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Related papers: ExoMol molecular line lists -- XXXVII: spectra of …

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Accurate rotation-vibration line lists are calculated for silicon monoxide. Line lists are presented for the main isotopologue, $^{28}$Si$^{16}$O, and for four monosubsituted isotopologues ($^{29}$Si$^{16}$O, $^{30}$Si$^{16}$O,…

Solar and Stellar Astrophysics · Physics 2013-09-27 Emma J. Barton , Sergei N. Yurchenko , Jonathan Tennyson

Silicon dioxide (SiO$_2$) is expected to occur in the atmospheres of hot rocky super-Earth exoplanets but a lack of spectroscopic data is hampering its possible detection. Here, we present the first, comprehensive molecular line list for…

Earth and Planetary Astrophysics · Physics 2020-05-29 A. Owens , E. K. Conway , J. Tennyson , S. N. Yurchenko

A new line list for hydronium (H$_3$$^{16}$O$^+$) is computed. The line list is based on a new ab initio dipole moment surface (CCSD(T)/aug-cc-pVQZ) and a new empirical potential energy surface (PES). The empirical PES of H$_3$O$^+$ was…

Earth and Planetary Astrophysics · Physics 2020-07-29 S. N. Yurchenko , Jonathan Tennyson , Steve Miller , V. V. Melnikov , J. O'Donoghue , L. Moore

Improved opacities are needed for modelling the atmospheres and evolution of cool carbon-rich stars and extra-solar planets; in particular, contributions made by the astrophysically important propadienediylidene (C$_3$) molecule need, at a…

Solar and Stellar Astrophysics · Physics 2024-10-25 A. E. Lynas-Gray , O. L. Polyansky , J. Tennyson , S. N. Yurchenko , N. F. Zobov

A rovibronic line list for the ground ($X$ $^3\Sigma^-$) and first excited ($a$ $^1\Delta$) states of phosphinidene, $^{31}$PH, is computed. The line list is designed for studies of exoplanetary and cool stellar atmospheres with…

Earth and Planetary Astrophysics · Physics 2019-07-17 Jonathan Langleben , Jonathan Tennyson , Sergei N. Yurchenko , Peter Bernath

Indications of aluminium monoxide in atmospheres of exoplanets are being reported. Studies using high-resolution spectroscopy should allow a strong detection but require high accuracy laboratory data. A \textsc{marvel} (measured active…

Earth and Planetary Astrophysics · Physics 2021-10-29 Charles A. Bowesman , Meiyin Shuai , Sergei N. Yurchenko , Jonathan Tennyson

New hot line lists for five isotopologues of N$_2$O are presented, for the parent $^{14}$N$_2^{16}$O and 4 singly substituted species $^{14}$N$_2^{17}$O, $^{14}$N$_2^{18}$O, $^{14}$N$^{15}$N$^{16}$O and $^{15}$N$^{14}$N$^{16}$O. The line…

Earth and Planetary Astrophysics · Physics 2024-10-01 Sergei N. Yurchenko , Thomas M. Mellor , Jonathan Tennyson

SiH has long been observed in the spectrum of our Sun and other cool stars. Computed line lists for the main isotopologues of silicon monohydride, $^{28}$SiH, $^{29}$SiH, $^{30}$SiH and $^{28}$SiD are presented. These line lists consider…

Solar and Stellar Astrophysics · Physics 2017-12-13 Sergei N. Yurchenko , Frances Sinden , Lorenzo Lodi , Christian Hill , Maire N. Gorman , Jonathan Tennyson

Nitric acid is a possible biomarker in the atmospheres of exoplanets. An accurate line list of rotational and rotational-vibrational transitions is computed for nitric acid (HNO$_3$). This line list covers wavelengths longer than 1.42…

Earth and Planetary Astrophysics · Physics 2015-08-06 Anatoly I. Pavlyuchko , Sergei N. Yurchenko , Jonathan Tennyson

Potassium hydroxide (KOH) and sodium hydroxide (NaOH) are expected to occur in the atmospheres of hot rocky super-Earth exoplanets but a lack of spectroscopic data is hampering their potential detection. Using robust first-principles…

Earth and Planetary Astrophysics · Physics 2021-03-03 A. Owens , J. Tennyson , S. N. Yurchenko

Line lists for the ground electronic ground state for six major isotopologues of nitric oxide are presented. The line lists are constructed using empirical energy levels (and line positions) and high-level {\it ab inito} intensities. The…

Earth and Planetary Astrophysics · Physics 2017-06-28 Andy Wong , Sergei N. Yurchenko , Peter Bernath , Holger S. P. Müller , Stephanie McConkey , Jonathan Tennyson

Accurate and complete rotational, rotational-vibrational and rotational-vibrational-electronic line lists are calculated for sodium hydride: both the NaH and NaD isotopologues are considered. These line lists cover all ro-vibrational states…

Astrophysics of Galaxies · Physics 2015-06-02 Tom Rivlin , Lorenzo Lodi , Sergei N. Yurchenko , Jonathan Tennyson , Robert J. Le Roy

A revised rotation-vibration line list for the combined hydrogen cyanide (HCN) / hydrogen isocyanide (HNC) system is presented. The line list uses {\it ab initio} transition intensities calculated previously (Harris et al., ApJ, 2002, 578,…

Solar and Stellar Astrophysics · Physics 2014-06-27 R. J. Barber , J. K. Strange , C. Hill , O. L. Polyansky , G. Ch. Mellau , S. N. Yurchenko , Jonathan Tennyson

Any future detection of the calcium monohydroxide radical (CaOH) in stellar and exoplanetary atmospheres will rely on accurate molecular opacity data. Here, we present the first comprehensive molecular line list of CaOH covering the \A--\X\…

Earth and Planetary Astrophysics · Physics 2022-10-25 Alec Owens , Alexander Mitrushchenkov , Sergei N. Yurchenko , Jonathan Tennyson

The ExoMol database (www.exomol.com) provides extensive line lists of molecular transitions which are valid over extended temperatures ranges. The status of the current release of the database is reviewed and a new data structure is…

A comprehensive, calculated line list of frequencies and transition probabilities for the singly deuterated isotopologue of H3+, H2D+, is presented. The line list, called ST1, contains over 22 million rotational-vibrational transitions…

Computational Physics · Physics 2010-05-11 Taha Sochi , Jonathan Tennyson

Published high-resolution rotation-vibration transitions of \spec{h212c16o}, the principal isotopologue of methanal, are analyzed using the MARVEL (Measured Active Rotation-Vibration Energy Levels) procedure. The literature results are…

An accurate line list for calcium oxide is presented covering transitions between all bound ro-vibronic levels from the five lowest electronic states \X, \Ap, \A, \astate, and \bstate. The ro-vibronic energies and corresponding…

Astrophysics of Galaxies · Physics 2016-07-05 Sergei N. Yurchenko , Audra Blissett , Usama Asari , Marcus Vasilios , Christian Hill , Jonathan Tennyson

Accurate line lists are crucial for correctly modelling a variety of astrophysical phenomena, including stellar photospheres and the atmospheres of extra-solar planets. This paper presents a new line database Toto for the main isotopologues…

The use of variational nuclear motion programs to compute line lists of transition frequencies and intensities is now a standard procedure. The ExoMol project has used this technique to generate line lists for studies of hot bodies such as…

Chemical Physics · Physics 2016-07-06 Jonathan Tennyson , S. N. Yurchenko