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A method to calculate the effective spin Hamiltonian for a transition metal impurity in a non- magnetic insulating host is presented and applied to the paradigmatic case of Fe in MgO. In a first step we calculate the electronic structure…

Mesoscale and Nanoscale Physics · Physics 2015-04-03 Alejandro Ferrón , Fernando Delgado , Joaquín Fernández-Rossier

In this chapter we review the quantitative and qualitative aspects of describing the properties of magnetic solids on the basis of electronic Hamiltonian. We show that a spin Hamiltonian approach becomes consistent with an electronic…

Strongly Correlated Electrons · Physics 2016-06-17 Myung-Hwan Whangbo , Hongjun Xiang

We study the nature of spin excitations of individual transition metal atoms (Ti, V, Cr, Mn, Fe, Co and Ni) deposited on a Cu$_2$N/Cu(100) surface using both spin-polarized density functional theory (DFT) and exact diagonalization of an…

Mesoscale and Nanoscale Physics · Physics 2016-08-08 Alejandro Ferrón , Jose Luis Lado , Joaquín Fernández-Rossier

Theoretical and experimental investigation of the electronic and magnetic structure of transition metal atoms on an insulating interface with a metallic substrate at low temperatures is quite challenging. In this paper, we show a density…

Using density functional theory, we investigate the electronic and magnetic properties of $3d$ transition-metal adatoms adsorbed on a monolayer of Mn on W(110). Mn/W(110) has a noncollinear cycloidal spin-spiral ground state with an angle…

Materials Science · Physics 2020-04-15 Mara Gutzeit , Soumyajyoti Haldar , Stefan Heinze

While the ground state of magnetic materials is in general well described on the basis of spin density functional theory (SDFT), the theoretical description of finite-temperature and non-equilibrium properties require an extension beyond…

Materials Science · Physics 2022-06-22 Sergiy Mankovsky , Hubert Ebert

We have presented the synthesis, structural, and magnetic properties from the experimental point of view. Then we verified our experimental observation by studying the electronic and magnetic properties of Al-doped LaMnO3 from the first…

Materials Science · Physics 2022-11-14 Tushar Kanti Bhowmik , Saswata Halder , T. P. Sinha

Magnetism in strongly correlated honeycomb systems with $d^5$ electronic configuration has garnered significant attention due to its potential to realize the Kitaev spin liquid state, characterized by exotic properties. However, real…

Strongly Correlated Electrons · Physics 2025-11-18 Ritwik Das , Indra Dasgupta

Spin excitations play a fundamental role in understanding magnetic properties of materials, and have significant technological implications for magnonic devices. However, accurately modeling these in transition-metal and rare-earth…

Materials Science · Physics 2025-05-07 Luca Binci , Nicola Marzari , Iurii Timrov

Interacting spins in quantum magnet can cooperate and exhibit exotic states like the quantum spin liquid. To explore the materialization of such intriguing states, the determination of effective spin Hamiltonian of the quantum magnet is…

Strongly Correlated Electrons · Physics 2021-09-01 Sizhuo Yu , Yuan Gao , Bin-Bin Chen , Wei Li

We show that an individual adatom on a magnetic surface can exhibit a noncollinear spin density. Using density functional theory we study Co and Ir adatoms on a Mn monolayer on the W(110) surface which possesses a noncollinear canted spin…

Materials Science · Physics 2018-12-12 Soumyajyoti Haldar , Stefan Heinze

The development of machine learning sheds new light on the problem of statistical thermodynamics in multicomponent alloys. However, a data-driven approach to construct the effective Hamiltonian requires sufficiently large data sets, which…

Materials Science · Physics 2020-01-01 Xianglin Liu , Jiaxin Zhang , Markus Eisenbach , Yang Wang

We analyze the interplay of spin-valley coupling, orbital physics and magnetic anisotropy taking place at single magnetic atoms adsorbed on semiconducting transition-metal dichalcogenides, MX$_2$ (M = Mo, W; X = S, Se). Orbital selection…

Mesoscale and Nanoscale Physics · Physics 2017-10-12 Bin Shao , Malte Schüler , Gunnar Schönhoff , Thomas Frauenheim , Gerd Czycholl , Tim O. Wehling

Mapping the magnetic exchange interactions from model Hamiltonian to density functional theory is a crucial step in multi-scale modeling calculations. Considering the usual magnetic force theorem but with arbitrary rotational angles of the…

Materials Science · Physics 2010-11-23 Samir Lounis , Peter H. Dederichs

Electronic structure and magnetic interactions of a Tb adatom on graphene are investigated from first principles using combination of density functional theory and multiconfigurational quantum chemistry techniques including spin-orbit…

Materials Science · Physics 2024-09-13 Monirul Shaikh , Alison Klein , Aleksander L. Wysocki

The interaction between electronic and nuclear spins in the presence of external magnetic fields can be described by a spin Hamiltonian, with parameters obtained from first principles, electronic structure calculations. We describe an…

Materials Science · Physics 2019-04-10 Krishnendu Ghosh , He Ma , Vikram Gavini , Giulia Galli

Our understanding of collective spin fluctuation in materials relies largely on Heisenberg-type spin Hamiltonians. Implicit in these spin models is the atomic moment picture that in transverse spin dynamics the magnetization around an atom…

Materials Science · Physics 2024-02-13 Yihao Lin , Ji Feng

A spin Hamiltonian, which characterizes interatomic interactions between spin moments, is highly valuable in predicting and comprehending the magnetic properties of materials. A deeper understanding of the microscopic origin of magnetic…

We review our recent work on the simulation, description and prediction of spin-excitations in adatoms and dimers deposited on metallic surfaces. This work done together with Douglas L. Mills, is an extension of his seminal contribution…

Spin-wave excitations are fundamental to understanding the behavior of magnetic materials and hold promise for future information and communication technologies. Yet, modeling these accurately in transition-metal compounds remains…

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