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In the development of highly efficient photovoltaic cells, solid perovskite systems have demonstrated unprecedented promise, with the figure of merit exceeding nineteen percent of efficiency. In this paper, we investigate the optical and…

Materials Science · Physics 2015-02-05 Towfiq Ahmed , C. La-O-Vorakiat , T. Salim , Y. M. Lam , Elbert E. M. Chia , Jian-Xin Zhu

It is unmistakably paradoxical that the weakest point of the photoactive organic-inorganic hybrid perovskite is its instability against light. Why and how perovskites break down under light irradiation and what happens at the atomistic…

Materials Science · Physics 2017-09-14 Kwisung Kwak , Eunhak Lim , Namyoung Ahn , Jiyoung Heo , Kijoon Bang , Seong Keun Kim , Mansoo Choi

Defects in halide perovskites play an essential role in determining the efficiency and stability of the resulting optoelectronic devices. Here, we present a systematic study of intrinsic point defects in six primary metal halide…

Materials Science · Physics 2022-01-03 Haibo Xue , Geert Brocks , Shuxia Tao

For the ferroelectric perovskite compounds BaTiO3 and PbTiO3, we have studied the effects of external electric fields on the structural properties of the (001) surfaces. The field-induced changes in the surface interlayer spacings and…

Materials Science · Physics 2009-10-31 B. Meyer , David Vanderbilt

Understanding the atomic structure and structural instability of organic-inorganic hybrid perovskites is the key to appreciate their remarkable photoelectric properties and failure mechanism. Here, using low-dose imaging technique by…

Since perovskite solar cells have attracted a lot of attentions over the past years, the enhancement of their optical absorption and current density are among the basic coming challenges. For this reason, first, we have studied structural…

Organic-inorganic halide perovskites, especially methylammonium lead halide, have recently led to a remarkable breakthrough in photovoltaic devices. However, due to the environmental and stability concerns of the heavy metal, lead, in these…

Materials Science · Physics 2015-09-29 Shijing Sun , Satoshi Tominaka , Jung-Hoon Lee , Fei Xie , Paul D. Bristowe , Anthony K. Cheetham

We explore the degradation behaviour under continuous illumination and direct oxygen exposure of inverted unencapsulated formamidinium(FA)0.83Cs0.17Pb(I0.8Br0.2)3, CH3NH3PbI3, and CH3NH3PbI3-xClx perovskite solar cells. We continuously test…

FAPbI3, as a typical hybrid organic-inorganic perovskite, has attracted considerable interest due to its band gap suitable for visible light absorption and good thermal stability. A barrier to the use of FAPbI3 in commercial, stable devices…

Materials Science · Physics 2022-01-17 Junwen Yin , Gilberto Teobaldi , Li-Min Liu

Effect of biaxial tensile strains on optical functions and band edge transitions of ultra thin epitaxial films was studied using as an example a 13 nm thick SrTiO3 films deposited on KTaO3(100) single-crystal substrates. Optical functions…

Materials Science · Physics 2015-05-14 A. Dejneka , M. Tyunina , J. Narkilahti , J. Levoska , D. Chvostova , L. Jastrabik , V. A. Trepakov

Metal halide perovskites possess many physical properties amenable to optoelectronic applications, whereas the realization of these potentials has been hampered by their environmental and electronic instabilities. The morphological and…

The exceptional optoelectronic properties of metal halide perovskites (MHPs) are presumed to arise, at least in part, from the peculiar interplay between the inorganic metal-halide sublattice and the atomic or molecular cations enclosed in…

Doping organic metal-halide perovskites with cesium could be the best solution to stabilize highly-efficient perovskite solar cells. The understanding of the respective roles of the organic molecule, on one hand, and the inorganic lattice,…

Hybrid Lead halide perovskites, despite having unique intrinsic properties with the possibility of flexible synthesis and device fabrication, still suffer from two fundamental issues, i.e. stability in external environment and toxicity due…

Materials Science · Physics 2018-05-16 Jiban Kangsabanik , Vipinraj Sugathan , Anuradha Yadav , Aswani Yella , Aftab Alam

Layered lead halide A'2An-1PbnI3n+1 perovskites (2D LHPs) are attracting considerable attention as a more stable alternative with respect to APbI3 parent phases - a promising material for a new generation of solar cells. However, a critical…

Perovskite materials, known for their structural versatility and multifunctional properties, continue to draw interest for advanced electronic and optoelectronic applications. In this study, we investigate the elastic and strain--engineered…

Metal halide perovskites (MHPs) are low-temperature processable hybrid semiconductor materials with exceptional performances that are revolutionizing the field of optoelectronic devices. Despite their great potential, commercial deployment…

Two-dimensional (2D) perovskites show higher stability in comparison to their three-dimensional (3D) counterparts. Therefore, 2D perovskites have invoked remarkable attention in basic understanding of their physical properties and…

Materials Science · Physics 2025-07-01 Deepika Gill , Gunjana Yadav , Saswata Bhattacharya

Vacancy-ordered double perovskites K2SnX6 (X = I, Br, Cl) attract significant research interest due to their potential application as light-absorbing materials in perovskite solar cells. However, a deep insight into their material…

Materials Science · Physics 2019-08-30 Un-Gi Jong , Chol-Jun Yu , Yun-Hyok Kye

Recently, it was experimentally shown that the performance and thermal stability of the perovskite MAPbI$_3$ were improved upon the adsorption of a molecular layer of caffeine. In this work, we used a hybrid methodology that combines…

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