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The Hubbard model provides a test bed to investigate the complex behaviour arising from electron-electron interaction in strongly-correlated systems and naturally emerges as the foundation model for lattice density functional theory (DFT).…

Strongly Correlated Electrons · Physics 2025-01-29 Eoghan Cronin , Rajarshi Tiwari , Stefano Sanvito

High-entropy alloys are solid solutions of multiple principal elements, capable of reaching composition and feature regimes inaccessible for dilute materials. Discovering those with valuable properties, however, relies on serendipity, as…

High-entropy alloys (HEAs) exhibit exceptional properties arising from a combination of thermodynamic, kinetic and structural factors and have found applications in numerous fields such as aerospace, energy, chemical industries, hydrogen…

Materials Science · Physics 2025-11-18 Manish Sahoo , Akash Deshmukh , Yash Kokane , Jayaprakash H M , Raghavan Ranganathan

Current neural networks for predictions of molecular properties use quantum chemistry only as a source of training data. This paper explores models that use quantum chemistry as an integral part of the prediction process. This is done by…

Chemical Physics · Physics 2018-08-22 Haichen Li , Christopher Collins , Matteus Tanha , Geoffrey J. Gordon , David J. Yaron

We propose a refined scheme of deriving an effective low-energy Hamiltonian for materials with strong electronic Coulomb correlations beyond density functional theory (DFT). By tracing out the electronic states away from the target degrees…

Strongly Correlated Electrons · Physics 2017-08-09 Motoaki Hirayama , Takashi Miyake , Masatoshi Imada , Silke Biermann

Computational virtual high-throughput screening (VHTS) with density functional theory (DFT) and machine-learning (ML)-acceleration is essential in rapid materials discovery. By necessity, efficient DFT-based workflows are carried out with a…

Materials Science · Physics 2021-06-25 Chenru Duan , Shuxin Chen , Michael G. Taylor , Fang Liu , Heather J. Kulik

We derive an exact representation of the exchange-correlation energy within density functional theory (DFT) which spawns a class of approximations leading to correct long-range asymptotic behavior. In what amounts to be the simplest…

Materials Science · Physics 2009-11-10 Roi Baer , Daniel Neuhauser

Reconstructing Hamiltonians from local measurements is key to enabling reliable quantum simulation: both validating the implemented model, and identifying any left-over terms with sufficient precision is a problem of increasing importance.…

Quantum Physics · Physics 2024-07-09 Sourav Nandy , Markus Schmitt , Marin Bukov , Zala Lenarčič

High-entropy alloys (HEAs) have attracted increasing attention due to their unique structural and functional properties. In the study of HEAs, thermodynamic properties and phase stability play a crucial role, making phase diagram…

Materials Science · Physics 2025-12-01 Siya Zhu , Doguhan Sariturk , Raymundo Arroyave

Effective Hamiltonians, when used in tandem with statistical mechanics techniques, offer a rigorous connection between 0 Kelvin ab-initio predictions and finite temperature experimental observations. For alloys, cluster expansion…

Materials Science · Physics 2016-09-26 Elizabeth Decolvenaere , Michael J. Gordon , Anton Van der Ven

Drawing on experimental data for baryon resonances, Hamiltonian effective field theory (HEFT) is used to predict the positions of the finite-volume energy levels to be observed in lattice QCD simulations of the lowest-lying $J^P=1/2^-$…

High Energy Physics - Lattice · Physics 2016-03-01 Zhan-Wei Liu , Waseem Kamleh , Derek B. Leinweber , Finn M. Stokes , Anthony W. Thomas , Jia-Jun Wu

Predicting the mean-field Hamiltonian matrix in density functional theory is a fundamental formulation to leverage machine learning for solving molecular science problems. Yet, its applicability is limited by insufficient labeled data for…

Machine Learning · Computer Science 2024-06-06 He Zhang , Chang Liu , Zun Wang , Xinran Wei , Siyuan Liu , Nanning Zheng , Bin Shao , Tie-Yan Liu

The true power of computational research typically can lay in either what it accomplishes or what it enables others to accomplish. In this work, both avenues are simultaneously embraced across several distinct efforts existing at three…

Materials Science · Physics 2024-11-06 Adam M. Krajewski

We develop a computational method to learn a molecular Hamiltonian matrix from matrix-valued time series of the electron density. As we demonstrate for three small molecules, the resulting Hamiltonians can be used for electron density…

Computational Physics · Physics 2020-09-01 Harish S. Bhat , Karnamohit Ranka , Christine M. Isborn

Computational screening is indispensable for the efficient design of high-entropy alloys (HEAs), which hold considerable potential for catalytic applications. However, the chemical space of HEAs is exponentially vast with respect to the…

Quantum Physics · Physics 2025-01-28 Tomoya Shiota , Kenji Ishihara , Wataru Mizukami

High entropy alloys (HEA) represent a class of materials with promising properties, such as high strength and ductility, radiation damage tolerance, etc. At the same time, a combinatorially large variety of compositions and a complex…

Materials Science · Physics 2025-10-03 Franco Moitzi , Lorenz Romaner , Andrei V. Ruban , Oleg E. Peil

Accelerating the design of materials with targeted properties is one of the key materials informatics tasks. The most common approach takes a data-driven motivation, where the underlying knowledge is incorporated in the form of…

Materials Science · Physics 2022-09-28 Shunshun Liu , Kyungtae Lee , Prasanna V. Balachandran

While density functional theory (DFT) serves as a prevalent computational approach in electronic structure calculations, its computational demands and scalability limitations persist. Recently, leveraging neural networks to parameterize the…

Computational Physics · Physics 2024-06-18 Yang Zhong , Hongyu Yu , Jihui Yang , Xingyu Guo , Hongjun Xiang , Xingao Gong

Hamiltonian systems with multiple timescales arise in molecular dynamics, classical mechanics, and theoretical physics. Long-time numerical integration of such systems requires resolving fast dynamics with very small time steps, which…

Numerical Analysis · Mathematics 2025-10-30 Rui Fang , Richard Tsai

We describe a procedure for mapping a self-consistent mean-field theory (also known as density functional theory) into a shell model Hamiltonian that includes quadrupole-quadrupole and monopole pairing interactions in a truncated space. We…

Nuclear Theory · Physics 2008-11-26 R. Rodriguez-Guzman , Y. Alhassid , G. F. Bertsch