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The momentum-space derivatives of Bloch wavefunctions are essential for studying quantum geometry and the equilibrium and response properties of solids. In practical first-principles calculations, these derivatives are obtained via Wannier…

Materials Science · Physics 2026-04-27 Jae-Mo Lihm , Minsu Ghim , Seung-Ju Hong , Cheol-Hwan Park

A new implementation is proposed for including van der Waals interactions in Density Functional Theory using the Maximally-Localized Wannier functions. With respect to the previous DFT/vdW-WF method, the present DFT/vdW-WF2 approach, which…

Strongly Correlated Electrons · Physics 2015-06-03 A. Ambrosetti , P. L. Silvestrelli

We investigate a recently developed approach [P. L. Silvestrelli, Phys. Rev. Lett. 100, 053002 (2008); J. Phys. Chem. A 113, 5224 (2009)] that uses maximally localized Wannier functions to evaluate the van der Waals contribution to the…

Materials Science · Physics 2012-06-12 Lampros Andrinopoulos , Nicholas D. M. Hine , Arash A. Mostofi

When using Wannier functions to study the electronic structure of multi-parameter Hamiltonians $H^{(\boldsymbol k,\bf \lambda)}$ carrying a dependence on crystal momentum $\boldsymbol k$ and an additional periodic parameter $\bf\lambda$,…

Materials Science · Physics 2015-06-11 Jan-Philipp Hanke , Frank Freimuth , Stefan Blügel , Yuriy Mokrousov

We present a first-principles scheme that allows the orbital magnetization of a magnetic crystal to be evaluated accurately and efficiently even in the presence of complex Fermi surfaces. Starting from an initial electronic-structure…

Materials Science · Physics 2012-02-03 M. G. Lopez , David Vanderbilt , T. Thonhauser , Ivo Souza

The construction of Wannier functions from Bloch orbitals offers a unitary freedom that can be exploited to yield Wannier functions with advantageous properties. Minimizing the spatial variance is a well-known choice; another, previously…

Materials Science · Physics 2026-04-29 Aaron Mahler , Jacob Z. Williams , Neil Qiang Su , Weitao Yang

We generalize the Wannier interpolation of the electron-phonon matrix elements to the case of polar-optical coupling in polar semiconductors. We verify our methodological developments against experiments, by calculating the widths of the…

Materials Science · Physics 2015-09-30 J. Sjakste , N. Vast , M. Calandra , F. Mauri

Quantum Entanglement plays an ubiquitous role in theoretical physics, from the characterization of novel phases of matter to understanding the efficacy of numerical algorithms. As such, there have been extensive studies on the entanglement…

Quantum Gases · Physics 2015-02-23 Ching Hua Lee , Peng Ye

We present a computational scheme to study spin excitations in magnetic materials from first principles. The central quantity is the transverse spin susceptibility, from which the complete excitation spectrum, including single-particle…

Materials Science · Physics 2010-03-04 Ersoy Sasioglu , Arno Schindlmayr , Christoph Friedrich , Frank Freimuth , Stefan Blügel

A method for increasing the accuracy of configuration interaction (CI) calculations of molecules and other electronic systems is proposed. The energy defect of a given calculation is associated with the electron pair origin of…

Chemical Physics · Physics 2025-11-18 Jerry L. Whitten

We present a new ab initio method for calculating effective onsite Coulomb interactions of itinerant and strongly correlated electron systems. The method is based on constrained local density functional theory formulated in terms of…

Strongly Correlated Electrons · Physics 2009-11-11 Kazuma Nakamura , Ryotaro Arita , Yoshihide Yoshimoto , Shinji Tsuneyuki

We present a simplified computational scheme in order to calculate the effects of electron correlations on the energy bands of diamond and silicon. By adopting a quasiparticle picture we compute first the relaxation and polarization effects…

Materials Science · Physics 2009-01-07 Uwe Birkenheuer , Peter Fulde , Hermann Stoll

We develop an ab initio formalism for dipolar electron-phonon interactions (EPI) in two-dimensional (2D) materials. Unlike purely longitudinal Fr\"ohlich model, we show that the out-of-plane dipoles also contribute to the long-wavelength…

Materials Science · Physics 2021-02-08 Tianqi Deng , Gang Wu , Wen Shi , Zicong Marvin Wong , Jian-Sheng Wang , Shuo-Wang Yang

A new implementation is proposed for including van der Waals (vdW) interactions in Density Functional Theory (DFT) using the Maximally-Localized Wannier functions (MLWFs), which is free from empirical parameters. With respect to the…

Chemical Physics · Physics 2019-05-22 Pier Luigi Silvestrelli , Alberto Ambrosetti

We propose a computational scheme for the ab initio calculation of Wannier functions (WFs) for correlated electronic materials. The full-orbital Hamiltonian H is projected into the WF subspace defined by the physically most relevant…

We present an approach to parameterize DFT+$U$+$V$ from hybrid-functional calculations using Wannier-function projections. The method constructs a common localized Wannier basis for both semilocal DFT and hybrid-functional calculations,…

Strongly Correlated Electrons · Physics 2026-02-25 Dmitry M. Korotin , Anna A. Anisimova , Vladimir I. Anisimov

Maximally-localized Wannier functions are quantum wavefunctions resembling atomic orbitals that are used to describe electrons in condensed matter. Since their introduction in 1997, these functions have become ubiquitous in ab initio…

Computational Physics · Physics 2026-04-09 Sabyasachi Tiwari , Bruno Cucco , Viet-Anh Ha , Feliciano Giustino

We present an automatic, high-order accurate, and adaptive Brillouin zone integration algorithm for the calculation of the optical conductivity with a non-zero but small broadening factor $\eta$, focusing on the case in which a Hamiltonian…

Materials Science · Physics 2024-06-25 Lorenzo Van Muñoz , Jason Kaye , Alex Barnett , Sophie Beck

Wannier interpolation is a powerful tool for performing Brillouin zone integrals over dense grids of $\mathbf{k}$ points, which are essential to evaluate such quantities as the intrinsic anomalous Hall conductivity or Boltzmann transport…

Materials Science · Physics 2021-02-22 Stepan S. Tsirkin

We present a method for obtaining well-localized Wannier-like functions (WFs) for energy bands that are attached to or mixed with other bands. The present scheme removes the limitation of the usual maximally-localized WFs method (N. Marzari…

Materials Science · Physics 2009-11-07 Ivo Souza , Nicola Marzari , David Vanderbilt