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We revisit the classical problem of flow of electrolyte solutions through charged capillary nanopores or nanotubes as described by the capillary pore model (also called "space charge" theory). This theory assumes very long and thin pores…

Chemical Physics · Physics 2019-08-16 P. B. Peters , R. van Roij , M. Z. Bazant , P. M. Biesheuvel

We present a broad family of high-order finite element algorithms for simulating the flow of electroneutral electrolytes. The governing partial differential equations that we solve are the electroneutral…

Numerical Analysis · Mathematics 2026-03-31 Aaron Baier-Reinio , Patrick E. Farrell , Charles W. Monroe

We consider a coupled system of Navier-Stokes and Nernst-Planck equations, describing the evolution of the velocity and the concentration fields of dissolved constituents in an electrolyte solution. Motivated by recent applications in the…

Analysis of PDEs · Mathematics 2012-06-12 Dieter Bothe , André Fischer , Jürgen Saal

Transport of electrolytic solutions under influence of electric fields occurs in phenomena ranging from biology to geophysics. Here, we present a continuum model for single-phase electrohydrodynamic flow, which can be derived from…

Fluid Dynamics · Physics 2020-06-30 Gaute Linga , Asger Bolet , Joachim Mathiesen

The transport and distribution of charged particles are crucial in the study of many physical and biological problems. In this paper, we employ an Energy Variational Approach to derive the coupled Poisson-Nernst-Planck-Navier-Stokes system.…

Fluid Dynamics · Physics 2014-10-14 Shixin Xu , Ping Sheng , Chun Liu

In this letter we analyze the effects of an externally applied electric field on thermal fluctuations for a fluid containing charged species. We show in particular that the fluctuating Poisson-Nernst-Planck equations for charged…

A systematic theoretical study of thermoelectric effect and temperature-gradient-driven electrokinetic flow of electrolyte solutions in charged nanocapillaries is presented. The study is based on a semianalytical model developed by…

Fluid Dynamics · Physics 2023-09-14 Wenyao Zhang , Qiuwang Wang , Min Zeng , Cunlu Zhao

We present an efficient and robust numerical model for simulation of electrokinetic phenomena in porous networks over a wide range of applications including energy conversion, desalination, and lab-on-a-chip systems. Coupling between fluid…

Fluid Dynamics · Physics 2016-10-04 Shima Alizadeh , Ali Mani

This study has numerically investigated the charge-heterogeneity effects in the electroviscous flow of symmetric ($1$:$1$) electrolyte liquid through a uniform slit microfluidic device. The Poisson's, Nernst-Planck (N-P), Navier-Stokes…

Fluid Dynamics · Physics 2024-09-26 Jitendra Dhakar , Ram Prakash Bharti

The description of electron-electron interactions in transport problems is both analytically and numerically difficult. Here we show that a much simpler description of electron transport in the presence of interactions can be achieved in…

Strongly Correlated Electrons · Physics 2009-11-11 Roberto D'Agosta , Massimiliano Di Ventra

We analyze the transport properties of a low density ensemble of identical macroscopic particles immersed in an active fluid. The particles are modeled as inelastic hard spheres (granular gas). The non-homogeneous active fluid is modeled by…

Soft Condensed Matter · Physics 2017-10-17 Francisco Vega Reyes , Antonio Lasanta

We consider hydrodynamic electron transport in the Hall-bar geometry. The theory is developed for systems with non-Galilean-invariant electron liquids. We show that inhomogeneity of the electron density induced by long-range disorder and…

Mesoscale and Nanoscale Physics · Physics 2022-04-27 Songci Li , A. V. Andreev , Alex Levchenko

We present a method to embed local electroneutrality within Onsager-Stefan-Maxwell electrolytic-transport models, circumventing their formulation as differential systems with an algebraic constraint. Flux-explicit transport laws are…

Fluid Dynamics · Physics 2022-11-28 Alexander Van-Brunt , Patrick E. Farrell , Charles W. Monroe

This work presents a finite element method for a modified Poisson-Nernst-Planck/Navier-Stokes (PNP/NS) model under the mechanical equilibrium, developed for compressible electrolytes. Another key contribution of this work is the reduction…

Numerical Analysis · Mathematics 2026-01-27 Ankur , Ram Jiwari , Satyvir Singh

Seemingly unrelated experiments such as electrolyte transport through nanotubes, nano-scale electrochemistry, NMR relaxometry and Surface Force Balance measurements, all probe electrical fluctuations: of the electric current, the charge and…

A model is developed for describing the transport of charged colloidal particles in an evaporating sessile droplet on the electrified metal substrate in the presence of a solvent flow. The model takes into account the electric charge of…

Soft Condensed Matter · Physics 2022-03-16 Semen V. Zavarzin , Andrei L. Kolesnikov , Yury A. Budkov , Lev Yu. Barash

The resistance of hydrogen-bond networks to ambient flow in water produces viscoelectric stresses and contributes to electrostrictive pressure. Within Onsager's nonequilibrium thermodynamic framework, a lattice-gas description of aqueous…

Soft Condensed Matter · Physics 2026-03-16 Pramodt Srinivasula

The paper presents a mean field theory of electrolyte solutions, extending the classical Debye-H\"{u}ckel-Onsager theory to provide a detailed description of the electrical conductivity in strong electrolyte solutions. The theory…

Soft Condensed Matter · Physics 2024-09-27 N. N. Kalikin , Yu. A. Budkov

The integration of the coupling effects of intrinsic wettability and surface charge in a nanochannel can cause non-intuitive behavior in the electrokinetic energy conversion processes. We demonstrate that in a nanofluidic device the energy…

Fluid Dynamics · Physics 2015-11-12 Chirodeep Bakli , Suman Chakraborty

We develop the theory of hydrodynamic electron transport in a long-range disorder potential for conductors in which the underlying electron liquid lacks Galilean invariance. For weak disorder, we express the transport coefficients of the…

Mesoscale and Nanoscale Physics · Physics 2020-08-19 Songci Li , Alex Levchenko , A. V. Andreev
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