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Statistical formulations of thermodynamic entropy, such as those by Boltzmann and Gibbs, were originally developed for classical systems and are well understood in that context. However, the foundational aspects of quantum statistical…

Quantum Physics · Physics 2025-10-08 Smitarani Mishra , Shaon Sahoo

Quantum Brownian motion model is a typical model in the study of nonequilibrium quantum thermodynamics. Entropy is one of the most fundamental physical concepts in thermodynamics. In this work, by solving the quantum Langevin equation, we…

Quantum Physics · Physics 2021-08-11 Tian Qiu , H. T. Quan

This paper is an introduction to the von Neumann entropy in a historic approach. Von Neumann's gedanken experiment is repeated, which led him to the formula of thermodynamic entropy of a statistical operator. In the analysis of his ideas we…

Mathematical Physics · Physics 2007-05-23 D. Petz

A quantum statistical expression for the entropy of a nonequilibrium system is defined so as to be consistent with Gibbs' relation, and is shown to corresponds to dynamical variable by introducing analogous to the Heisenberg picture in…

Statistical Mechanics · Physics 2013-05-29 Hiroki Majima , Akira Suzuki

A microscopic understanding of the thermodynamic entropy in quantum systems has been a mystery ever since the invention of quantum mechanics. In classical physics, this entropy is believed to be the logarithm of the volume of phase space…

Quantum Physics · Physics 2013-05-08 J. M. Deutsch , Haibin Li , Auditya Sharma

The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…

Statistical Mechanics · Physics 2015-11-18 Robert H. Swendsen

For a quantum state undergoing unitary Schr\"odinger time evolution, the von Neumann entropy is constant. Yet the second law of thermodynamics, and our experience, show that entropy increases with time. Ingarden introduced the quantum…

Quantum Physics · Physics 2019-07-03 Craig S. Lent

We define and investigate a notion of entropy for quantum error correcting codes. The entropy of a code for a given quantum channel has a number of equivalent realisations, such as through the coefficients associated with the Knill-Laflamme…

Quantum Physics · Physics 2009-02-24 David W. Kribs , Aron Pasieka , Karol Zyczkowski

It is well known that a Shannon based definition of information entropy leads in the classical case to the Boltzmann entropy. It is tempting to regard the Von Neumann entropy as the corresponding quantum mechanical definition. But the…

Quantum Physics · Physics 2009-11-10 Alexander Stotland , Andrei A. Pomeransky , Eitan Bachmat , Doron Cohen

Given the algebra of observables of a quantum system subject to selection rules, a state can be represented by different density matrices. As a result, different von Neumann entropies can be associated with the same state. Motivated by a…

Quantum Physics · Physics 2021-05-25 Paolo Facchi , Giovanni Gramegna , Arturo Konderak

Quantum information-theoretic approach has been identified as a way to understand the foundations of quantum mechanics as early as 1950 due to Shannon. However there hasn't been enough advancement or rigorous development of the subject. In…

Quantum Physics · Physics 2018-07-04 Shubhayan Sarkar

We construct a complete set of Wannier functions which are localized at both given positions and momenta. This allows us to introduce the quantum phase space, onto which a quantum pure state can be mapped unitarily. Using its probability…

Statistical Mechanics · Physics 2015-06-10 Xizhi Han , Biao Wu

We introduce an ergotropy-based formulation of quantum thermodynamics, which provides a strong connection between average heat and von Neumann entropy. By adopting this formulation, we can reinterpret the infinitesimal average heat in terms…

Quantum Physics · Physics 2025-11-26 J. M. Z. Choquehuanca , P. A. C. Obando , M. S. Sarandy , F. M. de Paula

Quantum thermodynamics has emerged as a central field for understanding how energy conversion processes occur in microscopic systems. In these systems, effects such as coherence, entanglement, and non-Markovianity play key roles. In this…

Quantum Physics · Physics 2025-12-02 J. M. Z. Choquehuanca

The von Neumann entropy of a quantum state is a central concept in physics and information theory, having a number of compelling physical interpretations. There is a certain perspective that the most fundamental notion in quantum mechanics…

Quantum Physics · Physics 2021-05-12 Gilad Gour , Mark M. Wilde

This paper investigates the relationship between categorical entropy and von Neumann entropy of quantum lattices. We begin by studying the von Neumann entropy, proving that the average von Neumann entropy per site converges to the logarithm…

Statistical Mechanics · Physics 2025-05-27 Haiqi Wu , Kai Xu

In this paper, we review the concept of entropy in connection with the description of quantum unstable systems. We revise the conventional definition of entropy due to Boltzmann and extend it so as to include the presence of complex-energy…

Quantum Physics · Physics 2018-05-09 Osvaldo Civitarese , Manuel Gadella

The Von Neumann entropy of reduced states is a measure of bipartite entanglement. Despite its name, the entanglement entropy cannot by itself be used as a resource for creating thermodynamic heat flows. In order to extract heat from an…

Quantum Physics · Physics 2026-05-04 Lisa Lenstra , Jasper van Wezel

The paper analyzes the entropy of a system composed by non-interacting and indistinguishable particles whose quantum state numbers are modelled as independent and identically distributed classical random variables. The crucial observation…

Statistical Mechanics · Physics 2023-05-18 Arnaldo Spalvieri

Despite well over a century of effort, the proper expression for the classical entropy in statistical mechanics remains a subject of debate. The Boltzmann entropy (calculated from a surface in phase space) has been criticized as not being…

Statistical Mechanics · Physics 2017-09-12 Robert H. Swendsen
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