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We analyze the role of coherent, non-perturbative system-bath interactions in a photosynthetic heat engine. Using the reaction-coordinate formalism to describe the vibrational phonon-environment in the engine, we analyze the efficiency…

Chemical Physics · Physics 2018-09-19 Melina Wertnik , Alex Chin , Franco Nori , Neill Lambert

In this work, we develop an optomechanical formalism for macroscopic quantum states in exciton-polariton systems with strong exciton-phonon interactions. We show that polariton optomechanical interactions induce dynamical backaction,…

Quantum Gases · Physics 2024-10-31 Vladislav Yu. Shishkov , Evgeny S. Andrianov , Anton V. Zasedatelev

The fast dynamics of molecular polaritonics is scrutinized theoretically through the implementation of two-dimensional spectroscopy protocols. We derive conceptually simple and computationally efficient formulas to calculate two-dimensional…

Quantum Physics · Physics 2024-03-08 Daniela Gallego-Valencia , Lars Mewes , Johannes Feist , José Luis Sanz-Vicario

Exposing a molecule to intense light pulses may bring this molecule to a nonstationary quantum state, thus launching correlated dynamics of electronic and nuclear subsystems. Although much had been achieved in the understanding of…

Chemical Physics · Physics 2024-04-11 Nikolay V. Golubev , Jiří Vaníček

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

Chemical Physics · Physics 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

Phonons, the quanta of vibrations, are very important for the equilibrium and dynamical properties of matter. GHz coherent phonons can also interact with and act as interconnects in a wide range of quantum systems. Harnessing and tailoring…

Optomechanical structures are well suited to study photon-phonon interactions, and they also turn out to be potential building blocks for phononic circuits and quantum computing. In phononic circuits, in which information is carried and…

We present a theory that efficiently describes the quantum dynamics of an electronic excitation that is coupled to a continuous, highly structured phonon environment. Based on a stochastic approach to non-Markovian open quantum systems, we…

Quantum Physics · Physics 2009-11-05 Jan Roden , Alexander Eisfeld , Wolfgang Wolff , Walter T. Strunz

A quantum system composed of a molecule and an atomic ensemble, confined in a microscopic cavity, is investigated theoretically. The indirect coupling between atoms and the molecule, realized by their interaction with the cavity radiation…

Chemical Physics · Physics 2020-05-05 Tamás Szidarovszky , Gábor J. Halász , Ágnes Vibók

Recently the possibility of generating nonclassical polariton states by means of parametric scattering has been demonstrated. Excitonic polaritons propagate in a complex interacting environment and contain real electronic excitations…

Mesoscale and Nanoscale Physics · Physics 2007-10-16 S. Portolan , O. Di Stefano , S. Savasta , F. Rossi , R. Girlanda

The dynamics of non-polar diatomic molecules interacting with a far-detuned narrow-band laser field, that only may drive rotational transitions, is studied. The rotation of the molecule is considered both classically and quantum…

Quantum Physics · Physics 2009-11-10 A. Adelswaerd , S. Wallentowitz

We show that the second-order, two-time correlation functions for phonons and photons emitted from a vibronic molecule in a thermal bath result in bunching and anti-bunching (a purely quantum effect), respectively. Signatures relating to…

Quantum Physics · Physics 2023-10-09 Ben S. Humphries , Dale Green , Magnus O. Borgh , Garth A. Jones

Ordinarily, photons do not interact with one another. However, atoms can be used to mediate photonic interactions, raising the prospect of forming synthetic materials and quantum information systems from photons. One promising approach uses…

Vibronic coupling has a dramatic influence over a large number of molecular processes, ranging from photo-chemistry, to spin relaxation and electronic transport. The simulation of vibronic coupling with multi-reference wavefunction methods…

Chemical Physics · Physics 2023-10-17 Lorenzo A. Mariano , Sourav Mondal , Alessandro Lunghi

In this article, we show that the collective light-matter strong coupling regime, where $N$ molecular emitters couple to the photon mode of an optical cavity, can be mapped to a quantum impurity model where the photon is the impurity that…

Quantum Physics · Physics 2023-10-25 Joel Yuen-Zhou , Arghadip Koner

We introduce a model description of a diatomic molecule in an optical cavity, with pump and fluorescent fields, and electron and nuclear motion are treated on equal footing and exactly. The model accounts for several optical response…

Quantum Physics · Physics 2024-05-30 Megha Gopalakrishna , Emil Viñas Boström , Claudio Verdozzi

This paper reviews recent advances in the study of strongly interacting systems of dipolar molecules. Heteronuclear molecules feature large and tunable electric dipole moments, which give rise to long-range and anisotropic dipole-dipole…

Quantum Gases · Physics 2016-07-14 Bryce Gadway , Bo Yan

We study the realization of lattice models, where cold atoms and molecules move as extra particles in a dipolar crystal of trapped polar molecules. The crystal is a self-assembled floating mesoscopic lattice structure with quantum dynamics…

Other Condensed Matter · Physics 2009-11-13 G. Pupillo , A. Griessner , A. Micheli , M. Ortner , D. -W. Wang , P. Zoller

We investigate light-matter coupling in metallic crystals where plasmons coexist with phonons exhibiting large oscillator strength. We demonstrate theoretically that this coexistence can lead to strong light-matter interactions without…

Mesoscale and Nanoscale Physics · Physics 2019-04-25 David Hagenmüller , Johannes Schachenmayer , Cyriaque Genet , Thomas W. Ebbesen , Guido Pupillo

We calculate the exact many-body time dynamics of polaritonic states supported by an optical cavity filled with organic molecules. Optical, vibrational and radiative processes are treated on an equal footing employing the Time-Dependent…

Mesoscale and Nanoscale Physics · Physics 2019-04-05 Javier del Pino , Florian A. Y. N. Schröder , Alex W. Chin , Johannes Feist , Francisco J. Garcia-Vidal