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We present exact analytical and numerical results for the electronic spectra and the Friedel oscillations around a substitutional impurity atom in a graphene lattice. A chemical dopant in graphene introduces changes in the on-site potential…

This paper is devoted to development of perturbation theory for studying the properties of graphene sheet of finite size, at nonzero temperature and chemical potential. The perturbation theory is based on the tight-binding Hamiltonian and…

Strongly Correlated Electrons · Physics 2015-12-16 N. Yu. Astrakhantsev , V. V. Braguta , M. I. Katsnelson

Graphene is thought to be a promising materials for many applications. However, pristine graphene is not suitable for most electrochemical devices, where defect engineering is crucial for its performance. We demonstrate how boron doping of…

Materials Science · Physics 2023-07-07 Milica S. Ritopečki , Natalia V. Skorodumova , Ana S. Dobrota , Igor A. Pašti

Graphene placed in a magnetic field possesses an extremely high mid/far-infrared optical nonlinearity originating from its unusual band structure and selection rules for the optical transitions near the Dirac point. Here we study the linear…

Mesoscale and Nanoscale Physics · Physics 2016-11-26 Xianghan Yao , Alexey Belyanin

We propose a mechanism by which chloromethane and dichloromethane decomposition reaction occurs on the surfaces of graphene. To this end we have performed calculations on the graphene surface with metal adsorption on the sheet on the…

Chemical Physics · Physics 2016-02-23 Y. P. Ortiz , A. F. Jalbout

We evaluate the autocorrelation function of the electrostatic potential in doped graphene due to nearby charged impurities. The screening of those impurities is described by a combination of the polarization function for graphene in random…

Materials Science · Physics 2013-10-25 Rastko Anicic , Zoran Miskovic

We have performed a thorough computational study to assess the accuracy of density functional theory (DFT) methods in describing the interactions of CO2 with model alkali-earth-metal (AEM, Ca and Li) decorated carbon structures, namely…

Materials Science · Physics 2013-01-15 Claudio Cazorla , Stephen A. Shevlin

Graphene is one of the stiffest known materials, with a Young's modulus of 1 TPa, making it an ideal candidate for use as a reinforcement in high-performance composites. However, being a one-atom thick crystalline material, graphene poses…

Materials Science · Physics 2010-07-13 L. Gong , I. A. Kinloch , R. J. Young , I. Riaz , R. Jalil , K. S. Novoselov

Graphene's intrinsically corrugated and wrinkled topology fundamentally influences its electronic, mechanical, and chemical properties. Experimental techniques allow the manipulation of pristine graphene and the controlled production of…

Materials Science · Physics 2025-09-09 Fabian L. Thiemann , Patrick Rowe , Andrea Zen , Erich A. Müller , Angelos Michaelides

A general theory is developed to describe graphene with arbitrary number of isolated impurities. The theory provides a basis for an efficient numerical analysis of the charge transport and is applied to calculate the minimal conductivity of…

Mesoscale and Nanoscale Physics · Physics 2011-03-28 P. M. Ostrovsky , M. Titov , S. Bera , I. V. Gornyi , A. D. Mirlin

We aim to understand how the van der Waals force between neutral adatoms and a graphene layer is modified by uniaxial strain and electron correlation effects. A detailed analysis is presented for three atoms (He, H, and Na) and graphene…

Mesoscale and Nanoscale Physics · Physics 2016-05-11 Nathan S. Nichols , Adrian Del Maestro , Carlos Wexler , Valeri N. Kotov

It is shown that it is now possible to include van der Waals interactions via a nonempirical implementation of density functional theory to describe the correlation energy in electronic structure calculations on infinite systems of no…

Materials Science · Physics 2009-11-11 Svetla D. Chakarova Kack , Elsebeth Schroder , Bengt I. Lundqvist , David C. Langreth

Graphene-water interaction has been under scrutiny ever since graphene discovery and realization of its exceptional properties. Several computational and experimental reports exist that have tried to look into the interactions involved,…

Materials Science · Physics 2020-02-19 Priyanka Solanky , Vidushi Sharma , Kamalika Ghatak , Jatin Kashyap , Dibakar Datta

The problem of a magnetic impurity, atomic or molecular, absorbed on top of a carbon atom in otherwise clean graphene is studied using the numerical renormalization group. The spectral, thermodynamic, and scattering properties of the…

Strongly Correlated Electrons · Physics 2009-01-27 P. S. Cornaglia , Gonzalo Usaj , C. A. Balseiro

Minimal conductivity of a single undoped graphene layer is known to be of the order of the conductance quantum, independent of the electron velocity. We show that this universality does not survive electron-electron interaction which…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 E. G. Mishchenko

We propose a model based on density functional theory (DFT) and quantum electrodynamics (QED) to study the dynamical characteristics of graphene quantum dots (GQDs). We assume the GQD edges are saturated with hydrogen atoms, effectively…

Mesoscale and Nanoscale Physics · Physics 2026-04-09 J. Olivo , J. Blengino Albrieu , Mauro Cuevas

The optical properties of graphene are strongly affected by electron-electron (e-e) and electron-hole (e-h) interactions. Here we tune these many-body interactions through varying the density of free charge carriers. Measurements from the…

Understanding strongly correlated systems is essential for advancing quantum chemistry and materials science, yet conventional methods like Density Functional Theory (DFT) often fail to capture their complex electronic behavior. To address…

Chemical Physics · Physics 2025-09-01 Archith Rayabharam , N. R. Aluru

The physical processes occurring in the presence of disorder: point defects, grain boundaries, etc. may have detrimental effects on the electronic properties of graphene. Here we present an approach to reveal the grain structure of graphene…

Recent atomic force microscopy (AFM) experiments~[ACS Nano {\bf 2014}, 8, 12410-12417] conducted on graphene-coated SiO$_2$ demonstrated that monolayer graphene (G) can effectively screen dispersion van der Waals (vdW) interactions deriving…

Materials Science · Physics 2018-06-13 Alberto Ambrosetti , Pier Luigi Silvestrelli