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A new process for obtaining the ethyl esters of volatile fatty acids with ethanol by using aluminium chloride hexahydrate as a catalyst is proposed. Aluminium chloride not only exhibits good activity, composition equilibrium is achieved…

Chemical Physics · Physics 2020-03-18 Luigi di Bitonto , Sandro Menegatti , Carlo Pastore

Sucrose esters (SEs), derived from sucrose and fatty acids, are biodegradable and non-toxic surfactants increasingly favored as substitutes for petrochemically-synthesized ones in food, cosmetics, and pharmaceuticals. SEs provide versatile…

Soft Condensed Matter · Physics 2025-05-12 Diana Cholakova , Slavka Tcholakova

Trehalose diesters exhibiting $\alpha$,$\omega$-unsaturation are glycolipids which can be easily polymerized by ADMET (acyclic diene metathesis) polymerization. In this paper, enzymatic esterification was performed to selectively esterify…

Applied Physics · Physics 2019-11-22 Geoffrey Hibert , Etienne Grau , Didier Pintori , Sébastien Lecommandoux , Henri Cramail

Background: the stability of serum specimen during time storage is importance in clinical and medical science researches in addition of diagnosis. Lipids are organic molecules that classified into 8 classes: fatty acids, phospholipids,…

Biomolecules · Quantitative Biology 2023-11-14 Mohammed Mahdi Sami , Mataz J. Jamai , Bushra A. Jassam

Preparation of nanoemulsions of triglyceride oils in water usually requires high mechanical energy and sophisticated equipment. Recently, we showed that alpha-to-beta (viz. gel-to-crystal) phase transition, observed with most lipid…

Soft Condensed Matter · Physics 2021-07-07 Diana Cholakova , Desislava Glushkova , Slavka Tcholakova , Nikolai Denkov

To substitute petroleum-based materials with bio-based alternatives, microbial fermentation combined with inexpensive biomass is suggested. In this study Saccharina latissima hydrolysate, candy-factory waste, and digestate from full-scale…

Vegetable oil based hybrid films were developed thanks to a novel solvent- and heating- free method at the air-water interface using silylated castor oil cross-linked via a sol-gel reaction. To understand the mechanism of the hybrid film…

We describe several unexpected phenomena, caused by a solid-solid phase transition (gel-to-crystal) typical for all main classes of lipid substances - phospholipids, triglycerides, diglycerides, alkanes, etc. We discovered that this…

Materials Science · Physics 2020-08-26 Diana Cholakova , Desislava Glushkova , Slavka Tcholakova , Nikolai Denkov

The use of biodegradable polymers simplifies the development of therapeutic devices with regards to transient implants and three-dimensional platform suitable for tissue engineering. Further advances have also occurred in the controlled…

Biomolecules · Quantitative Biology 2023-01-27 Mohammad Anwar Ul Alam , Aschalew Kassu , Lamin Kassama

In literature it has been reported that the gamma-phase PVDF film is formed from dimethyl sulfoxide (DMSO) solvents regardless of preparation temperature. In this report the crystallization of both alpha and gamma phase from DMSO solvent by…

Materials Science · Physics 2008-08-05 S. Satapathy , P. K. Gupta , Santosh Pawar , K. B. R. Varma

This study proposes a novel design of glucose sensor with enhanced selectivity and sensitivity by using graphene Schottky diodes, which is composed of Graphene (G)/Platinum Oxide (PtO)/n-Silicon (Si) heterostructure. The sensor was tested…

Applied Physics · Physics 2020-01-01 Mahmoud A. Sakr , Karim Elgammal , Anna Delin , Mohamed Serry

Lanthanides ($Ln$) are notoriously difficult to intercalate into graphite. We investigated the possibility of using Na to catalyze the formation of $Ln$-intercalated graphite and successfully synthesized $Ln$C$_6$ ($Ln$ = Sm, Eu, and Yb)…

Li3VO4/C composites have been synthesized by a sol-gel method and post-annealing at 650 {\deg}C for 1 h in N2 flow using either tartaric acid, malic acid, or glucose as both chelating agents and carbon source. The presence of these organic…

Materials Science · Physics 2020-12-17 E. Thauer , G. S. Zakharova , S. A. Wegener , Q. Zhu , R. Klingeler

We build a model for the hepatic fatty acid metabolism and its metabolic and genetic regulations. The model has two functioning modes: synthesis and oxidation of fatty acids. We provide a sufficient condition (the strong lipolytic…

Cell Behavior · Quantitative Biology 2007-05-23 O. Radulescu , A. Siegel , E. Pecou , S. Lagarrigue

Titanic acid nanotubes (with a chemical formula H2Ti2O4(OH)2, abbreviated as TANTs) were synthesized by the hydrothermal method using commercial TiO2 nanoparticle powder (P25, Degussa, Germany) including anatase and rutile phase as a…

Materials Science · Physics 2011-06-15 Baoli Tian , Xing Zhang , Shuxi Dai , Ke Cheng , Zhensheng Jin , Yabin Huang , Zuliang Du , Guangtian Zou , Bingsuo Zou

Plastic scintillators that can discriminate between gamma rays, fast neutrons, and thermal neutrons were synthesized and characterized while considering the balance between processing and performance at the kilogram scale. These trade-offs…

Ethanolamine (EA), a key component of phospholipids, has recently been detected in the interstellar medium within molecular clouds. To understand this observation, laboratory studies of its formation and destruction are essential and should…

Astrophysics of Galaxies · Physics 2025-03-06 T. Suhasaria , S. M. Wee , R. Basalgète , S. Krasnokutski , C. Jäger , K. Schwarz , Th. Henning

We have investigated the photodynamics of $\beta$-D-glucose employing our field-induced surface hopping method (FISH), which allows us to simulate the coupled electron-nuclear dynamics, including explicitly nonadiabatic effects and…

Chemical Physics · Physics 2018-03-20 Jens Petersen , Joachim O. Lindner , Roland Mitric

MoO2/C-composites have been fabricated for the first time by a tartaric acid/glucose-assisted sol-gel method with post-annealing at 500 {\deg}C for 1 h in N2 flow. The synthesized materials were fully characterized with respect to…

Materials Science · Physics 2020-12-11 G. S. Zakharova , L. Singer , Z. A. Fattakhova , S. Wegener , E. Thauer , Q. Zhu , E. V. Shalaeva , R. Klingeler

Glucose oxidation is a key reaction in biosensing and energy conversion, with anodized copper electrodes showing great potential as catalysts for its enhancement. This study explores the relationship between anodization parameters and…

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