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The van der Waals (vdW) dispersion interaction between two finite neutral objects typically follows the standard nonretarded $d^{-6}$ law. Here, we reveal an anomalous $d^{-10}$ scaling law between nanostructures with strong geometric or…

Mesoscale and Nanoscale Physics · Physics 2025-07-01 Hui Pan , Yuhua Ren , Jian-Sheng Wang

We explore the interplay between tunneling process and chiral interactions in the discrimination of chiral states for an ensemble of molecules in a biological environment. Each molecule is described by an asymmetric double-well potential…

Biomolecules · Quantitative Biology 2017-04-28 Arash Tirandaz , Farhad Taher Ghahramani , Afshin Shafiee

Chirality is probably the most mysterious among all symmetry transformations. Very readily broken in biological systems, it is practically absent in naturally occurring inorganic materials and is very challenging to create artificially.…

The long-range quadrupole-quadrupole ($\sim R^{-5}$) and leading dispersion ($\sim R^{-6}$) interactions between all pairs of excited Hg($6s6p$) $^3P_0$, $^3P_1$, $^3P_2$, and $^1P_1$ atoms are determined. The quadrupole moments are…

Atomic Physics · Physics 2009-11-13 James S. Cohen , Andrei Derevianko

We theoretically investigate light matter interactions for chiral molecules in the presence of non-chiral nanoantennas. Isotropic nanostructures supporting optical-frequency electric or magnetic dipoles are sufficient to locally enhance the…

Mesoscale and Nanoscale Physics · Physics 2013-06-14 Aitzol Garcia-Etxarri , Jennifer A. Dionne

Long-range exchange and correlation effects, responsible for the failure of currently used approximate density functionals in describing van der Waals forces, are taken into account explicitly after a separation of the electron-electron…

Materials Science · Physics 2009-11-11 Janos G. Angyan , Iann C. Gerber , Andreas Savin , Julien Toulouse

We analyze van der Waals interactions between two rigid polymers with sequence-specific, anisotropic polarizabilities along the polymer backbones, so that the dipole moments fluctuate parallel to the polymer backbones. Assuming that each…

Soft Condensed Matter · Physics 2020-10-01 Bing-Sui Lu , Ali Naji , Rudolf Podgornik

Mutual Coulomb interactions between electrons lead to a plethora of interesting physical and chemical effects, especially if those interactions involve many fluctuating electrons over large spatial scales. Here, we identify and study in…

We consider the dispersion energy of a pair of dipoles embedded in a metallic waveguide with transverse dimension $a$ smaller than the characteristic dipolar wavelength. We find that $a$ sets the scale that separates retarded,…

Quantum Physics · Physics 2013-06-13 Ephraim Shahmoon , Gershon Kurizki

Chiral four-wave-mixing signals are calculated using the irreducible tensor formalism. Different polarization and crossing angle configurations allow to single out the magnetic dipole and the electric quadrupole interactions. Other…

Chemical Physics · Physics 2020-07-30 Jérémy R. Rouxel , Ahmadreza Rajabi , Shaul Mukamel

We study the dispersion interaction of the van der Waals and Casimir-Polder (vdW-CP) type between a neutral atom and the surface of a metal by allowing for nonlocal electrodynamics, i.e. electron diffusion. We consider two models: (i) bulk…

Atomic Physics · Physics 2014-07-23 Elad Eizner , Baruch Horovitz , Carsten Henkel

By inferring the dynamic permittivity of different material media from the observations and calculating dynamic electric dipole polarizabilties of the Li through Cs alkali atoms, precise values of $C_3$ coefficients were estimated in Phys.…

Atomic Physics · Physics 2023-10-02 Harpreet Kaur , Vipul Badhan , Bindiya Arora , B. K. Sahoo

The dispersion energy between extended molecular chains (or equivalently infinite wires) with non-zero band gaps is generally assumed to be expressible as a pair-wise sum of atom-atom terms which decay as $R^{-6}$. Using a model system of…

Mesoscale and Nanoscale Physics · Physics 2012-12-17 Alston J. Misquitta , James Spencer , Anthony J. Stone , Ali Alavi

We establish a general relation between dispersion forces. First, based on QED in causal media, leading-order perturbation theory is used to express both the single-atom Casimir-Polder and the two-atom van der Waals potentials in terms of…

Quantum Physics · Physics 2007-06-12 Stefan Yoshi Buhmann , Hassan Safari , Dirk-Gunnar Welsch , Ho Trung Dung

Van der Waals interactions between flat surfaces in uniaxial anisotropic media are investigated in the nonretarded limit. The main focus is the effect of nonzero tilt between the optical axis and the surface normal on the strength of van…

Soft Condensed Matter · Physics 2018-03-13 Pavel Kornilovitch

Van der Waals heterostructures of atomically thin layers with rotational misalignments, such as twisted bilayer graphene, feature interesting structural moir\'e superlattices. Due to the quantum coupling between the twisted atomic layers,…

It is shown that chiral plasmons, characterized by a longitudinal magnetic moment accompanying the longitudinal charge plasmon, lead to electromagnetic near-fields that are also chiral. For twisted bilayer graphene, we estimate that the…

Mesoscale and Nanoscale Physics · Physics 2021-09-21 T. Stauber , T. Low , G. Gómez-Santos

We study the propagation of electromagnetic waves in a chiral fluid, where the molecules are described by a simplified version of the Kuhn coupled oscillator model. The eigenmodes of Maxwell's equations are circularly polarized waves. The…

Physics Education · Physics 2008-03-05 T. Garel

The chiral source and its mechanism in the molecular system are of great significance in many fields. In this work, we proposed visualized methods to investigate physical mechanism of chiral molecule, where the electric and magnetic…

Chemical Physics · Physics 2019-05-29 Jingang Wang , Xiangtao Chen , Jizhe Song , Xijiao Mu , Mengtao Sun

We estimate polarizabilities of atoms in molecules without electron density, using a Voronoi tesselation approach instead of conventional density partitioning schemes. The resulting atomic dispersion coefficients are calculated, as well as…

Chemical Physics · Physics 2015-08-31 Tristan Bereau , O. Anatole von Lilienfeld