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The dispersion relation for noninteracting excitons and the influence of perturbative correction is examined in the case of pentacene structure. The values of exchange integrals are determined by the nonlinear fits to the experimental…

Strongly Correlated Electrons · Physics 2018-11-09 Sonja Gombar , Petar Mali , Milan Pantić , Milica Pavkov-Hrvojević , Slobodan Radošević

We have examined the singlet excitons in two representatives of acene-type (tetracene and pentacene) and phenacene-type (chrysene and picene) molecular crystals, respectively, using electron energy-loss spectroscopy at low temperatures. We…

We have studied the low-energy electronic excitations of solid picene at 20 K using momentum dependent electron energy-loss spectroscopy. Our results demonstrate the presence of five excitonic features below the transport energy gap of…

Materials Science · Physics 2011-04-28 Friedrich Roth , Benjamin Mahns , Bernd Büchner , Martin Knupfer

Excitonic effects due to the correlation of electrons and holes in excited states of matter dominate the optical spectra of many interesting materials. They are usually studied in the long-wavelength limit. Here we investigate excitons at…

Materials Science · Physics 2023-04-18 Vitaly Gorelov , Lucia Reining , Matteo Gatti

The deuteron-proton elastic scattering is studied in the multiple scattering expansion formalism. The contributions of the one-nucleon-exchange, single- and double scattering are taken into account. The Love and Franey parameterization of…

Nuclear Theory · Physics 2009-11-05 N. B. Ladygina

Understanding the nature of molecular excitons in low-dimensional molecular solids is of paramount importance in fundamental photophysics and various applications such as energy harvesting, switching electronics and display devices. Despite…

Materials Science · Physics 2023-05-18 Dogyeong Kim , Sol Lee , Jiwon Park , Jinho Lee , Hee Cheul Choi , Kwanpyo Kim , Sunmin Ryu

We theoretically investigate an exciton transfer process in a donor domain of organic photovoltaic cells focusing on the roles of local and nonlocal electron-phonon interactions. Our model consists of a three-level system described by the…

Materials Science · Physics 2021-01-25 Mauro Cainelli , Yoshitaka Tanimura

We propose a theory of interference contributions to the two-dimensional exciton diffusion coefficient. The theory takes into account four spin states of the heavy-hole exciton. An interplay of the single particle, electron and hole, spin…

Mesoscale and Nanoscale Physics · Physics 2016-04-13 M. V. Durnev , M. M. Glazov

We have carried out electron energy-loss investigations of the lowest singlet excitons in pentacene at 20 K. Our studies allow to determine the full exciton band structure in the a*,b* reciprocal lattice plane. The lowest singlet exciton…

Materials Science · Physics 2012-06-01 Friedrich Roth , Roman Schuster , Andreas König , Martin Knupfer , Helmuth Berger

We present an ab initio study of electronically excited states of three-dimensional solids using Gaussian-based periodic equation-of-motion coupled-cluster theory with single and double excitations (EOM-CCSD). The explicit use of…

Materials Science · Physics 2020-01-31 Xiao Wang , Timothy C. Berkelbach

Exciton dynamics, lifetimes and scattering are directly related to the exciton dispersion, or bandstructure. While electron and phonon bandstructures are well understood and can be easily calculated from first principles, the exciton…

Materials Science · Physics 2021-10-04 Diana Y. Qiu , Galit Cohen , Dana Novichkova , Sivan Refaely-Abramson

Excitons dominate the optoelectronic response of many materials. Depending on the time scale and host material, excitons can exhibit free diffusion, phonon-limited diffusion, or polaronic diffusion, and exciton transport often limits the…

Mesoscale and Nanoscale Physics · Physics 2026-01-28 Joshua J. P. Thompson , Wojciech J. Jankowski , Robert-Jan Slager , Bartomeu Monserrat

Understanding the dynamics of excitons in two dimensional semiconductors requires a theory that incorporates the essential physics distinct from their three-dimensional counterparts. In addition to the modified dielectric environment,…

Mesoscale and Nanoscale Physics · Physics 2019-01-30 Pengke Li , Ian Appelbaum

Low-dimensional materials differ from their bulk counterpart in many respects. In particular, the screening of the Coulomb interaction is strongly reduced, which can have important consequences such as the significant increase of exciton…

The concept of an exciton as a quasiparticle that represents collective excited states was originally adapted from solid-state physics and has been successfully applied to molecular aggregates by relying on the well-established limits of…

Chemical Physics · Physics 2026-01-01 Seogjoo J. Jang , Irene Burghardt , Chao-Ping Hsu , Christopher J. Bardeen

Two-dimensional perovskites, in which inorganic layers are stabilized by organic spacer molecules, are attracting increasing attention as a more robust analogue to the conventional three-dimensional metal-halide perovskites. However,…

Excitons in semiconductors can form a variety of collective states leading to different regimes of exciton propagation. Here we theoretically demonstrate the possibility to reach the viscous hydrodynamic -- liquid-like -- regime of exciton…

Mesoscale and Nanoscale Physics · Physics 2024-10-23 V. N. Mantsevich , M. M. Glazov

Self-assembled aggregates of pigment molecules are potential building blocks for excitonic circuits that find their application in energy conversion and optical signal processing. Recent experimental studies of one-dimensional…

Mesoscale and Nanoscale Physics · Physics 2017-10-03 Semion K. Saikin , Mars A. Shakirov , Christoph Kreisbeck , Uri Peskin , Yurii N. Proshin , Alan Aspuru-Guzik

Dirac particles, massless relativistic entities, obey linear energy dispersions and hold important implication in particle physics. Recent discovery of Dirac fermions in condensed matter systems including graphene and topological insulators…

Mesoscale and Nanoscale Physics · Physics 2015-06-11 Na Young Kim , Kenichiro Kusudo , Andreas Loeffler , Sven Hoefling , Alfred Forchel , Yoshihisa Yamamoto

The interplay of optics, dynamics and transport is crucial for the design of novel optoelectronic devices, such as photodetectors and solar cells. In this context, transition metal dichalcogenides (TMDs) have received much attention. Here,…

Mesoscale and Nanoscale Physics · Physics 2019-11-04 Raul Perea-Causin , Samuel Brem , Roberto Rosati , Roland Jago , Marvin Kulig , Jonas D. Ziegler , Jonas Zipfel , Alexey Chernikov , Ermin Malic
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