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Related papers: Single-atom catalysts boost nitrogen electroreduct…

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Single atom catalysts (SACs) present the ultimate level of catalyst utilization, which puts them in the focus of current research. For this reason, their understanding is crucial for the development of new efficient catalytic systems. Using…

Materials Science · Physics 2021-01-11 Aleksandar Z. Jovanović , Slavko V. Mentus , Natalia V. Skorodumova , Igor A. Pašti

The reduction reaction of turning Cr(VI) into Cr(III) by appropriate oxidants together with nanoscale catalysts in contaminated soil and water received significant amount of attention for its environmental benefits. Single-atom catalysts…

Chemical Physics · Physics 2022-09-20 Jianglu Ping , Haojun Jia

Industrial scale NH3 production is mainly produced by the Haber Bosch process, but it suffers from intensive energy consumption with serious CO2 emission. Electrochemical N2 reduction reaction (NRR) is now used for energy-saving NH3…

Materials Science · Physics 2019-09-02 Tongwei Wu , Yanning zhang

Electrochemical CO2 reduction (CO2R) offers a promising approach to decarbonize chemical manufacturing through production of carbon-neutral fuels. However, insufficient performance and instability of membrane electrode assembly (MEA)…

Despite the immense potential of Dual Single-Atom Compounds (DSACs), the challenges in their synthesis process, including complexity, stability, purity, and scalability, remain primary concerns in current research. Here, we present a…

Applied Physics · Physics 2024-04-09 Yao Hu , Haihui Lan , Junjun He , Wenjing Fang , Wen-Da Zhang , Shuanglong Lu , Fang Duan , Mingliang Du

In this work, we provide a computational methodological framework using the single-atom systems as an example material class for ammonia synthesis that is robust towards parameter selection. Applying this to Pt$_1$/g-C$_3$N$_4$,…

Materials Science · Physics 2020-07-21 Lance Kavalsky , Venkatasubramanian Viswanathan

Over the past decade, extensive research into single-atom catalysts (SACs) has revealed that the catalytic behavior of metal adatoms is highly dependent on how they interact with their support. A strong dependence on the local coordination…

Materials Science · Physics 2025-01-09 Gareth S. Parkinson

Inter-site interactions between single atom catalysts (SACs) in the high loading regime are critical to tuning the catalytic performance. However, the understanding on such interactions and their distance dependent effects remains elusive,…

Chemical Physics · Physics 2022-01-19 Tong Yang , Jun Zhou , Xiaoyang Ma , Keda Ding , Kay Chen Tan , Ge Wang , Haitao Huang , Ming Yang

Exploring and developing low-cost, high-performance, and stable catalysts for the oxygen reduction reaction (ORR) is of great importance, though progress is ongoing. In this work, a simple evaporation-pyrolysis method is employed to…

Materials Science · Physics 2024-10-11 Yuqin Wang , Lizi He , Ning Han

In recent years, single-atom catalysts attracted lots of attention because of their high catalytic activity, selectivity, stability, maximum atom utilization, exceptional performance, and low cost. Single-atom catalyst contains isolated…

Materials Science · Physics 2021-04-16 Deepak Kumar Rai

Zn-air battery (ZAB) has distinguished itself as new generation of energy storage device due to the high theoretical energy density and its performance relies on the oxygen reduction reaction (ORR) performance of the cathode catalysts.…

Applied Physics · Physics 2020-12-21 Kwun Nam Hui

The field of single atom catalysis (SAC) has expanded greatly in recent years. While there has been much success developing new synthesis methods, a fundamental disconnect exists between most experiments and the theoretical computations…

Materials Science · Physics 2022-09-12 Florian Kraushofer , Gareth S. Parkinson

Single-atom metal alloy catalysts (SAACs) have recently become a very active new frontier in catalysis research. The simultaneous optimization of both facile dissociation of reactants and a balanced strength of intermediates' binding make…

Materials Science · Physics 2021-04-14 Zhong-Kang Han , Debalaya Sarker , Runhai Ouyang , Yi Gao , Sergey V. Levchenko

Bimetallic catalysts provide new routes toward sustainable ammonia synthesis, but the structural dynamics controlling their performance under real-world conditions remain poorly understood. Here, we combine in situ gas-cell and multimodal…

Two-dimensional materials supported by single atom catalysis (SACs) are foreseen to replace platinum for large-scale industrial scalability of sustainable hydrogen generation. Here, a series of metal (Al, Sc, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn)…

Materials Science · Physics 2022-11-04 M. V. Jyothirmai , D. Roshini , B. Moses Abraham , Jayant K. Singh

Heterogeneous gas and solid catalyst reactions occur at the atomic level, and understanding and controlling complex catalytic reactions at this level is crucial for the development of improved processes and materials. There are postulations…

Chemical Physics · Physics 2017-05-19 Edward Boyes , Pratibha Gai

Understanding the fundamental mechanisms of single-atom catalysis (SAC) is important to design systems with improved performance and stability. This is problematic, however, because single-atom active sites are extremely difficult to…

Materials Science · Physics 2017-06-30 Gareth S. Parkinson

Photoelectrocatalytic (PEC) reduction of N2 to ammonia (NH3) is emerging as the potential alternative to overcome the standard Haber-Bosch approach. In this communication, solar N2 reduction was demonstrated with molybdenum carbide (Mo2C)…

Nitrogen reduction reaction (NRR) which converts nitrogen (N2) to ammonia (NH3) normally requires harsh conditions to break the bound nitrogen bond. Herein, via first-principles calculation we reveal that a superior NRR catalytic activity…

Materials Science · Physics 2022-01-31 Zheng Shu , Yongqing Cai

Oxygen evolution reaction (OER) electrolysis, as an important reaction involved in water splitting and rechargeable metal-air battery, has attracted increasing attention for clean energy generation and efficient energy storage. Nickel/iron…

Materials Science · Physics 2014-11-19 Ming Gong , Hongjie Dai