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Optical nonlinearities - how light-matter interactions are influenced by previous interactions with photons, are key resources in the contemporary photonics toolbox, relevant to quantum gate operations and all-optical switches. Optical…

Recent experiments and theory demonstrate that the the ground state properties and chemical reactivity of molecules can be modified inside an optical cavity. The vibrational strong or ultrastrong coupling results in the formation of…

Chemical Physics · Physics 2022-12-01 Qi Yu

We study a system of interacting matter quasiparticles strongly coupled to photons inside an optomechanical cavity. The resulting normal modes of the system are represented by hybrid polaritonic quasiparticles, which acquire effective…

Quantum Gases · Physics 2017-02-27 N. Bobrovska , M. Matuszewski , T. C. H. Liew , O. Kyriienko

Molecular polaritons within the mid-infrared regime have emerged as a source for modifying and manipulating molecular and photonic properties. However, the development of new methodologies for photon generation is still a challenge in…

Quantum Physics · Physics 2025-09-17 Arley Flórez López , Johan F. Triana , José Luis Sanz-Vicario

We investigated coherence delocalization on a coupled-cavity molecular polariton platform in time, frequency, and spatial domains, enabled by ultrafast two-dimensional infrared hyperspectral imaging. Unidirectional coherence delocalization…

Quantum Physics · Physics 2021-07-12 Bo Xiang , Zimo Yang , Yi-Zhuang You , Wei Xiong

There is growing interest in using strongly coupled organic microcavities to tune molecular dynamics, including the electronic and vibrational properties of molecules. However, very little attention has been paid to the utility of cavity…

Materials Science · Physics 2024-06-12 Bin Liu , Vinod M. Menon , Matthew Y. Sfeir

The ultrafast non-radiative relaxation of a molecular ensemble coupled to a cavity mode is considered theoretically and by real-time quantum dynamics. For equal coupling strength of single molecules to the cavity mode, the non-radiative…

Chemical Physics · Physics 2018-12-26 Oriol Vendrell

Engineering strong interactions between optical photons is a great challenge for quantum science. Envisioned applications range from the realization of photonic gates for quantum information processing to synthesis of photonic quantum…

Mesoscale and Nanoscale Physics · Physics 2019-11-26 Patrick Knüppel , Sylvain Ravets , Martin Kroner , Stefan Fält , Werner Wegscheider , Atac Imamoglu

Molecular polaritons are hybrid light-matter states that emerge when a molecular transition strongly interacts with photons in a resonator. At optical frequencies, this interaction unlocks a way to explore and control new chemical phenomena…

Fabry-Perot microcavities can strongly enhance interactions between light and molecules, leading to the formation of hybrid light-matter states known as polaritons. Polaritons possess much smaller effective masses and much larger group…

Chemical Physics · Physics 2023-10-18 Zeyu Zhou , Hsing-Ta Chen , Maxim Sukharev , Joseph E. Subotnik , Abraham Nitzan

Strong coupling between light and matter in an optical cavity provides a pathway to giant polariton nonlinearity, where effective polariton-polariton interactions are mediated by materials' nonlinear responses. The pursuit of such enhanced…

Optics · Physics 2024-11-26 Zhi Wang , Li He , Bumho Kim , Bo Zhen

We propose leveraging strong and ultrastrong light-matter coupling to efficiently generate and exchange nonclassical light and quantum matter states. Two initial conditions are considered: (a) a displaced quadrature-squeezed matter state,…

Quantum Physics · Physics 2024-10-03 Ilia Tutunnikov , Vasil Rokaj , Jianshu Cao , H. R. Sadeghpour

Molecular polaritons are the optical excitations which emerge when molecular transitions interact strongly with confined electromagnetic fields. Increasing interest in the hybrid molecular-photonic materials that host these excitations…

Mesoscale and Nanoscale Physics · Physics 2018-02-26 Raphael F. Ribeiro , Luis A. Martínez-Martínez , Matthew Du , Jorge Campos-Gonzalez-Angulo , Joel Yuen-Zhou

The realization of exciton-polaritons -- hybrid excitations of semiconductor quantum well excitons and cavity photons -- has been of great technological and scientific significance. In particular, the short-range collisional interaction…

Quantum Gases · Physics 2018-07-17 Valentin Walther , Robert Johne , Thomas Pohl

We introduce a theoretical framework that allows for the systematic and efficient description of the ultrafast nonlinear response of molecular polaritons, i.e., hybrid light-matter states, in the collective regime of large numbers of…

Quantum Physics · Physics 2025-05-22 Michael Reitz , Arghadip Koner , Joel Yuen-Zhou

We study theoretically the interaction between two photons in a nonlinear cavity. The photons are loaded into the cavity via a method we propose here, in which the input/output coupling of the cavity is effectively controlled via a tunable…

Quantum Physics · Physics 2020-04-29 Mikkel Heuck , Kurt Jacobs , Dirk R. Englund

Molecular polaritons are hybrid states of photonic and molecular character that form when molecules strongly interact with light. Strong coupling tunes energy levels and importantly, can modify molecular properties (e.g. photoreaction…

Chemical Physics · Physics 2023-02-14 Francesca Fassioli , Kyu Hyung Park , Sarah E. Bard , Gregory D. Scholes

Controlling the quantum field statistics of confined light is a long-standing goal in integrated photonics. We show that by coupling molecular vibrations with a confined mid-infrared cavity vacuum, the photocount and quadrature field…

Quantum Physics · Physics 2022-02-23 Johan F. Triana , Felipe Herrera

Cavity-polaritons in semiconductor microstructures have emerged as a promising system for exploring nonequilibrium dynamics of many-body systems. Key advances in this field, including the observation of polariton condensation,…

Mesoscale and Nanoscale Physics · Physics 2019-04-05 Aymeric Delteil , Thomas Fink , Anne Schade , Sven Höfling , Christian Schneider , Ataç Imamoğlu

We demonstrate a new type of transition within the strong coupling regime, which alters the coupling mechanism in multimode cavities. We show that this transition drastically modifies the Hamiltonian describing the polaritons, such that…

Mesoscale and Nanoscale Physics · Physics 2021-06-16 M. Balasubrahmaniyam , C. Genet , T. Schwartz
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