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An ab initio study of the electronic structures of solid metallotetrabenzoporphyrins (MTBPs) utilized in organic transistors and photovoltaics is presented. Bandstructures, densities of states, and orbitals are calculated for H2, Cu, Ni,…

Materials Science · Physics 2015-05-28 Patrick B. Shea , Jerzy Kanicki

We perform the first-principles many-body GW and Bethe-Salpeter equation (BSE) calculations on the two-dimensional hexagonal boron nitride (2D-hBN) to explore the effects of opposite atoms on the electronic structure and linear one-photon…

Materials Science · Physics 2023-01-04 You-Zhao Lan

First-principles calculations have been used to investigate the electronic and topological properties of the two-dimensional C6-2x(BN)x biphenylene network, a graphene-like structure composed of not only hexagonal ring but also octagonal…

Materials Science · Physics 2024-07-23 Guang F. Yang , Hong X. Song , Dan Wang , Hao Wang , Hua Y. Geng

We present our findings of a large-scale screening for new synthesizable materials in five M-Sn binaries, M = Na, Ca, Cu, Pd, and Ag. The focus on these systems was motivated by the known richness of M-Sn properties with potential…

Materials Science · Physics 2025-07-10 Aidan Thorn , Daviti Gochitashvili , Saba Kharabadze , Aleksey N. Kolmogorov

Hexagonal boron nitride (h-BN) has long been recognized as an ideal substrate for electronic devices due to its dangling-bond-free surface, insulating nature and thermal/chemical stability. Therefore, to analyse the lattice structure and…

Fabrication of atomic scale of metallic wire remains challenging. In present work, a nanoribbon with two parallel symmetric metallic and magnetic edges was designed from semiconductive monolayer PtS2 by employing first-principles…

Materials Science · Physics 2017-10-20 Ziran Liu , Shan Liu , Heyu Zhu , Guanghui Zhou

In this study, we investigate a novel hybrid borocarbonitrides (bpn-BCN) 2D material inspired by recent advances in carbon biphenylene synthesis, using first-principles calculations and semi-classical Boltzmann transport theory. Our…

Materials Science · Physics 2025-01-28 Ajay Kumar Parbati Senapati , Prakash Parida

In the rapidly progressing field of organometal halide perovskites, the dimensional reduction could open up new opportunities for device applications. Herein, taking the recently synthesized trimethylsulfonium lead triiodide…

Mesoscale and Nanoscale Physics · Physics 2020-06-08 Muhammad Ejaz Khan , Juho Lee , Seongjae Byeon , Yong-Hoon Kim

When monolayer graphene is crystallographically aligned to hexagonal boron nitride (BN), a moir\'e superlattice is formed, producing characteristic satellite Dirac peaks in the electronic band structure. Aligning a second BN layer to…

With the motivation of searching for new superconductors in the Mg-B system, we performed ab initio evolutionary searches for all the stable compounds in this binary system in the pressure range of 0-200 GPa. We found previously unknown,…

Superconductivity · Physics 2017-05-24 M. M. Davari Esfahani , Q. Zhu , H. Dong , A. R. Oganov , S. Wang , M. S. Rakitin , X-F. Zhou

We report a double-layer electronic system made of two closely-spaced but electrically isolated graphene monolayers sandwiched in boron nitride. For large carrier densities in one of the layers, the adjacent layer no longer exhibits a…

Wurtzite Boron Nitride ($w$BN) is a wide band gap BN polymorph with peculiar mechanical properties (hardness and stiffness). After its first synthesis in 1963 as a transformation of hexagonal BN ($h$BN) under high temperature and pressure…

Materials Science · Physics 2023-05-31 Martino Silvetti , Claudio Attaccalite , Elena Cannuccia

Polymeric nitrogen with single bonds can be created from the molecular form at high pressure and due to large energy difference between triple and single bonds it is interesting as energetic material. Its structure and properties are,…

Materials Science · Physics 2018-11-21 Dominika Melicherová , Oto Kohulák , Dušan Plašienka , Roman Martoňák

Heterostructures of two-dimensional transition metal dichalcogenides (TMDs) are emerging as a promising platform for investigating exotic correlated states of matter. Here, we propose to engineer Bose-Fermi mixtures in these systems by…

Mesoscale and Nanoscale Physics · Physics 2024-08-01 Caterina Zerba , Clemens Kuhlenkamp , Ataç Imamoğlu , Michael Knap

Two-dimensional (2D) carbon nitride materials play an important role in energy-harvesting, energy-storage and environmental applications. Recently, a new carbon nitride, 2D polyaniline (C3N) was proposed [PNAS 113 (2016) 7414-7419]. Based…

Materials Science · Physics 2016-12-13 Linyang Li , Xiangru Kong , Ortwin Leenaerts , Xin Chen , Biplab Sanyal , François M. Peeters

Non-metal nitrides are an exciting field of chemistry, featuring a significant number of compounds that can possess outstanding material properties. This characteristic relies on maximizing the number of strong covalent bonds, with…

Two-dimensional boron structures, due to the diversity of properties, attract great attention because of their potential applications in nanoelectronic devices. A series of \ce{TiB_x} ($4\leq x \leq 11$) monolayers are efficiently…

Chemical Physics · Physics 2020-08-26 Jason Yu , Jihai Liao , Yujun Zhao , Yinchang Zhao , Xiaobao Yang

We report a high-throughput ab-initio study of the thermodynamic and superconducting proper- ties of the recently synthesized XB$_3$C$_3$ clathrates. These compounds, in which boron and carbon form a sponge-like network of interconnected…

Superconductivity · Physics 2022-03-14 Simone Di Cataldo , Shadi Qulaghasi , Giovanni B. Bachelet , Lilia Boeri

The stability of atomic intercalated boron nitride K4 crystal structures, XBN (X=H, Li, Be, B, C, N, O, F, Na, Mg, Al, Si, P, S, Cl, K, Ca, Ga, Ge, As, Se, Br, Rb or Sr) is evaluated by the geometric optimization and frozen phonon…

Materials Science · Physics 2010-04-21 Masahiro Itoh , Seiichi Takami , Yoshiyuki Kawazoe , Tadafumi Adschiri

Using first-principles density functional theoretical analysis, we predict coexisting ferroelectric and semi-metallic states in two-dimensional monolayer of h-NbN subjected to electric field and in-plane strain ($\epsilon$). At strains…

Mesoscale and Nanoscale Physics · Physics 2019-07-24 Anuja Chanana , Umesh V. Waghmare