Related papers: Topological Studies related to Molecular Systems f…
During the dawn of chemistry when the temperature of the young Universe had fallen below $\sim$4000 K, the ions of the light elements produced in Big Bang nucleosynthesis recombined in reverse order of their ionization potential. With its…
The present study is devoted to the possibility that tri-atomic molecules were formed during or shortly after the Big Bang. For this purpose we consider the ordinary $H_3^{+}$ and $H_3$ and the primitive tri-atomic molecular system,…
HeH$^+$ was the first heteronuclear molecule to form in the metal-free Universe after the Big Bang. The molecule gained significant attention following its first circumstellar detection in the young and dense planetary nebula NGC 7027. We…
The sheer interstellar abundance of helium makes any bound molecules or complexes containing it of potential interest for astrophysical observation. This work utilizes high-level and trusted quantum chemical techniques to predict the…
Molecular hydrogen (H$_2$) and hydrogen deuteride (HD) are key coolants in primordial gas and regulate the formation of the first stars and proto-galaxies. Recent results from the James Webb Space Telescope provide striking insights into…
From four independent calculations using three different theoretical approaches, rate coefficients for the formation of HeH$^+$ via the radiative association of He$^+$ and H were computed. Good agreement is found between our new…
Star formation activity in molecular clouds is often found to be correlated with the amount of material above a column density threshold of $\sim 10^{22} \, {\rm cm^{-2}}$. Attempts to connect this column density threshold to a ${\it…
At early times the Universe was filled up with an extremely dense and hot gas. Due to the expansion it cooled below the binding energies of atoms which led to the formation of the first nuclei. In the physical environment of the…
In our recent papers (Kereslidze et all 2019a, 2021) a non-standard quasi-molecular mechanism was suggested and applied to treat the cosmological recombination. It was assumed that in the pre-recombination stage of evolution of the Universe…
In the framework of a quasi-molecular approach, the formation of hydrogen atom in the pre-recombination period of evolution of the universe is analysed quantitatively. Calculations in an adiabatic multi-level representation enable estimates…
HeH$^+$ belongs to the class of "reactive" ions that can be destroyed so quickly that chemical formation and destruction rates may compete with inelastic rates and should be considered when solving the statistical equilibrium equations.…
Much of what we know about molecular clouds, and by extension star formation, comes from molecular line observations. Interpreting these correctly requires knowledge of the underlying molecular abundances. Simulations of molecular clouds…
After the recombination of Hydrogen, primordial molecules such as H_2, $HD$ can be formed.The formation of structures in the post-recombination gaseous medium is commonly explained by primordial density fluctuations. In a self-gravitating…
Molecular Cloud Complexes (MCCs) are highly structured and ``turbulent''. Observational evidence suggests that MCCs are dynamically dominated systems, rather than quasi-equilibrium entities. The observed structure is more likely a…
This article is part of a series of articles trying to establish the concept Molecular Field. The theory that induced us to introduce this novel concept is based on the Born-Huang expansion as applied to the Schroedinger equation that…
It is now well known that a primordial chemistry, involving light elements produced during the nucleosynthesis period, might develop during the hydrogen post-recombination era. In particular, molecular ions and primordial molecules such as…
Context. Molecular hydrogen and its cation H+2 are among the first species formed in the early Universe, and play a key role in the thermal and chemical evolution of the primordial gas. In molecular clouds, H+2 ions formed through…
Molecular clouds (MCs) are highly structured and ``turbulent''. Colliding gas streams of atomic hydrogen have been suggested as a possible source of MCs, imprinting the filamentary structure as a consequence of dynamical and thermal…
The process of molecule formation in the primordial gas is considered in the framework of Friedmann cosmological models from redshift z=1e4 to z=0. First, a comprehensive analysis of 87 gas phase reaction rates (both collisional and…
In pre-Born-Oppenheimer (pre-BO) theory a molecule is considered as a quantum system as a whole, including the electrons and the atomic nuclei on the same footing. This approach is fundamentally different from the traditional quantum…