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A combination of numerical and analytical methods is employed to study a one-dimensional chain of identical atoms with adsorbates. We show that the electron-mediated interaction energy between two impurities can change sign and magnitude…

Mesoscale and Nanoscale Physics · Physics 2019-06-25 Aleksandr Rodin , Keian Noori , Su Ying Quek

Hydrogen adatoms on graphene are investigated using DFT and analytical approaches. We demonstrate that the level of lattice deformation due to the hydrogen adsorption does not substantially change the coupling between the graphene $p_{z}$…

Materials Science · Physics 2020-11-18 Keian Noori , Su Ying Quek , Aleksandr Rodin

The chapter combines analytical (statistical-thermodynamic and kinetic) with numerical (Kubo-Greenwood-formalism-based) approaches used to ascertain an influence of the configurations of point (impurities, vacancies) and line (grain…

Mesoscale and Nanoscale Physics · Physics 2014-06-04 T. M. Radchenko , V. A. Tatarenko , I. Yu. Sagalianov , Yu. I. Prylutskyy

We introduce a computationally efficient method based on the path integral formalism to describe defect-modified graphene. By taking into account the entire Brillouin zone, our approach respects the lattice symmetry and can be used to…

Mesoscale and Nanoscale Physics · Physics 2022-11-23 Hillol Biswas , Harshitra Mahalingam , Aleksandr Rodin

We review the problem of adatoms in graphene under two complementary points of view, scattering theory and strong correlations. We show that in both cases impurity atoms on the graphene surface present effects that are absent in the physics…

We propose a mechanism to control the interaction between adsorbates on graphene. The interaction between a pair of adsorbates---the change in adsorption energy of one adsorbate in the presence of another---is dominated by the interaction…

Mesoscale and Nanoscale Physics · Physics 2013-09-13 Dmitry Solenov , Chad Junkermeier , Thomas L. Reinecke , Kirill A. Velizhanin

The interaction of two resonant impurities in graphene has been predicted to have a long-range character with weaker repulsion when the two adatoms reside on the same sublattice and stronger attraction when they are on different…

Mesoscale and Nanoscale Physics · Physics 2015-07-14 S. LeBohec , J. Talbot , E. G. Mishchenko

The effective spin exchange coupling between impurities (adatoms) on graphene mediated by conduction electrons is studied as a function of the strength of the potential part of the on-site energy $U$ of the electron-adatom interaction. With…

Mesoscale and Nanoscale Physics · Physics 2017-02-15 M. Agarwal , E. G. Mishchenko

The present manuscript summarizes the modern view on the problem of the graphene-metal interaction. Presently, the close-packed surfaces of d metals are used as templates for the preparation of highly-ordered graphene layers. Different…

Materials Science · Physics 2017-08-23 E. N. Voloshina , Yu. S. Dedkov

We outline a Kohn-Sham-Dirac density-functional-theory (DFT) scheme for graphene sheets that treats slowly-varying inhomogeneous external potentials and electron-electron interactions on an equal footing. The theory is able to account for…

Strongly Correlated Electrons · Physics 2008-09-23 Marco Polini , Andrea Tomadin , Reza Asgari , A. H. MacDonald

We theoretically investigate the impurity levels and exchange interaction between magnetic impurities in graphene driven by an off-resonant circularly polarized light field. Our analysis captures the non-perturbative effects resulting from…

Mesoscale and Nanoscale Physics · Physics 2022-08-29 Modi Ke , Wang-Kong Tse

This paper reviews the theoretical work undertaken using density functional theory (DFT) to explore graphene's interactions with its surroundings. We look at the impact of substrates, gate dielectrics and edge effects on the properties of…

Mesoscale and Nanoscale Physics · Physics 2012-07-31 Priyamvada Jadaun , Bhagawan R. Sahu , Leonard F. Register , Sanjay K. Banerjee

The ground-state and the transport properties of graphene subject to the potential of in-plane charged impurities are studied. The screening of the impurity potential is shown to be nonlinear, producing a fractal structure of electron and…

Mesoscale and Nanoscale Physics · Physics 2009-12-02 M. M. Fogler

The electronic transport properties of single layer graphene having a dilute coating of indium adatoms has been investigated. Our studies establish that isolated indium atoms donate electrons to graphene and become a source of charged…

Mesoscale and Nanoscale Physics · Physics 2019-12-11 U. Chandni , Erik A. Henriksen , J. P. Eisenstein

Though weak surface interactions and adsorption can play an important role in plasma processing and materials science, they are not necessarily simple to model. A boron adatom adsorbed on a graphene sheet serves as a case study for how…

Computational Physics · Physics 2024-01-08 S. Jubin , A. Rau , Y. Barsukov , S. Ethier , I. D. Kaganovich

The influence of hydrated cation-{\pi} interaction forces on the adsorption and filtration capabilities of graphene-based membrane materials is significant. However, the lack of interaction potential between hydrated Cs+ and graphene limits…

Computational Physics · Physics 2024-12-02 Yangjun Qin , Liuhua Mu , Xiao Wan , Zhicheng Zong , Tianhao Li , Nuo Yang

In this work, we investigate dispersion interactions in a selection of atomic, molecular, and molecule-surface systems, comparing high-level correlated methods with empirically-corrected density functional theory (DFT). We assess the…

Chemical Physics · Physics 2021-01-27 Tyler J. Hughes , Robert A. Shaw , Salvy P. Russo

We analyse the interaction between charges and graphene layers. The electric polarisability of graphene induces a force, that can be described by an image charge. The analysis shows that graphene can be described as an imperfect conductor…

Mesoscale and Nanoscale Physics · Physics 2016-05-27 Francisco Guinea , Niels R. Walet

We first demonstrate how two-dimensional sheets are incorporated in the formalism for planar structures. Then we derive the interaction in the geometry of two free-standing graphene sheets and of one graphene sheet above a substrate.…

Mesoscale and Nanoscale Physics · Physics 2012-05-15 Bo E. Sernelius

Vacancies in graphene present sites of altered chemical reactivity and open possibilities to tune graphene properties by defect engineering. The understanding of chemical reactivity of such defects is essential for successful implementation…

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