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We present a theoretical study of wetting phenomena and interactions between liquid-vapor interfaces based on the density functional theory. The focus is mostly on the impact of long-range van der Waals interactions both within the fluid…

Chemical Physics · Physics 2011-11-10 Arik Yochelis , Len M. Pismen

Most of the existing classical CO$_2$ models fail to reproduce some or many experimental properties such as surface tension, vapor pressure, density and dielectric constant at difference thermodynamic conditions. Therfore, it is proposed a…

Atomic Physics · Physics 2019-05-09 Raul Fuentes-Azcatl , Hector Dominguez

Within the effective interfacial Hamiltonian approach we evaluate the excess line free energy associated with cylinder-shaped droplets sessile on a stripe-like chemical inhomogeneity of a planar substrate. In the case of short-range…

Statistical Mechanics · Physics 2017-09-06 Pawel Jakubczyk Marek Napiorkowski

In this paper, the pinning and depinning mechanism of the contact line during droplet evaporation on chemically stripe-patterned surfaces is numerically investigated using a thermal multiphase lattice Boltzmann (LB) model with liquid-vapor…

Fluid Dynamics · Physics 2019-08-14 Qing Li , P. Zhou , H. J. Yan

The curvature dependence of the surface tension is related to the excess equimolar radius of liquid drops, i.e., the deviation of the equimolar radius from that defined with the macroscopic capillarity approximation. Based on the Tolman [J.…

Regarding a recent dispute about the symmetry of the stress tensor of fluids, more considerations are presented. The usual proofs of this symmetry are reviewed, and contradictions between this symmetry and the mechanism of gas viscosity are…

Fluid Dynamics · Physics 2024-08-02 Ji Luo

The dynamics of receding contact lines is investigated experimentally through controlled perturbations of a meniscus in a dip coating experiment. We first characterize stationary menisci and their breakdown at the coating transition. It is…

Fluid Dynamics · Physics 2015-05-13 G. Delon , M. Fermigier , J. H. Snoeijer , B. Andreotti

The effects of contact-line pinning are well-known in macroscopic systems, but are only just beginning to be explored at the microscale in colloidal suspensions. We use digital holography to capture the fast three-dimensional dynamics of…

Soft Condensed Matter · Physics 2017-09-13 Anna Wang , W. Benjamin Rogers , Vinothan N. Manoharan

We present an explicit finite difference method to simulate the non-ideal multi-phase fluid flow. The local density and the momentum transport are modeled by the Navier-Stokes (N-S) equations and the pressure is computed by the Van der…

Fluid Dynamics · Physics 2023-07-12 Chunheng Zhao , Alexandre Limare , Stephane Zaleski

Parametric scaling representations are obtained and studied for the asymptotic behavior of interfacial tensions in the \textit{full} neighborhood of a fluid (or Ising-type) critical endpoint, i.e., as a function \textit{both} of temperature…

Statistical Mechanics · Physics 2009-11-10 Shun-yong Zinn , Michael E. Fisher

Surface tension plays a ubiquitous role in phase transitions including condensation or evaporation of atmospheric liquid droplets. Especially, understanding of interfacial thermodynamics of the critical nucleus of 1 nm scale is important…

Soft Condensed Matter · Physics 2020-04-28 QHwan Kim , Wonho Jhe

Sintering, as a thermal process at elevated temperature below the melting point, is widely used to bond contacting particles into engineering products such as ceramics, metals, polymers, and cemented carbides. Modelling and simulation as…

Materials Science · Physics 2023-02-13 Min Yi , Wenxuan Wang , Ming Xue , Qihua Gong , Bai-Xiang Xu

The interplay of slow dynamics and thermodynamic features of dense liquids is studied by examinining how the glass transition changes depending on the presence or absence of Lennard-Jones-like attractions. Quite different thermodynamic…

Materials Science · Physics 2009-11-13 Th. Voigtmann

The main causes of energy dissipation in micro- and nano-scale wetting are viscosity and liquid-solid friction localized in the three-phase contact line region. Theoretical models predict the contactline friction coefficient to correlate…

Fluid Dynamics · Physics 2024-02-12 Michele Pellegrino , Berk Hess

Molecular dynamics simulations on a three dimensional defective Lennard-Jones solid containing a void are performed in order to investigate detailed properties of hot spot generation. In addition to the temperature, I monitor the number of…

Materials Science · Physics 2007-05-23 Takahiro Hatano

Experiments suggest that localization via self-trapping plays a central role in the behavior of equilibrated low mass particles in both liquids and in supercritical fluids. In the latter case, the behavior is dominated by the liquid-vapor…

Mesoscale and Nanoscale Physics · Physics 2015-06-25 Bruce N. Miller , Terrence L. Reese

Kinetics of crystal-growth is investigated along the solid-liquid coexistence line for the (100), (110) and (111) orientations of the Lennard-Jones and Weeks-Chandler-Andersen fcc crystal-liquid interface, using non-equilibrium molecular…

Statistical Mechanics · Physics 2015-04-29 Ronald Benjamin , Jürgen Horbach

We analyze the surface tension exerted at the interface between an active fluid and a solid boundary in terms of tangential forces. Focusing on active systems known to possess an equation of state for the pressure, we show that interfacial…

The Martini model, a coarse-grained forcefield for biomolecular simulations, has experienced a vast increase in popularity in the past decade. Its building-block approach balances computational efficiency with high chemical specificity,…

Various condensed phases of water, spanning from the liquid state to multiple ice phases, have been systematically investigated under extreme conditions of pressure and temperature to delineate their stability boundaries. This study focuses…

Chemical Physics · Physics 2024-05-29 Carlos P. Herrero , Rafael Ramirez
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