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Recent experiments have demonstrated that the glass transition temperature of thin polymer films can be shifted as compared to the same polymer in the bulk, the amplitude and the sign of this effect depending on the interaction between the…

Statistical Mechanics · Physics 2007-05-23 D. Long , P. Sotta

Direct atomically resolved observation of dynamics deep in the glassy regime has proved elusive for atomic and molecular glasses. Studies below the glass transition temperature Tg are especially rare due to long waiting times required to…

Mesoscale and Nanoscale Physics · Physics 2010-06-10 Sumit Ashtekar , Gregory Scott , Joseph Lyding , Martin Gruebele

In this article, we present a universal relationship between the glass transition temperature $T_g$ and the local glass structure. The derivation of the simplest expression of this relationship and some comparisons with experimental $T_g$…

Disordered Systems and Neural Networks · Physics 2009-10-31 Matthieu Micoulaut

At temperatures well below their glass transition, the deformation properties of bulk metallic glasses are characterised by a sharp transition from elasticity to plasticity, a reproducible yield stress, and an approximately linear decrease…

Soft Condensed Matter · Physics 2013-11-18 P. M. Derlet , R. Maaß

Metallic glasses are promising materials with unique mechanical and thermal properties, but their atomic-scale dynamics remain challenging to understand. In this work, we develop a unified approach to investigate the glass transition and…

Materials Science · Physics 2025-02-07 Anh D. Phan , Do T. Nga , Ngo T. Que , Hailong Peng , Thongchanh Norhourmour , Le M. Tu

We present results of a simulation study of inelastic hard-disks vibrated in a vertical container. An Event-Driven Molecular Dynamics method is developed for studying the onset of convection. Varying the relevant parameters (inelasticity,…

Statistical Mechanics · Physics 2016-08-31 Daniela Paolotti , Alain Barrat , Umberto Marini Bettolo Marconi , Andrea Puglisi

Using molecular dynamics computer simulations we investigate how in silica the glass transition and the properties of the resulting glass depend on the cooling rate with which the sample is cooled. By coupling the system to a heat bath with…

Condensed Matter · Physics 2009-10-28 Katharina Vollmayr , Walter Kob , Kurt Binder

Supercooled liquid state is a particularly interesting state in that it exhibits several unusual physical properties. To illustrate, the liquid displays a single peak relaxation frequency at high temperatures, which splits into $\alpha$…

Soft Condensed Matter · Physics 2024-12-17 Wenlong Jiang

Understanding the connection between thermodynamics and dynamics in glass-forming liquids remains a central challenge in condensed matter physics. In this study, we investigate a novel model system that enables a continuous crossover from a…

Soft Condensed Matter · Physics 2025-05-30 Ehtesham Anwar , Ujjwal Kumar Nandi , Palak Patel , Sanket Kumawat , Sarika Maitra Bhattacharyya

Prompted by results that showed that a simple protein model, the frustrated G\=o model, appears to exhibit a transition reminiscent of the protein dynamical transition, we examine the validity of this model to describe the low-temperature…

Statistical Mechanics · Physics 2014-01-24 Johannes-Geert Hagmann , Naoko Nakagawa , Michel Peyrard

In the present work, a detailed analysis of the glassy behavior and the relaxation dynamics of the liquid crystal dimer {\alpha}-(4-cyanobiphenyl-4'-yloxy)-{\omega}-(1-pyrenimine-benzylidene-4'-oxy) heptane (CBO7O.Py) throughout both…

Soft Condensed Matter · Physics 2018-10-02 David O. López , Josep Salud , María Rosario de la Fuente , Nerea Sebastián , Sergio Diez-Berart

Sizable glass formers feature numerous unique properties and potential applications, but many questions regarding their glass transition dynamics have not been resolved yet. Here we analyzed structural relaxation times measured as a…

Soft Condensed Matter · Physics 2024-03-08 Marzena Rams-Baron , Alfred Blazytko , Riccardo Casalini , Marian Paluch

We have investigated the reduction of the glass transition temperature, $T_g$, for thin supported films of particularly small molecular weight ($M_W$ = 2 kg/mol) polystyrene, and found good agreement with earlier studies on larger…

Soft Condensed Matter · Physics 2009-09-25 Ralf Seemann , Karin Jacobs , Stephan Herminghaus

We discuss the microscopic mechanisms by which low-temperature amorphous states, such as ultrastable glasses, transform into equilibrium fluids, after a sudden temperature increase. Experiments suggest that this process is similar to the…

Statistical Mechanics · Physics 2016-07-05 Robert L. Jack , Ludovic Berthier

We show that a glass transition, signaled by a peak in the specific heat vs. temperature, can occur because a glassy system that shows no signs of aging progresses so slowly through the energy landscape that the time needed to obtain an…

Disordered Systems and Neural Networks · Physics 2007-05-23 Clare C. Yu , Herve M. Carruzzo

Super-cooled liquids are characterized by their fragility: the slowing down of the dynamics under cooling is more sudden and the jump of specific heat at the glass transition is generally larger in fragile liquids than in strong ones.…

Disordered Systems and Neural Networks · Physics 2014-01-14 Le Yan , Gustavo Düring , Matthieu Wyart

The Glauber dynamics of disordered spin models with multi-spin interactions on sparse random graphs (Bethe lattices) is investigated. Such models undergo a dynamical glass transition upon decreasing the temperature or increasing the degree…

Disordered Systems and Neural Networks · Physics 2009-11-11 Andrea Montanari , Guilhem Semerjian

We investigate the Johari-Goldstein (JG) $\beta$-relaxation process in a model metallic glass-forming (GF) material (Al90Sm10), previously studied extensively by both frequency-dependent mechanical measurements and simulation studies…

Materials Science · Physics 2021-03-09 Hao Zhang , Xinyi Wang , Hai-Bin Yu , Jack F. Douglas

We present a mean-field theory of a coarse-grained model of a super-cooled liquid in which relaxation occurs via local plastic rearrangements. Local relaxation can be induced by thermal fluctuations or by the long-range elastic consequences…

Soft Condensed Matter · Physics 2023-12-07 Joseph W. Baron , Giulio Biroli

We theoretically investigate glass transition behaviors of the glassy graphene in a wide range of temperature, where this amorphous graphene is described as a hard-sphere fluid. The dynamic arrest of a particle is assumingly caused by…

Soft Condensed Matter · Physics 2020-03-11 Tran Dinh Cuong , Anh D. Phan , Katsunori Wakabayashi , Pham Thanh Huy