Related papers: Optomechanical Collective Effects in Surface-Enhan…
Raman scattering is the inelastic process where photons bounce off molecules, losing energy and becoming red-shifted. This weak effect is unique to each molecular species, making it an essential tool in e.g. spectroscopy and label-free…
In this study, we combined the surface-enhanced Raman scattering (SERS) with density functional theory (DFT) calculations to investigate the SERS spectra of lanthanide (Ln)-citrate complexes (Ln = La, Ce, Pr, Nd, Sm, Eu, and Gd) under 488,…
It is an established understanding that the electromagnetic contribution (the plasmon-mediated enhancement of the laser and scattered local electromagnetic fields) is the main actor in Surface Enhanced Raman Scattering (SERS), with the…
The dependence of surface-enhanced Raman scattering (SERS) spectra on the precise axial position of the laser focus relative to a solid nanostructured substrate has received little to no attention in the literature. Here we show this…
The paper demonstrates possibility of giant enhancement of Surface Enhanced Hyper Raman Scattering on the base of qualitative consideration of electromagnetic field near some models of rough metal surfaces and of some features of the dipole…
In this paper, we study the stochastic resonance (SR) effect in an optomechanical system driven by a strong coupling field and two weak signals in both semiclassical and quantum frameworks. In the semiclassical description, the SR phenomena…
The present approach to SERS does not rely on a hihj electrical conductivity substrate or admixture to enable the SERS process. The novelty of our method is to create an artificial periodic electron distribution on a surface by illumination…
Classical optical frameworks such as the discrete dipole approximation (DDA) assume that the linear spectrum of coupled quantum emitters can be computed solely from the linear susceptibilities of individual constituents. However, recent…
We present a general model study of surface-enhanced resonant Raman scattering and fluorescence focusing on the interplay between electromagnetic effects and the molecular dynamics. Our model molecule is placed close to two Ag…
Surface-enhanced Raman spectroscopy (SERS) allows single-molecule detection due to the strong field localization occurring at sharp bends or kinks of the metal-vacuum interface. An important question concerns the limits of the signal…
Rayleigh scattering is usually considered to be the elastic scattering of photons from sub-wavelength physical objects, such as small particles or molecules. Here, we present the spectroscopic study of the scattering properties of molecules…
We report on the observation of the natural isotopic spread of carbon from single-molecule Surface Enhanced Raman Spectroscopy (SM-SERS). By choosing a dye molecule with a very localized Raman active vibration in a cyano bond (C$\equiv$N…
Tip-enhanced Raman spectroscopy (TERS) is a valuable method for surface analysis with nanometer to angstrom-scale resolution, however, the accurate simulation of particular TERS signals remains a computational challenge. We present a unique…
Surface enhanced Raman scattering (SERS) in nanoscale hotspots has been placed great hopes upon for identification of minimum chemical traces and in-situ investigation of single molecule structures and dynamics. However, previous work…
The impact of stochasticity effects (SEs) in photon emissions on the proton energy spectra during laser-plasma interaction is theoretically investigated in the quantum radiation-dominated regime, which may facilitate SEs experimental…
The paper briefly describes main statements of the theory of the SERS spectra with regards to the single molecule regime, when the enhancement achieves the values . Analysis of the spectra of 4,4-bypyridine, obtained on the dimer lattice of…
Stimulated Raman scattering (SRS) is a powerful method for label-free imaging and spectroscopy of materials. Recent experiments have shown that quantum-enhanced Raman scattering can surpass the shot noise limit and improve the sensitivity…
We discuss intensity effects in collisions between beams of optical photons from a high-power laser and relativistic electrons. Our main focus are the modifications of the emission spectra due to realistic finite-beam geometries. By…
We present a description of a strongly driven multimode optomechanical system that shows the emergence of cooperative effects usually known from systems of atom-light interaction. Our calculations show that under application of a coherent…
Stimulated Raman scattering (SRS) represents a powerful tool for accessing the vibrational properties of molecular compounds or solid state systems. From a spectroscopic perspective, SRS is able to capture Raman spectra free from incoherent…