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We report on a method to fabricate and measure gateable molecular junctions which are stable at room temperature. The devices are made by depositing molecules inside a few-layer graphene nanogap, formed by feedback controlled…

We present batch-fabricated, low-power and highly sensitive sensors. We present the design, fabrication, and characterization of batch-fabricated sidewall etched vertical nanogap tunneling-junctions for bio-sensing. The device consists of…

Applied Physics · Physics 2020-08-17 Aishwaryadev Banerjee

This article presents a new class of batch-fabricated, low-power and highly sensitive chemiresistive sensors. We first present the design, fabrication and characterization of batch-fabricated sidewall etched vertical nanogap…

Applied Physics · Physics 2020-06-24 Aishwaryadev Banerjee

A simple and highly reproducible technique is demonstrated for the fabrication of metallic electrodes with nanometer separation. Commercially available bare gold colloidal nanoparticles are first trapped between prefabricated…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 Saiful I. Khondaker , Zhen Yao

Break junctions provide tip-shaped contact electrodes that are fundamental components of nano and molecular electronics. However, the fabrication of break junctions remains notoriously time-consuming and difficult to parallelize. Here we…

We have fabricated a variety of novel molecular tunnel junctions based on self-assembled-monolayers (SAM) of two-component solid-state mixtures of molecular wires (1,4 methane benzene-dithiol; Me-BDT with two thiol anchoring groups), and…

Materials Science · Physics 2009-11-11 Vladimir Burtman , Alexander S. Ndobe , Valy Z. Vardeny

We present a quantitative exploration, combining experiment and simulation, of the mechanical and electronic properties, as well as the modifications induced by an alkylthiolated coating, at the single NP level. We determine the response of…

Mesoscale and Nanoscale Physics · Physics 2015-01-27 K. Smaali , S. Desbief , G. Foti , T. Frederiksen , D. Sanchez-Portal , A. Arnau , J. P. Nys , P. Leclere , D. Vuillaume , N. Clement

Crystalline nanoporous molecular networks are assembled on the Ag(111) surface, where the pores confine electrons originating from the surface state of the metal. Depending on the pore sizes and their coupling, an antibonding level is…

Recent years have shown steady progress in research towards molecular electronics [1,2], where molecules have been investigated as switches [3-5], diodes [6], and electronic mixers [7]. In much of the previous work a Scanning Tunnelling…

Mesoscale and Nanoscale Physics · Physics 2009-11-07 R. H. M. Smit , Y. Noat , C. Untiedt , N. D. Lang , M. van Hemert , J. M. van Ruitenbeek

The understanding and modeling of the heat transport across nanometer and sub-nanometer gaps where the distinction between thermal radiation and conduction become blurred remains an open question. In this work, we present a…

Mesoscale and Nanoscale Physics · Physics 2022-08-17 Yangyu Guo , Christophe Adessi , Manuel Cobian , Samy Merabia

Molecules with versatile functionalities and well-defined structures, can serve as building blocks for extreme nanoscale devices. This requires their precise integration into functional heterojunctions, most commonly in the form of…

Graphene electrodes provide a suitable alternative to metal contacts in molecular conduction nanojunctions. Here, we propose to use graphene electrodes as a platform for effective photon assisted tunneling through molecular conduction…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 Boris Fainberg

We report electron transport measurements of a silicon double dot formed in multi-gated metal-oxide-semiconductor structures with a 15-nm-thick silicon-on-insulator layer. Tunable tunnel coupling enables us to observe an excitation spectrum…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 H. W. Liu , T. Fujisawa , H. Inokawa , Y. Ono , A. Fujiwara , Y. Hirayama

We study electron transport through single-molecule junctions formed by an octanethiol molecule bonded with the thiol anchoring group to a gold electrode and the opposing methyl endgroup to a carbon tip. Using the scanning tunneling…

We present a microscopic theory of single-electron tunneling through metallic nanoparticles connected to the electrodes through molecular bridges. It combines the theory of electron transport through molecular junctions with the description…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Yongqiang Xue , Mark A. Ratner

This mini review focuses on conductance measurements through molecular junctions containing few tens of molecules, which are fabricated along two approaches: (i) conducting atomic force microscope contacting a self-assembled monolayers on…

Applied Physics · Physics 2019-11-12 Dominique Vuillaume

We have developed a controlled and highly reproducible method of making nanometer-spaced electrodes using electromigration in ambient lab conditions. This advance will make feasible single molecule measurements of macromolecules with…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 D. R. Strachan , D. E. Smith , D. E. Johnston , T. -H. Park , M. J. Therien , D. A. Bonnell , A. T. Johnson

Molecular nanowires in which a single molecule bonds chemically to two metal electrodes and forms a stable electrically conducting bridge between them have been studied intensively for more than a decade. However the experimental…

Chemical Physics · Physics 2012-08-21 Firuz Demir , George Kirczenow

Nanogaps are ubiquitous across science, confining molecules and thus changing chemistries which influence many areas such as catalysis, corrosion, photochemistry, and sensing. However in ambient conditions, it is unclear how water solvates…

We form single-electron transistors from individual chemically-synthesized gold nanoparticles, 5-15 nm in diameter, with monolayers of organic molecules serving as tunnel barriers. These devices allow us to measure the discrete electronic…

Mesoscale and Nanoscale Physics · Physics 2008-12-17 F. Kuemmeth , K. I. Bolotin , S. -F. Shi , D. C. Ralph
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