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The formation of hybrid light-molecule states (polaritons) offers a new strategy to manipulate the photochemistry of molecules. To fully exploit its potential, one needs to build a toolbox of polaritonic phenomenologies that supplement…

Mesoscale and Nanoscale Physics · Physics 2018-11-20 Jacopo Fregoni , Giovanni Granucci , Emanuele Coccia , Maurizio Persico , Stefano Corni

Strong light-matter interactions are gaining importance in controlling the photoswitching behavior of molecules exhibiting bistability. Here, we used the strategy of electronic strong coupling of both the E and Z-isomers of azopyrrole…

Strong coupling of molecules to vacuum fields has been widely reported to lead to modified chemical properties such as reaction rates. However, some recent attempts to reproduce infrared strong coupling results have not been successful,…

Mesoscale and Nanoscale Physics · Physics 2024-01-03 Philip A. Thomas , Wai Jue Tan , Vasyl G. Kravets , Alexander N. Grigorenko , William L. Barnes

Entanglement control of qubits in a photoisomerizing molecule is studied in the context of an NMR quantum computer by taking azobenzene as an example. Azobenzene has two different isomers, {\it{}trans}-azobenzene (TAB) and…

Quantum Physics · Physics 2010-04-07 Taiga Yasuda , Masahito Tada-Umezaki , Mikio Nakahara , Tomonari Wakabayashi

We demonstrate that a ionising transition can be strongly coupled to a photonic resonance. The strong coupling manifests itself with the appearance of a narrow optically active resonance below the ionisation threshold. Such a resonance is…

When the interaction between a molecular system and confined light modes in an optical or plasmonic cavity is strong enough to overcome the dissipative process, hybrid light-matter states (polaritons) become the fundamental excitations in…

Mesoscale and Nanoscale Physics · Physics 2020-01-08 Yu Zhang , Tammie Nelson , Sergei Tretiak

Photonic resonances are a powerful tool for controlling light-matter interactions. However, unlocking many of the most scientifically intriguing and technologically promising phenomena requires entering the strong coupling regime, where…

Molecular strong coupling offers exciting prospects in physics, chemistry and materials science. Whilst attention has been focused on developing realistic models for the molecular systems, the important role played by the entire photonic…

The ability to control chemical reactions by coupling organic molecules to confined light in a cavity has recently attracted much attention. While most previous studies have focused on single-mode photonic or plasmonic cavities, here we…

Chemical Physics · Physics 2025-09-10 Anael Ben-Asher , Thomas Schnappinger , Markus Kowalewski , Johannes Feist

Manipulation of chemical reactivity often involves changing reagents or environmental conditions. Alternatively, strong coupling between light and matter offers a way to tunably hybridize their physicochemical properties and thereby change…

Quantum Physics · Physics 2018-11-19 Matthew Du , Raphael F. Ribeiro , Joel Yuen-Zhou

Intermolecular bonds are weak compared to covalent bonds, but they are strong enough to influence the properties of large molecular systems. In this work, we investigate how strong light-matter coupling inside an optical cavity can modify…

Chemical Physics · Physics 2021-03-17 Tor S. Haugland , Christian Schäfer , Enrico Ronca , Angel Rubio , Henrik Koch

In a first-principles study based on many-body perturbation theory, we analyze the optical excitations of azobenzene-functionalized SAMs with increasing packing density and different terminations, considering for comparison the…

Materials Science · Physics 2017-09-05 Caterina Cocchi , Claudia Draxl

The Jaynes-Cummings model, describing the interaction between a single two-level system and a photonic mode, has been used to describe a large variety of systems, ranging from cavity quantum electrodynamics, trapped ions, to superconducting…

Mesoscale and Nanoscale Physics · Physics 2013-02-05 Natsuko Ishida , Tim Byrnes , Franco Nori , Yoshihisa Yamamoto

Engineering the properties of quantum materials via strong light-matter coupling is a compelling research direction with a multiplicity of modern applications. Those range from modifying charge transport in organic molecules, steering…

The study of light-matter interaction has seen a resurgence in recent years, stimulated by highly controllable, precise, and modular experiments in cavity quantum electrodynamics (QED). The achievement of strong coupling, where the coupling…

Magnon-photon coupling has been experimentally realized inside a cavity and the emerging field known as cavity spintronics has attracted significant attention for its potential docking with quantum information science. However, one seldom…

Mesoscale and Nanoscale Physics · Physics 2020-04-27 H. Y. Yuan , Shasha Zheng , Zbigniew Ficek , Q. Y. He , Man-Hong Yung

Optical non-linearities at the single-photon level are key ingredients for future photonic quantum technologies. Prime candidates for the realization of strong photon-photon interactions necessary for implementing quantum information…

Mesoscale and Nanoscale Physics · Physics 2012-02-10 Andreas Reinhard , Thomas Volz , Martin Winger , Antonio Badolato , Kevin J. Hennessy , Evelyn L. Hu , Atac Imamoglu

We study the emission from a molecular photonic cavity formed by two proximal photonic crystal defect cavities containing a small number (<3) of In(Ga)As quantum dots. Under strong excitation we observe photoluminescence from the bonding…

In this work, we present a field-theoretic model of strongly coupled photonic molecules composed of interacting dielectric cavities in a closed, perfect-electric-conductor domain. Within this setting, we treat the resulting inter-mode…

Optics · Physics 2025-12-17 Kevin C. Smith , Austin G. Nixon , David J. Masiello

There is an increasing scientific and technological interest on the design and implementation of nanoscale sources of quantum light. Here, we investigate the quantum statistics of the light scattered from a plasmonic nanocavity coupled to a…

Mesoscale and Nanoscale Physics · Physics 2019-03-14 R. Sáez-Blázquez , J. Feist , A. I. Fernández-Domínguez , F. J. García-Vidal
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