal)) of…

Materials Science · Physics 2019-09-10 Levi C. Felix , Cristiano F. Woellner , Douglas S. Galvao

Triply Periodic Minimal Surfaces (TPMS) possess locally minimized surface area under the constraint of periodic boundary conditions. Different families of surfaces were obtained with different topologies satisfying such conditions. Examples…

We carried out fully atomistic reactive molecular dynamics simulations to study the mechanical behavior of six newly proposed hybrid schwarzite-based structures (interlocked petal-schwarzites). Schwarzites are carbon crystalline…

Schwarzites are porous (spongy-like) carbon allotropes with negative Gaussian curvatures. They were proposed by Mackay and Terrones inspired by the works of the German mathematician Hermann Schwarz on Triply-Periodic Minimal Surfaces…

The 3D porous carbon-based structures called Schwarzites have been recently a subject of renewed interest due to the possibility of being synthesized in the near future. These structures exhibit negatively curvature topologies with tuneable…

Computational Physics · Physics 2018-01-22 Daiane Damasceno Borges , Douglas S. Galvao

Schwarzites are porous structures that present negative Gaussian curvatures. Although initially proposed for carbon, in principle, schwarzites of other elements are possible. In this work, we have carried out a detailed investigation of the…

Materials Science · Physics 2022-08-23 Raphael M. Tromer , Levi C. Felix , Cristiano F. Woellner , Douglas S. Galvao

Nature-occurring structures exhibiting unique topological features such as complex and gradient porosity has been the basis to create new materials and/or structures. Most studies have been focused on complex periodic porous structures but…

Materials Science · Physics 2021-11-15 Eliezer F. Oliveira , Rushikesh S. Ambekar , Douglas S. Galvao , Chandra S. Tiwary

We use ab initio density functional calculations to study the stability, elastic properties and electronic structure of sp2 carbon minimal surfaces with negative Gaussian curvature, called schwarzites. We focus on two systems with cubic…

Mesoscale and Nanoscale Physics · Physics 2010-09-03 Sora Park , Kritsada Kittimanapun , Jeung-Sun Ahn , Young-Kyun Kwon , David Tomanek

The superior mechanical properties and low density of carbon nanostructures make them promising ballistic protection materials, stimulating investigations on their high-strain-rate behavior. Recent experiments and simulations revealed…

Mesoscale and Nanoscale Physics · Physics 2018-01-17 David L. Azevedo , Rafael A. Bizao , Douglas S. Galvao

Results based on {\em ab initio} density functional calculations indicate a general graphitization tendency in ultrathin slabs of cubic diamond, boron nitride, and many other cubic structures including rocksalt. Whereas such compounds often…

Materials Science · Physics 2015-06-22 Pavel B. Sorokin , Alexander G. Kvashnin , Zhen Zhu , David Tománek

The widely used crystal structures for both heptazine-based and triazine-based two-dimensional (2D) graphitic carbon nitride (g-C$_3$N$_4$) are the flat P-6m2 configurations. However, the experimentally synthesized 2D g-C$_3$N$_4$ possess…

Materials Science · Physics 2021-02-03 Luneng zhao , Xizhi Shi , Jin Li , Tao Ouyang , Chunxiao Zhang , Chao Tang , Chaoyu He , Jianxin Zhong

The topologically engineered complex Schwarzites architecture has been used to build novel and unique structural components with a high specific strength. The mechanical properties of these building blocks can be further tuned, reinforcing…

Understanding the reactivity of carbon surfaces is crucial for the development of advanced functional materials. In this study, we systematically investigate the reactivity of graphene surfaces with the Stone-Wales (SW) defect using Density…

Materials Science · Physics 2023-08-11 Aleksandar Z. Jovanović , Ana S. Dobrota , Natalia V. Skorodumova , Igor A. Pašti

Energetic and geometric aspects of the permeation of low-Z atoms through graphene sheets are investigated. Energy barriers and deformations are calculated via density functional theory for the permeation of H, He, Li and Be atoms at several…

Chemical Physics · Physics 2012-10-02 Stefan E. Huber , Andreas Mauracher , Michael Probst

A set of sp2 amorphous carbons involving natural mineral shungite carbon and antraxolite as well as two synthetic carbon blacks were investigated by using neutron powder diffraction and inelastic neutron scattering at low temperature. NDP…

Martensitic transformations, viewed as continuous transformations between triply periodic minimal surfaces (TPMS), as originally proposed by Hyde and Andersson [Z. Kristallogr. 174, 225 (1986)], is extended to include paths between the…

Materials Science · Physics 2024-02-05 Mengdi Yin , Dimitri D. Vvedensky

Experiments with multiwalled carbon nanotubes and graphite as targets in a source of negative ions with cesium sputtering have shown that nanotubes with nanometer radii and micrometer length can be compared with micrometer size graphite…

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