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Any structural transformation of water is sensitive to an external electric field, since water molecules have dipole moments. We study influence of external uniform electric field on crystallization of supercooled water enclosed between two…

Soft Condensed Matter · Physics 2019-09-05 Ramil M. Khusnutdinoff , Anatolii V. Mokshin

The paper discusses the features of supercooled water thin film of width $d=3.97$~nm contained by the perfect graphene layers and crystallizing under external stationary electric field. It was found that the electric field applied…

Materials Science · Physics 2020-05-22 R. M. Khusnutdinoff , A. V. Mokshin

Understanding the phase behaviors of nanoconfined water has driven notable research interests recently. In this work, we examine the structures and thermodynamics of water encapsulated under a graphene cover. We find layered water…

Statistical Mechanics · Physics 2016-07-19 Shuping Jiao , Chuanhua Duan , Zhiping Xu

Water confined between two graphene layers with a small separation forms a two-dimensional ice structure,with an apparent square symmetry [Algara-Siller et al., Nature (London) 519, 443 (2015)], which is poorly understood. A density…

Mesoscale and Nanoscale Physics · Physics 2017-02-06 Niels R. Walet

An external electric field changes the physical properties of polar-liquids due to the reorientation of their permanent dipoles. For example it should affect significantly the physical properties of water confined in a nanochannel. The…

Mesoscale and Nanoscale Physics · Physics 2016-08-03 Sobrino Fernández Mario , M. Neek-Amal , F. M. Peeters

A generally accepted understanding of the anomalous properties of water will only emerge if it becomes possible to systematically characterize water in the deeply supercooled regime, from where the anomalies appear to emanate. This has…

Within the so-called "no-man's land" between about 150 and 235 K, crystallization of bulk water is inevitable. The glasslike freezing and a liquid-to-liquid transition of water, predicted to occur in this region, can be investigated by…

Soft Condensed Matter · Physics 2020-09-17 Jonas K. H. Fischer , Pit Sippel , Dmytro Denysenko , Peter Lunkenheimer , Dirk Volkmer , Alois Loidl

Molecular dynamics simulations are carried out to explore the dynamical crossover phenomenon in strongly confined and mildly supercooled water in graphene oxide nanopores. In contrast to studies where confinement is used to study the…

Soft Condensed Matter · Physics 2020-03-09 Rajasekaran M , K. Ganapathy Ayappa

There is a long-standing question about the molecular configuration of interfacial water molecules in the proximity of solid surfaces, particularly carbon atoms which play a crucial role in electrochemistry and biology. In this study, the…

Statistical Mechanics · Physics 2021-03-03 Iman Ahmadabadi , Ali Esfandiar , Ali Hassanali , Mohammad Reza Ejtehadi

Adsorbed layers of water are ubiquitously present at surfaces and fill in microscopic pores, playing a central role in many phenomena in such diverse fields as materials science, geology, biology, tribology, nanotechnology. Despite such…

Mesoscale and Nanoscale Physics · Physics 2015-03-26 G. Algara-Siller , O. Lehtinen , F. C. Wang , R. R. Nair , U. Kaiser , H. A. Wu , I. V. Grigorieva , A. K. Geim

In the absence of disorder, electrons can display glassy behavior through supercooling the liquid state, avoiding the solidification into a charge ordered state. Such supercooled electron liquids are experimentally found in organic…

Strongly Correlated Electrons · Physics 2016-02-16 Louk Rademaker , Arnaud Ralko , Simone Fratini , Vladimir Dobrosavljevic

Various properties of water are affected by confinement as the space-filling of the water molecules is very different from bulk water. In our study, we challenged the creation of a stable system in which water molecules are permanently…

Mesoscale and Nanoscale Physics · Physics 2026-04-28 Tim Verhagen , Jiri Klimes , Barbara Pacakova , Martin Kalbac , Jana Vejpravova

We present a phase diagram for water confined to cylindrical silica nanopores in terms of pressure, temperature and pore radius. The confining cylindrical wall is hydrophilic and disordered, which has a destabilizing effect on ordered water…

Statistical Mechanics · Physics 2015-06-05 David T. Limmer , David Chandler

Using molecular dynamics simulations, we systematically investigate supercooled liquids formed at cooling rates below and above the critical cooling rate (CCR). By analyzing the distribution of short-time averaged potential energies (DoPE)…

Soft Condensed Matter · Physics 2025-04-08 B Zhang , M. Zhang , D. Y. Sun , X. G. Gong

Water has many anomalous properties compared to "simple" liquids, and these anomalies are typically enhanced in supercooled water. While numerous models have been proposed, including the liquid-liquid critical point, the singularity-free…

Chemical Physics · Physics 2020-10-28 Loni Kringle , Wyatt A. Thornley , Bruce D. Kay , Greg A. Kimmel

The process of homogeneous crystal nucleation has been considered in a model liquid, where the interparticle interaction is described by a short-range spherical oscillatory potential. Mechanisms of initiating structural ordering in the…

Materials Science · Physics 2018-12-18 Bulat N. Galimzyanov , Dinar T. Yarullin , Anatolii V. Mokshin

One of water's unsolved puzzles is the question of what determines the lowest temperature to which it can be cooled before freezing to ice. The supercooled liquid has been probed experimentally to near the homogeneous nucleation temperature…

Soft Condensed Matter · Physics 2011-12-08 Emily B. Moore , Valeria Molinero

In sharp contrast to the prevailing view that electric fields promote water freezing, here we show by molecular dynamics simulations that monolayer ice confined between two parallel plates can melt into liquid water under perpendicularly…

Fluid Dynamics · Physics 2013-05-08 Hu Qiu , Wanlin Guo

In this work, the dielectric behavior of water inside charged nanoslit of graphene is studied to analized the water molecules under electrical confinement; through polarizing the nanoslit of graphene, creating an electric field inside the…

Soft Condensed Matter · Physics 2022-08-12 Raúl Fuentes-Azcatl , José Rafael Bordin , Marcia C. Barbosa

When we lower the temperature of a liquid, at some point we meet a first order phase transition to the crystal. Yet, under certain conditions it is possible to keep the system in its metastable phase and to avoid crystallization. In this…

Statistical Mechanics · Physics 2009-05-12 Andrea Cavagna
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