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Simulating charged many-body systems has been a computational demanding task due to the long-range nature of electrostatic interaction. For the multi-scale model of electrolytes which combines the strengths of atomistic/continuum…

Computational Physics · Physics 2022-07-22 Jing Fu , Zecheng Gan

The evaluation of long-range Coulomb interactions is a significant cost in molecular dynamics (MD), even when using Particle Mesh Ewald (PME) or Particle-Particle-Particle-Mesh (PPPM) methods, which rely on Ewald splitting and the fast…

Numerical Analysis · Mathematics 2026-04-21 Jiuyang Liang , Libin Lu , Alex Barnett , Leslie Greengard , Shidong Jiang

We study the electrostatic potential of a molecular wire bridging two metallic electrodes in the limit of weak contacts. With the use of a tight-binding model including a fully three-dimensional treatment of the electrostatics of the…

Chemical Physics · Physics 2007-05-23 Stéphane Pleutin , Hermann Grabert , Gert-Ludwig Ingold , Abraham Nitzan

Massively-parallel molecular dynamics simulation is applied to systems containing electrolytes, vapour-liquid interfaces, and biomolecules in contact with water-oil interfaces. Novel molecular models of alkali halide salts are presented and…

An expression for the effective Coulomb logarithm in one-component-plasma is proposed, which allows to extend the applicability of the classical formula for the self-diffusion coefficient to the strongly coupled regime. The proposed…

Plasma Physics · Physics 2013-06-18 Sergey A. Khrapak

In this paper we study a general theoretical framework which allows to approximate the real space Ewald sum by means of effective force shifted screened potentials, together with a self term. Using this strategy it is possible to generalize…

Materials Science · Physics 2014-11-10 Victor H. Elvira , Luis G. MacDowell

Accurate modelling of electrostatic interactions and charge transfer is fundamental to computational chemistry, yet most machine learning interatomic potentials (MLIPs) rely on local atomic descriptors that cannot capture long-range…

Symmetry-adapted perturbation theory (SAPT) is a popular and versatile tool to compute and decompose noncovalent interaction energies between molecules. The intramolecular SAPT (ISAPT) variant provides a similar energy decomposition between…

Chemical Physics · Physics 2024-05-09 Du Luu , Clemence Corminboeuf , Konrad Patkowski

The lattice fluid model of the system with short range and long range Coulomb interactions is suggested. In the framework of the collective variables method, the screening of the Coulomb interactions in the bulk is considered. It is shown…

Other Condensed Matter · Physics 2019-01-24 George Bokun , Dung di Caprio , Myroslav Holovko , Vyacheslav Vikhrenko

Machine learning interatomic potentials (MLIPs) provide a computationally efficient alternative to quantum mechanical simulations for predicting material properties. Message-passing graph neural networks, commonly used in these MLIPs, rely…

Chemical Physics · Physics 2025-09-08 Moin Uddin Maruf , Sungmin Kim , Zeeshan Ahmad

We describe a practical procedure to calculate the Coulomb matrix elements of 2D spatially separated and confined charge carriers, which are needed for detailed theoretical descriptions of important condensed matter finite systems. We…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Ian Mondragon-Shem , Francisco E. Lopez , Boris A. Rodriguez

A variational approach, based on a discrete representation of the chain, is used to calculate free energy and conformational properties in polyelectrolytes. The true bond and Coulomb potentials are approximated by a trial isotropic harmonic…

chem-ph · Physics 2016-08-15 B. Jönsson , C. Peterson , B. Söderberg

We present a highly efficient method to directly simulate the photodissociation followed by Coulomb explosion of methyl iodide. In order to achieve statistical reliability, more than 40,000 trajectories are calculated on accurate potential…

Chemical Physics · Physics 2024-11-06 Yijue Ding , Loren Greenman , Daniel Rolles

A novel energy-efficient edge computing paradigm is proposed for real-time deep learning-based image upsampling applications. State-of-the-art deep learning solutions for image upsampling are currently trained using either resize or…

Computer Vision and Pattern Recognition · Computer Science 2021-07-27 Ian Colbert , Ken Kreutz-Delgado , Srinjoy Das

A proper treatment of electrostatic interactions is crucial for the accurate calculation of forces in computer simulations. Electrostatic interactions are typically modeled using Ewald based methods, which have become one of the…

Soft Condensed Matter · Physics 2016-09-21 K. A. Terrón-Mejía , R. López-Rendón , A. Gama Goicochea

We propose a novel deterministic particle method to numerically approximate the Landau equation for plasmas. Based on a new variational formulation in terms of gradient flows of the Landau equation, we regularize the collision operator to…

Analysis of PDEs · Mathematics 2020-05-26 Jose A. Carrillo , Jingwei Hu , Li Wang , Jeremy Wu

The effective on-site Coulomb interaction (Hubbard $U$) between 5$f$ electrons in actinide metals (Th-Cf) is calculated with the framework of density-functional theory (DFT) using linear response approach. The $U$ values seldom rely on the…

Materials Science · Physics 2020-01-14 Ruizhi Qiu , Bingyun Ao , Li Huang

A practical method to solve cut-off Coulomb problems of two-cluster systems in the momentum space is given. When a sharply cut-off Coulomb force with a cut-off radius $\rho$ is introduced at the level of constituent particles, two-cluster…

Nuclear Theory · Physics 2012-09-03 Yoshikazu Fujiwara , Kenji Fukukawa

Unitary Coupled Cluster (UCC) theory is a promising variational method for electronic structure calculations, especially for strongly correlated systems and quantum computers. However, its practical application is limited by the steep…

Chemical Physics · Physics 2026-02-05 Prateek Vaish , Brenda Rubenstein

We consider different Linear Combination of Unitaries (LCU) decompositions for molecular electronic structure Hamiltonians. Using these LCU decompositions for Hamiltonian simulation on a quantum computer, the main figure of merit is the…

Quantum Physics · Physics 2023-06-13 Ignacio Loaiza , Alireza Marefat Khah , Nathan Wiebe , Artur F. Izmaylov