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Field-induced reorientation of colloidal particles is especially relevant to manipulate the optical properties of a nanomaterial for target applications. We have recently shown that surprisingly feeble external stimuli are able to transform…

Soft Condensed Matter · Physics 2021-07-07 Effran Mirzad Rafael , Luca Tonti , Daniel Corbett , Alejandro Cuetos , Alessandro Patti

In this thesis we study the lateral electrostatic interaction between a pair of non-identical, moderately charged colloidal particles trapped at an electrolyte interface in the limit of short inter-particle separations. Using a simplified…

Soft Condensed Matter · Physics 2017-10-17 Timo Schmetzer

Active colloids and liquid crystals are capable of locally converting the macroscopically-supplied energy into directional motion and promise a host of new applications, ranging from drug delivery to cargo transport at the mesoscale. Here…

The geometric shape, symmetry, and topology of colloidal particles often allow for controlling colloidal phase behavior and physical properties of these soft matter systems. In liquid crystalline dispersions, colloidal particles with low…

Soft Condensed Matter · Physics 2024-10-14 Ye Yuan , Ivan I. Smalyukh

A multiple-image method is developed to accurately calculate the electrostatic interaction between neutral dielectric particles and a uniformly charged dielectric substrate. The difference in dielectric constants between the particle and…

Soft Condensed Matter · Physics 2024-12-18 Xin Li , Changhao Li , Xiangui Chen , Zaixin Wang , Sun Min , Decai Huang

In this paper, we theoretically study the electrostatic interaction between a pair of identical colloids with constant surface potentials sitting in close vicinity of each other at a fluid interface. By employing a simplified yet reasonable…

Soft Condensed Matter · Physics 2020-07-29 Rick Bebon , Arghya Majee

We demonstrate several examples of driving and steering of colloids when dispersed in nematic liquid crystals. The driving mechanism is based on the principle of nonlinear electrophoresis which is mediated by the asymmetry in the structure…

Soft Condensed Matter · Physics 2019-08-28 S. Hernàndez-Navarro , P. Tierno , J. Ignés-Mullol , F. Sagués

The physical behaviour of anisotropic charged colloids is determined by their material dielectric anisotropy, affecting colloidal self-assembly, biological function and even out-of-equilibrium behaviour. However, little is known about…

Soft Condensed Matter · Physics 2021-01-29 Jeffrey C. Everts , Bohdan Senyuk , Haridas Mundoor , Miha Ravnik , Ivan I. Smalyukh

Field induced assembly of reconfigurable structures with complex hierarchical configurations has recently become an area of intense research with the promise for exciting applications in programmable self-assembly and nano/microstructure…

Soft Condensed Matter · Physics 2026-01-14 Indira Barros , Sayanth Ramachandran , Indrani Chakraborty

Nematic colloids exhibit a large diversity of topological defects and structures induced by colloidal particles in the orientationally ordered liquid crystal host fluids. These defects and field configurations define elastic interactions…

Soft Condensed Matter · Physics 2016-12-30 Bohdan Senyuk , Qingkun Liu , Ye Yuan , Ivan I. Smalyukh

Colloidal particles disturb the alignment of rod-like molecules of liquid crystals, giving rise to long-range interactions that minimize the free energy of distorted regions. Particle shape and topology are known to guide this self-assembly…

Soft Condensed Matter · Physics 2017-12-29 Ye Yuan , Angel Martinez , Bohdan Senyuk , Mykola Tasinkevych , Ivan I. Smalyukh

Anisotropic particles oriented in a specific direction can act as artificial atoms and molecules, and their controlled assembly can result in a wide variety of ordered structures. Towards this, we demonstrate the orientation transitions of…

Soft Condensed Matter · Physics 2022-08-12 Mohit Singh , Yoav Tsori

Abundant in nature, colloids also find increasingly important applications in science and technology, ranging from direct probing of kinetics in crystals and glasses to fabrication of third-generation quantum-dot solar cells. Because…

We study the self-assembly of colloidal microgel particles at a quasi-two-dimensional air-water interface of a drying droplet. Using bright-field microscopy, we demonstrate that increasing particle elasticity drives interfacial organization…

Soft Condensed Matter · Physics 2026-03-10 Vaibhav Raj Singh Parmar , Sayantan Chanda , Rituparno Mandal , Ranjini Bandyopadhyay

Colloidal particles suspended in liquid crystals can exhibit various effective anisotropic interactions that can be tuned and utilized in self-assembly processes. We simulate a two-dimensional system of hard disks suspended in a solution of…

Soft Condensed Matter · Physics 2020-07-30 David Müller , Tobias A. Kampmann , Jan Kierfeld

The electrostatic interaction between colloidal particles trapped at the interface between two immiscible electrolyte solutions is studied in the limit of small inter-particle distances. Within an appropriate model exact analytic…

Soft Condensed Matter · Physics 2014-05-07 Arghya Majee , Markus Bier , S. Dietrich

Emulsions comprising isotropic fluid drops within a nematic host are of interest for applications ranging from biodetection to smart windows, which rely on changes of molecular alignment structures around the drops in response to chemical,…

Soft Condensed Matter · Physics 2022-01-10 Bohdan Senyuk , Ali Mozaffari , Kevin Crust , Rui Zhang , Juan J. de Pablo , Ivan I. Smalyukh

Colloidal rods immersed in a thermotropic liquid-crystalline solvent are at the basis of so-called hybrid liquid crystals which are characterized by tunable nematic fluidity with symmetries ranging from conventional uniaxial nematic or…

Soft Condensed Matter · Physics 2021-07-28 B. Senyuk , H. Mundoor , I. I. Smalyukh , H. H. Wensink

Colloidal particles at complex fluid interfaces and within films assemble to form ordered structures with high degrees of symmetry via interactions that include capillarity, elasticity, and other fields like electrostatic charge. Here we…

The ability to dictate colloid motion is an important challenge in fields ranging from materials science to living systems. Here, by embedding energy landscapes in confined nematic liquid crystals, we design a versatile platform to define…

Soft Condensed Matter · Physics 2018-11-07 Yimin Luo , Daniel A. Beller , Giuseppe Boniello , Francesca Serra , Kathleen J. Stebe