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A simple method of variational calculations of the electronic structure of a two-electron atom/ion, primarily near the nucleus, is proposed. The method as a whole consists of a standard solution of a generalized matrix eigenvalue equation,…

Atomic Physics · Physics 2024-10-08 Evgeny Z. Liverts

Photodetachment of the outer-most electrons in few- and many-electron atomic systems is studied in the non-relativistic dipole approximation. Such a photodetachment is analyzed for the neutral atoms and positively charged atomic ions. We…

Atomic Physics · Physics 2021-11-04 Alexei M. Frolov

In our work we construct a Hamiltonian, whose eigenstates approximate the solutions of the self-consistent Hartree-Fock equations for nonrelativistic atoms and ions. Its eigenvalues are given by completely algebraic expressions and the…

Quantum Physics · Physics 2025-06-18 N. Q. San , O. D. Skoromnik , V. V. Triguk , I. D. Feranchuk

The radiative self-energy correction to the bound-electron g factor of 2P_1/2 and 2P_3/2 states in one-electron ions is evaluated to order alpha (Z alpha)^2. The contribution of high-energy virtual photons is treated by means of an…

Atomic Physics · Physics 2012-07-06 U. D. Jentschura

We calculate elastic electron-deuteron scattering in a chiral effective field theory approach for few-nucleon systems based on a modified Weinberg power counting. We construct the current operators and the deuteron wave function at…

Nuclear Theory · Physics 2009-11-07 Markus Walzl , Ulf-G. Meißner

The system describing a single Dirac electron field coupled with classically moving point nuclei is presented and studied. The model is a semi-relativistic extension of corresponding time-dependent one-body Hartree-Fock equation coupled…

Analysis of PDEs · Mathematics 2019-02-05 Federico Cacciafesta , Anne-Sophie de Suzzoni , Diego Noja

We present the theory and implementation of a highly efficient relativistic third-order algebraic diagrammatic construction [ADC(3)] method based on a four-component (4c) Dirac-Coulomb (DC) Hamiltonian for the calculation of ionization…

Chemical Physics · Physics 2024-11-01 Sudipta Chakraborty , Tamoghna Mukhopadhyay , Malaya K. Nayak , Achintya Kumar Dutta

In this paper, we consider the Dirac-Hartree-Fock equations for system has many-particles. The difficulties associated with Gaussians model are likely to be more complex in relativistic Dirac-Hartree-Fock calculations. To processing these…

Atomic Physics · Physics 2019-12-11 Bilal K. Jasim , Ayad A. Al-Ani. Saad N. Abood

We study nucleon-nucleon scattering on the lattice at next-to-leading order in chiral effective field theory. We determine phase shifts and mixing angles from the properties of two-nucleon standing waves induced by a hard spherical wall in…

Nuclear Theory · Physics 2008-11-26 Bugra Borasoy , Evgeny Epelbaum , Hermann Krebs , Dean Lee , Ulf-G. Meißner

We consider the three-nucleon system within an effective theory with contact interactions at leading order in the large scattering length. We calculate the charge form factor of the triton at low momentum transfer and extract the triton…

Nuclear Theory · Physics 2009-11-11 L. Platter , H. -W. Hammer

We develop a relativistic model to describe the bound states of positive energy and negative energy in finite nuclei at the same time. Instead of searching for the negative-energy solution of the nucleon's Dirac equation, we solve the Dirac…

Nuclear Theory · Physics 2016-08-15 G. Mao , H. Stöcker , W. Greiner

The second-order Stark effect for a planar Dirac one-electron atom in the ground state is analyzed within the framework of the Rayleigh-Schr\"odinger perturbation theory, with the use of the Sturmian series expansion of the generalized…

Quantum Physics · Physics 2018-10-24 Radosław Szmytkowski

We report a new implementation of multireference algebraic diagrammatic construction theory (MR-ADC) for simulations of electron attachment and ionization in strongly correlated molecular systems (EA/IP-MR-ADC). Following our recent work on…

Chemical Physics · Physics 2021-01-19 Koushik Chatterjee , Alexander Yu. Sokolov

The work is devoted to studying some new classical electrodynamics models of interacting charged point particles and the aspects of the quantization via the Dirac procedure related to them. Based on the vacuum field theory no-geometry…

Mathematical Physics · Physics 2009-10-07 N. N. Bogolubov , A. K. Prykarpatsky

We present a novel theory and implementation for computing coupled electronic and quantal nuclear subsystems on a single potential energy surface, moving beyond the standard Born-Oppenheimer (BO) separation of nuclei and electrons. We…

Chemical Physics · Physics 2021-11-15 Ziyong Chen , Jun Yang

We model a single-electron ion (hydrogenic atom) as a static, spherically symmetric electrovacuum spacetime in which the nucleus is treated as a timelike line-singularity and the electron is treated as a test particle following Dirac's…

Mathematical Physics · Physics 2020-09-28 Moulik Kallupalam Balasubramanian

Electron density is a fundamental quantity, which can in principle determine all ground state electronic properties of a given system. Although machine learning (ML) models for electron density based on either an atom-centered basis or a…

Chemical Physics · Physics 2024-10-08 Chaoqiang Feng , Yaolong Zhang , Bin Jiang

A non-linear non-perturbative relativistic atomic theory introduces spin in the dynamics of particle motion. The resulting energy levels of Hydrogen atom are exactly same as the Dirac theory. The theory accounts for the energy due to…

General Physics · Physics 2014-11-26 Vikram H. Zaveri

We present an efficient implementation of the second- and third-order single-reference algebraic diagrammatic construction theory for electron attachment (EA) and ionization (IP) energies and spectra (EA/IP-ADC(n), n = 2, 3). Our new…

Chemical Physics · Physics 2021-07-12 Samragni Banerjee , Alexander Yu. Sokolov

We deal with the problem of studying the effective theories and the symmetries of long-range models around critical points. We focus in particular on the Kitaev chain with long-range pairings decaying with distance as power-law with…

Strongly Correlated Electrons · Physics 2016-08-30 Luca Lepori , Davide Vodola , Guido Pupillo , Giacomo Gori , Andrea Trombettoni