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High-resolution ac-calorimetry has been carried out on dispersions of aerosils in the liquid crystal octyloxycyanobiphenyl (8OCB) as a function of aerosil concentration and temperature spanning the crystal to isotropic phases. The…

Soft Condensed Matter · Physics 2016-08-31 A. Roshi , G. S. Iannacchione , P. S. Clegg , R. J. Birgeneau

The effects of dispersed aerosil nanoparticles on two of the phase transitions of the thermotropic liquid crystal material 4-n-pentylphenylthiol-4'-n-octyloxybenzoate 8barS5 have been studied using high-resolution x-ray diffraction…

Soft Condensed Matter · Physics 2009-11-10 P. S. Clegg , R. J. Birgeneau , S. Park , C. W. Garland , G. S. Iannacchione , R. L. Leheny , M. E. Neubert

The pretransitional behavior of dodecylcyanobiphenyl (12CB) (isotropic-smectic-A-solid mesomorphism) with $d = 50$ nm $BaTiO_3$ nanoparticles (NPs) linked the cubic phase was monitored via temperature studies of dielectric constant. Tests…

A high-resolution calorimetric study has been carried out on nano-colloidal dispersions of aerosils in the liquid crystal 4-\textit{n}-pentylphenylthiol-4'-\textit{n}-octyloxybenzoate ($\bar{8}$S5) as a function of aerosil concentration and…

Soft Condensed Matter · Physics 2009-11-11 A. Roshi , G. S. Iannacchione , P. S. Clegg , R. J. Birgeneau , M. E. Neubert

An extension to a high-order model for the direct isotropic/smectic-A liquid crystalline phase transition was derived to take into account thermal effects including anisotropic thermal diffusion and latent heat of phase-ordering.…

Soft Condensed Matter · Physics 2009-09-29 Nasser Mohieddin Abukhdeir , Alejandro D. Rey

The existence of a 'crossover region' in glass-forming liquids has long been considered as a general phenomenon that is as important as the glass transition. One potential origin for the crossover behavior is a liquid-to-liquid phase…

Materials Science · Physics 2015-09-14 S. Lan , M. Blodgett , K. F. Kelton , X. -L. Wang

A high-resolution dielectric and calorimetric study of the isotropic (I) to nematic (N) phase transition of carbon nanotube (CNT) dispersed liquid crystal (LC) functional composites as a function of CNT concentration is reported. The…

Soft Condensed Matter · Physics 2009-09-30 Rajratan Basu , Krishna P. Sigdel , Germano S. Iannacchione

The short-range order which remains when the isotropic to smectic-A transition is perturbed by a gel of silica nanoparticles (aerosils) has been studied using high-resolution synchrotron x-ray diffraction. The gels have been created…

Soft Condensed Matter · Physics 2009-11-10 M. K. Ramazanoglu , P. S. Clegg , R. J. Birgeneau , C. W. Garland , M. E. Neubert , J. M. Kim

Melting/freezing are canonical examples of discontinuous phase transitions, for which no pretransitional effects in the liquid phase are expected.For the solid phase, weak premelting effects are evidenced. This report shows long-range,…

Soft Condensed Matter · Physics 2022-07-26 Aleksander Szpakiewicz Szatan , Sylwester J. Rzoska , Aleksandra Drozd-Rzoska

By means of NMR experiment and MD computer simulation we investigate the dynamical properties of a chloroadamantane orientationally disordered crystal. We find a plastic-plastic dynamical transition at T_x ~ 330 K in the pico-nanosecond…

Materials Science · Physics 2009-10-31 F. Affouard , E. Cochin , R. Decressain , M. Descamps

The report presents pressure-related broadband dielectric spectroscopy (BDS) studies in liquid crystalline octyloxycyanbiphenyl and its nanocolloid with BaTiO3 nanoparticles, focused on the low-frequency ionic domain and the impact of…

Soft Condensed Matter · Physics 2022-10-25 J. Łoś , A. Drozd-Rzoska , S. J. Rzoska

We present a neutron scattering analysis of the structure of the smectic liquid crystal octylcyanobiphenyl (8CB) confined in one-dimensional nanopores of porous silicon films (PS). The smectic transition is completely suppressed, leading to…

Soft Condensed Matter · Physics 2016-08-16 Régis Guégan , Denis Morineau , Claude Loverdo , Wilfried Béziel , Mohammed Guendouz

Nanoconfined liquid crystals (LCs) and their nanocomposites are driving the next generation of photonic applications. Consequently, deepening our understanding of mesophase stability, defect topology, and the dynamic response of LCs at the…

A theoretical study of the variation of thermodynamic and transport properties of calamitic liquid crystals across the isotropic-nematic phase transition is carried out by calculating the {\it wavenumber (k) and time (t)} dependent…

Soft Condensed Matter · Physics 2008-02-18 Prasanth P. Jose , Biman Bagchi

In the present work, a detailed analysis of the glassy behavior and the relaxation dynamics of the liquid crystal dimer {\alpha}-(4-cyanobiphenyl-4'-yloxy)-{\omega}-(1-pyrenimine-benzylidene-4'-oxy) heptane (CBO7O.Py) throughout both…

Soft Condensed Matter · Physics 2018-10-02 David O. López , Josep Salud , María Rosario de la Fuente , Nerea Sebastián , Sergio Diez-Berart

We investigate Isotropic - Nematic transition in liquid crystal elastomers employing non-Boltzmann Monte Carlo techniques. We consider a lattice model of a liquid elastomer and Selinger-Jeon-Ratna Hamiltonian which accounts for…

Soft Condensed Matter · Physics 2007-05-23 D. Jayasri , N. Satyavathi , V. S. S. Sastry , K. P. N. Murthy

The interplay among solute and solvent molecules in lyotropic mesophases governs their physicochemical properties, such as phase behaviors and viscoelasticity. In our model system, a lyotropic chromonic liquid crystal (LCLC) made by…

Soft Condensed Matter · Physics 2024-09-10 Jiyong Cheon , Joonwoo Jeong

The nature of the melting transition in two-dimensional systems of particles has attracted considerable research attention since the development of Kosterlitz-Thouless-Halperin-Nelson-Young (KTHNY) theory. The hexatic phase proposed by this…

Other Condensed Matter · Physics 2026-05-13 Daniel Schick , Tim Matthies , Thomas Mutschler , Levente Rózsa , Ulrich Nowak

We report a high-resolution x-ray scattering study of the smectic liquid crystal octylcyanobiphenyl (8CB) confined to aligned colloidal aerosil gels. The aligned gels introduce orientational fields that promote long-range nematic order…

Disordered Systems and Neural Networks · Physics 2015-06-25 Dennis Liang , Robert L. Leheny

The influence of the shape anisotropy of magnetic particles on the isotropic-nematic phase transition was studied in ferronematics based on the nematic liquid crystal 4-(trans-4-n-hexylcyclohexyl)-isothiocyanato-benzene (6CHBT). The liquid…

Soft Condensed Matter · Physics 2014-09-08 V. Gdovinová , N. Tomašovičová , N. Éber , T. Tóth-Katona , V. Závišová , M. Timko , P. Kopčanský
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