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In this article, we propose a generalized model for nonequilibrium vibrational energy distribution functions. The model can be used, in place of equilibrium (Boltzmann) distribution functions, when deriving reaction rate constants for…

Chemical Physics · Physics 2020-07-15 Narendra Singh , Thomas Schwartzentruber

A recombination reaction model for high-temperature chemical kinetics is derived from ab initio simulations data. A kinetic recombination rate model is derived using a recently developed ab initio state-specific dissociation model and the…

Chemical Physics · Physics 2020-09-15 Narendra Singh , Thomas Schwartzentruber

In this article, we implement a recently developed non-equilibrium chemical kinetics model \cite{singhmodeldevelopment2019} based on \textit{ab initio} simulation data and perform verification studies. Direct molecular simulation data is…

Fluid Dynamics · Physics 2020-07-15 Narendra Singh , Thomas Schwartzentruber

A kinetic model for the Boltzmann equation is proposed and explored as a practical means to investigate the properties of a dilute granular gas. It is shown that all spatially homogeneous initial distributions approach a universal…

Statistical Mechanics · Physics 2009-11-10 James W. Dufty , Aparna Baskaran , Lorena Zogaib

Combining analytical and numerical methods, we study within the framework of the homogeneous non-linear Boltzmann equation, a broad class of models relevant for the dynamics of dissipative fluids, including granular gases. We use the new…

Statistical Mechanics · Physics 2007-09-23 E. Trizac , A. Barrat , M. H. Ernst

The local balance equations for the density, momentum, and energy of a dilute gas of elastic or inelastic hard spheres, strongly confined between two parallel hard plates are obtained. The starting point is a Boltzmann-like kinetic…

Statistical Mechanics · Physics 2020-04-22 J. Javier Brey , P. Maynar , M. I. García de Soria

We calculate the frequencies and damping rates of the low-lying collective modes of a Bose-Einstein condensed gas at nonzero temperature. We use a complex nonlinear Schr\"odinger equation to determine the dynamics of the condensate atoms,…

Condensed Matter · Physics 2014-10-13 U. Al Khawaja , H. T. C. Stoof

We present a concise derivation of the Boltzmann form for single-particle energy distributions in classical many-body Hamiltonian systems. The derivation relies on two physical facts: coarse-graining-scale invariance of the empirical…

Statistical Mechanics · Physics 2026-05-26 Weicheng Fu , Yisen Wang , Yong Zhang , Hong Zhao

Boltzmann equation requires some alternative simpler kinetic model like BGK to replace the collision term. Such a kinetic model which replaces the Boltzmann collision integral should preserve the basic properties and characteristics of the…

Fluid Dynamics · Physics 2013-12-31 Ajit Kumar Mahendra , Ram Kumar Singh

The simulation of non-equilibrium electron distributions is essential for capturing light-metal interactions and therefore the study of photoabsorption, photocatalysis, laser ablation, and many other phenomena. Current methodologies, such…

Materials Science · Physics 2025-03-13 M. Uehlein , H. T. Snowden , C. Seibel , T. Held , S. T. Weber , R. J. Maurer , B. Rethfeld

A model kinetic equation is solved exactly for a special stationary state describing nonlinear Couette flow in a low density system of inelastic spheres. The hydrodynamic fields, heat and momentum fluxes, and the phase space distribution…

Statistical Mechanics · Physics 2016-08-15 M. Tij , E. E. Tahiri , J. M. Montanero , V. Garzó , A. Santos , J. W. Dufty

A general framework for the kinetic modelling of non-relativistic polyatomic gases is proposed,where each particle is characterized both by its velocity and by its internal state, and the Boltzmann collisionoperator involves suitably…

Mathematical Physics · Physics 2023-01-05 Thomas Borsoni , Marzia Bisi , Maria Groppi

We connect two different generalizations of Boltzmann's kinetic theory by requiring the same stationary solution. Non-extensive statistics can be produced by either using corresponding collision rates nonlinear in the one-particle densities…

Statistical Mechanics · Physics 2009-11-11 T. S. Biro , G. Kaniadakis

A 2-dimensional discrete Boltzmann model for combustion is presented. Mathematically, the model is composed of two coupled discrete Boltzmann equations for two species and a phenomenological equation for chemical reaction process.…

Soft Condensed Matter · Physics 2018-09-07 Chuandong Lin , Aiguo Xu , Guangcai Zhang , Yingjun Li

Two kinetic models are proposed for high-temperature rarefied (or non-equilibrium) gas flows with radiation. One of the models uses the Boltzmann collision operator to model the translational motion of gas molecules, which has the ability…

Fluid Dynamics · Physics 2023-06-28 Qi Li , Jianan Zeng , Lei Wu

In this paper, for the first time a theory is formulated that predicts velocity and spatial correlations between occupation numbers that occur in lattice gas automata violating semi-detailed balance. Starting from a coupled BBGKY hierarchy…

comp-gas · Physics 2009-10-22 H. J. Bussemaker , M. H. Ernst , J. W. Dufty

Abstact: We introduce new models of energy redistribution in stochastic chemical kinetics with several molecule types and energy parameters. The main results concern the situations when there are product form measures. Using a probabilistic…

Probability · Mathematics 2011-12-20 Guy Fayolle , Vadim Malyshev , Serguei Pirogov

We describe in detail a recently proposed lattice-Boltzmann model for simulating flows with multiple phases and components. In particular, the focus is on the modeling of one-component fluid systems which obey non-ideal gas equations of…

comp-gas · Physics 2009-10-22 Xiaowen Shan , Hudong Chen

A new kinetic theory Boltzmann-like collision term including correlations is proposed. In equilibrium it yields the one-particle distribution function in the form of a generalised-Lorentzian resembling but not being identical with the…

Plasma Physics · Physics 2009-10-31 R. A. Treumann

We consider a non-interacting one-dimensional gas accelerated by a constant and uniform external field. The energy absorbed from the field is transferred via elastic collisions to a bath of scattering obstacles. At gas-obstacle encounters…

Statistical Mechanics · Physics 2009-11-11 Jaroslaw Piasecki , Rodrigo Soto
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