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This chapter summarizes the properties of near-threshold molecular states that can be formed from ultracold atoms. The properties of the states for a single potential are characterized for different partial waves using the concepts of…

Atomic Physics · Physics 2009-02-11 Paul S. Julienne

In order to interpret precise measurements of molecular properties the finite nuclear mass corrections to the Born-Oppenheimer approximation have to be accounted for. It is shown that they can be obtained systematically in the perturbative…

Chemical Physics · Physics 2015-05-14 Krzysztof Pachucki

It is possible to tune the scattering length for the collision of ultra-cold 1S0 ground state alkaline-earth atoms using an optical Feshbach resonance. This is achieved with a laser far detuned from an excited molecular level near the…

Atomic Physics · Physics 2009-11-10 R. Ciurylo , E. Tiesinga , P. S. Julienne

We discuss the stability of homonuclear and heteronuclear mixtures of 3He and 4He atoms in the metastable 2^3S_1 state (He*) and predict positions and widths of Feshbach resonances by using the Asymptotic Bound-state Model (ABM). All…

Quantum Gases · Physics 2010-10-29 M. R. Goosen , T. G. Tiecke , W. Vassen , S. J. J. M. F. Kokkelmans

A theoretical approach was developed for an exact numerical description of a pair of ultracold atoms interacting via a central potential that are trapped in a three-dimensional optical lattice. The coupling of center-of-mass and…

Quantum Physics · Physics 2013-05-29 Sergey Grishkevich , Alejandro Saenz

Feshbach resonances, which allow for tuning the interactions of ultracold atoms with an external magnetic field, have been widely used to control the properties of quantum gases. We propose a~scheme for using scattering resonances as a…

One of the main limitations of cesium atomic fountains has been the cold collision frequency shift. By using a method based on a transfer of population by adiabatic passage allowing to prepare cold atomic samples with a well defined ratio…

We demonstrate high accuracy calculations for the HeH$^+$ molecule using newly developed analytic formulas for two-center two-electron integrals with exponential functions. The Born-Oppenheimer potential for the ground electronic…

Chemical Physics · Physics 2015-06-04 Krzysztof Pachucki

We report on highly accurate calculations of Born-Oppenheimer potentials for excited $n\,\Sigma^{+}$ states of the hydrogen molecule for all possible combinations of singlet/triplet and gerade/ungerade symmetries up to $n=7$. A relative…

Atomic Physics · Physics 2023-02-28 Michał Siłkowski , Magdalena Zientkiewicz , Krzysztof Pachucki

Compared to purely atomic collisions, ultracold molecular collisions potentially support a much larger number of Fano-Feshbach resonances due to the enormous number of ro-vibrational states available. In fact, for alkali-metal dimers we…

Atomic Physics · Physics 2012-10-19 Michael Mayle , Goulven Quéméner , Brandon P. Ruzic , John L. Bohn

The route toward a Bose-Einstein condensate of dipolar molecules requires the ability to efficiently associate dimers of different chemical species and transfer them to the stable rovibrational ground state. Here, we report on recent…

Other Condensed Matter · Physics 2009-05-15 G. Thalhammer , G. Barontini , J. Catani , F. Rabatti , C. Weber , A. Simoni , F. Minardi , M. Inguscio

Feshbach resonances are fundamental to interparticle interactions and become particularly important in cold collisions with atoms, ions, and molecules. Here we present the detection of Feshbach resonances in a benchmark system for strongly…

Quantum lattice solitons in a system of two ultracold bosons near Feshbach resonance are investigated. It is shown that their binding energy, effective mass, and spatial width, can be manipulated varying the detuning from the Feshbach…

Other Condensed Matter · Physics 2007-05-23 K. V. Krutitsky , D. V. Skryabin

We formulate a time-dependent density functional theory for the coupled dynamics of electrons and nuclei that goes beyond the Born-Oppenheimer (BO) approximation. We prove that the time-dependent marginal nuclear probability density…

Chemical Physics · Physics 2025-11-14 Chen Li , Ryan Requist , E. K. U. Gross

We solve a finite range two-channel model for three resonant identical bosons. The model provides a minimal description of the various magnetic Feshbach resonances in single species ultra-cold bosonic systems, including off-resonant…

Quantum Physics · Physics 2010-02-08 Mattia Jona-Lasinio , Ludovic Pricoupenko

This PhD tutorial article is a review of our experiments on heteronuclear quantum gas mixtures at the University of Hamburg. We introduce basic properties of trapped Fermi-Bose mixtures and demonstrate the achievement of large quantum…

Other Condensed Matter · Physics 2008-10-07 C. Ospelkaus , S. Ospelkaus

The coupling of a molecule and a cavity induces non-adiabaticity in the molecule which makes the description of its dynamics complicated. For polyatomic molecules, reduced-dimensional models and the use of the Born-Oppenheimer approximation…

Chemical Physics · Physics 2020-09-18 Csaba Fábri , Gábor J. Halász , Lorenz S. Cederbaum , Ágnes Vibók

We study the behavior of the Eisenbud-Wigner collisional time delay around Feshbach resonances in cold and ultracold atomic and molecular collisions. We carry out coupled-channels scattering calculations on ultracold Rb and Cs collisions.…

Atomic Physics · Physics 2019-10-23 Matthew D. Frye , Jeremy M. Hutson

We report the first creation of a bulk sample of ultracold heteronuclear p-wave Feshbach molecules in an optically trapped Bose-Bose mixture of 23Na and 87Rb atoms. Using loss spectroscopy and binding energy measurements, we systematically…

Atomic Physics · Physics 2026-05-13 Fan Jia , Zhichao Guo , Zerong Huang , Dajun Wang

We present measurements of more than 80 magnetic Feshbach resonances in collisions of ultracold $^{23}$Na$^{40}$K with $^{40}$K. We assign quantum numbers to a group of low-field resonances and show that they are due to long-range states of…

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